Bernard Raveau - Böcker

"Physics and Materials Science of High Temperature Superconductors II" represents the results of a fruitful dialogue between physicists and materials scientists which took place under the auspices of a NATO Advanced Study Institute in Porto Carras, Greece, between 18 and 31 August 1991. It builds on and carries forward the success of NATO ASI 181 published in 1990. The theoretical side of the discussions reveal the basic premise of the phenomenological and Ginzburg-Landau theories of superconductivity, the implications of short coherence length, long penetration depth, the melting of flux lattices, and other matters, while the materials science includes discussions of microstructures, local inhomogeneities, deviations from ideal chemistry, the effects of systematic errors in materials preparation, the definition of imperfections, and the utilization of common materials analysis techniques.The reader is made aware of the potential significance of Angstrom scale structural and chemical details, and the need to consider basic theoretical concepts when designing procedures to process viable, solid conductors, specifically the effects of oxygen stoichiometry and deviations from it, as well as the microstructural demands on pinning in the light of very short coherence lengths.

The recent discovery of high-temperature superconductivity in copper­ based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli­ cations. The numerous papers published in the field of high Tc supercon­ ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc­ ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon­ ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir­ radiation effects.

Physics and Materials Science of High Temperature Superconductors, II represents the results of a fruitful dialogue between physicists and materials scientists which took place under the auspices of a NATO Advanced Study Institute in Porto Carras, Greece, between 18 and 31 August, 1991. It builds on and carries forward the success of NATO ASI 181 published in 1990. The theoretical side of the discussions reveal the basic premise of the phenomenological and Ginzburg-Landau theories of superconductivity, the implications of short coherence length, long penetration depth, the melting of flux lattices, and other matters, while the materials science includes discussions of microstructures, local inhomogeneities, deviations from ideal chemistry, the effects of systematic errors in materials preparation, the definition of imperfections, and the utilization of common materials analysis techniques. The reader will be made aware of the potential significance of Angstrom scale structural and chemical details, and the need to consider basic theoretical concepts when designing procedures to process viable, solid conductors, specifically the effects of oxygen stoichiometry and deviations from it, as well as the microstructural demands on pinning in the light of very short coherence lengths.