Bruno Yaron - Böcker

This book is dedicated to understanding the processes governing the fate of pollutants, originating from both agriculture and industry, in soils. Investigated here are the properties of the interacting materials, pollutant partitioning between the soil phases, pollutant behavior in soils affected by environmental factors, as well as the principles to be considered in defining pollutant behavior. The authors offer specialists working on soil pollution remediation the necessary background for their day-to-day work. The book will also be useful for graduate students starting research in this field.

This book combines soil science, earth science, and environmental geochemistry, providing comprehensive background information for specialists interested in chemical-induced changes in the soil-subsurface system. Readers are introduced to the chemistry of contaminants that often disturb the natural soil-subsurface equilibrium as a result of human activity. While the soil-subsurface system has in many cases been affected by human impact, the effects of chemical contaminants on the actual matrix and properties have been largely neglected. The major focus of the book is on changes to the soil-subsurface matrix and properties caused by chemical pollution. By integrating results available in the literature, we observe that chemical pollutants may lead to the irreversible formation of a new soil-subsurface regime characterized by a matrix and properties different than those of the natural regime. In contrast to the geological time scales dictating natural changes to the matrix and properties of the soil-subsurface system, the time scale associated with chemical pollutant-induced changes is far shorter and extends over a “human lifetime scale.” The numerous examples presented in the book confirm that chemical contamination should be considered as an additional factor in the formation of a contemporary soil-subsurface regime that is different than that of the pristine system.

This book combines soil science, earth science, and environmental geochemistry, providing comprehensive background information for specialists interested in chemical-induced changes in the soil-subsurface system. Readers are introduced to the chemistry of contaminants that often disturb the natural soil-subsurface equilibrium as a result of human activity. While the soil-subsurface system has in many cases been affected by human impact, the effects of chemical contaminants on the actual matrix and properties have been largely neglected. The major focus of the book is on changes to the soil-subsurface matrix and properties caused by chemical pollution. By integrating results available in the literature, we observe that chemical pollutants may lead to the irreversible formation of a new soil-subsurface regime characterized by a matrix and properties different than those of the natural regime. In contrast to the geological time scales dictating natural changes to the matrix and properties of the soil-subsurface system, the time scale associated with chemical pollutant-induced changes is far shorter and extends over a “human lifetime scale.” The numerous examples presented in the book confirm that chemical contamination should be considered as an additional factor in the formation of a contemporary soil-subsurface regime that is different than that of the pristine system.

In this updated and expanded second edition, new literature has been added on contaminant fate in the soil-subsurface environment. In particular, more data on the behavior of inorganic contaminants and on engineered nanomaterials were included, the latter comprising a group of “emerging contaminants” that may reach the soil and subsurface zones.New chapters are devoted to a new perspective of contaminant geochemistry, namely irreversible changes in pristine land and subsurface systems following chemical contamination. Two chapters were added on this topic, focusing attention on the impact of chemical contaminants on the matrix and properties of both liquid and solid phases of soil and subsurface domains. Contaminant impacts on irreversible changes occurring in groundwater are discussed and their irreversible changes on the porous medium solid phase are surveyed. In contrast to the geological time scale controlling natural changes of porous media liquid and solid phases, the time scale associated with chemical pollutant induced changes is far shorter and extends over a “human lifetime scale”.

The soil is the medium through which pollutants originating from human activities, both in agriculture and industry, move from the land surfaces to groundwater. Polluting substances are subject to complex physical, chemical and biological transformations during their movement through the soil. Their displacement depends on the transport properties of the water-air-soil system and on the molecular properties of the pollutants. Prediction of soil pollution and restoration of polluted soils requires an under­ standing of the processes controlling the fate of pollutants in the soil medium and of the dynamics of the contaminants in the un­ saturated zone. Our book was conceived· as a basic overview of the processes governing the behavior of pollutants as affected by soil constituents and environmental factors. It was written for the use of specialists working on soil and unsaturated zone pollution and restoration, as well as for graduate students starting research in this field. Since many specialists working on soil restoration lack a back­ ground in soil science or a knowledge of the properties of soil pollutants, we have included this information which forms the first part of the book. In the second part, we discuss the partitioning of pollutants between the aqueous, solid and gaseous phase of the soil medium. The retention, transformation and transport of pollutants in the soils form the third section.

A book previously published within the framework of the Ecological Studies Series, entitled "Physical Aspects of Soil Water and Salts in Ecosystems" included awidespectrum of research papers devoted to new findings in the field of soil-plant-water relationships. "Arid Zone Irrigation" has been written specifically as a textbook for agronomists, soil scientists, agrometeorologists, water engineers and plant physiologists who want a clear presentation of irrigation fundamentals in arid and semi-arid zones. It was our intention to provide an understanding of the basic principles governing irrigation technology and to help overcome the problem of water shortage in arid zone agriculture. This book, written by a large number of specialists and covering a broad spectrum of different disciplines, is based on general up-to-date information, as well as on the results of the authors' own research. The idea of preparing such a textbook was conceived during a series of international advanced courses on irrigation held annually at the Institute of Soils and Water, Agricul­ tural Research Organization, Volcani Center, Bet Dagan, Israel. The final organization of the material has been influenced by discussions with colleagues from Sweden and Holland and the participants in our summer courses. Grateful acknowledgements are due to Professor CALVIN C. ROSE, CSIRO, Canberra, Australia, Professor DALE SWARTZENDRUBER, Purdue University, Lafayetta, U.S.A., and Dr. SHLOMO P. NEUMAN, Agricultural Research Organization, Bet Dagan, Israel, for their many helpful suggestions during critical reading of the manuscript. We thank also Mrs.

In March, 1983 a workshop on Pollutants in Porous Media was hosted by the Institute of Soils and Water of the Agricultural Research Organi­ zation in Bet Dagan, Israel. At this workshop, the unsaturated zone be­ tween the soil surface and groundwater was the focal point of discus­ sions for scientists from various disciplines such as soil chemists, physicists, biologists and environmental engineers. Since then, the prob­ lem of soil and water pollution has only worsened as more and more cases of pollution caused by human activities including agriculture and industry have been revealed. A great deal of work has been carried out by environmental scientists since 1983 in elucidating the behavior of the many classes of pollutants and the complex physical, chemical, and bio­ logical transformations which they undergo as they move through the soil to the vadose zone and, in many cases, the groundwater. In light of this, it was felt that another meeting of specialists from the many disciplines which deal with this subject was necessary and so a Second International Workshop on the Behavior of Pollutants in Porous Media, sponsored by IUPAC (the International Union of Pure and Applied Chemistry) and IAHS (the International Association of Hydrological Sciences), was organized and held in the Institute of Soils and Water of the Agricultural Research Organization in Bet Dagan, Israel during 1987. June, The present volume is a selection of the talks presented at this second workshop and deals only with toxic organic chemicals in porous media.

As the world population increases, there is increasingcompetition for waterquantity as well as quality.Provided here is an up-to-date perspective on AvailableWater Resources (Part I), Water Conservation and TechnologyinAgricultural Systems (Part II), Problem Water Uses andTreatment (Part III),and Management and Policy Evaluation(Part IV).