Gabriele Centi – författare

This text covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process.This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that it is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.

Unlocking the Future of Renewable Energy and Chemistry through Catalysis provides a broad view of the gaps and opportunities related to the ongoing energy and chemistry transition, particularly in the science and technology, as well as complementary aspects, including societal ones, needed to unlock the future of renewable energy and chemistry through catalysis. It provides background and complementary aspects that are needed to understand the future scenarios to identify priorities and missing aspects in technologies and scientific background, and to create an open mind approach in science and technology to unlock the renewable energy and chemistry future.The book focuses on catalysis and complements the review articles currently available in the literature. It provides general knowledge, allowing the reader to understand the fast-evolving scenario better and, in turn, identify opportunities and needs.Offers an integrated view of the changing outlook for energy and chemistry and the impact on catalysisProvides a gaps and opportunity analysis, combining the analysis of the transformative scenario to S&T backgrounds and advancesWritten by top scientists and industrial managers to offer a perspective on priorities and bottlenecks to develop a renewables-based economy

Catalysis, Green Chemistry and Sustainable Energy: New Technologies for Novel Business Opportunities offers new possibilities for businesses who want to address the current global transition period to adopt low carbon and sustainable energy production. This comprehensive source provides an integrated view of new possibilities within catalysis and green chemistry in an economic context, showing how these potential new technologies may become useful to business. Fundamentals and specific examples are included to guide the transformation of idea to innovation and business.

Offering an overview of the new possibilities for creating business in catalysis, energy and green chemistry, this book is a beneficial tool for students, researchers and academics in chemical and biochemical engineering.

Discusses new developments in catalysis, energy and green chemistry from the perspective of converting ideas to innovation and business Presents case histories, preparation of business plans, patent protection and IP rights, creation of start-ups, research funds and successful written proposals Offers an interdisciplinary approach combining science and business

Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.

Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.

PROMISING NEW APPROACHES TO RECYCLE CARBON DIOXIDE AND REDUCE EMISSIONSWith this book as their guide, readers will learn a variety of new approaches and methods to recycle and reuse carbon dioxide (CO2) in order to produce green fuels and chemicals and, at the same time, minimize CO2 emissions. The authors demonstrate how to convert CO2 into a broad range of essential products by using alternative green energy sources, such as solar, wind, and hydro-power as well as sustainable energy sources. Readers will discover that CO2 can be a driving force for the sustainable future of both the chemical industry and the energy and fuels industry.Green Carbon Dioxide features a team of expert authors, offering perspectives on the latest breakthroughs in CO2 recycling from Asia, Europe, and North America. The book begins with an introduction to the production of CO2-based fuels and chemicals. Next, it covers such topics as: Transformation of CO2 to useable products through free-radical-induced reactionsHydrogenation of CO2 to liquid fuelsDirect synthesis of organic carbonates from CO2 and alcohols using heterogeneous oxide catalystsElectrocatalytic reduction of CO2 in methanol mediumFuel production from photocatalytic reduction of CO2 with water using TiO2-based nanocompositesUse of CO2 in enhanced oil recovery and carbon capture and sequestrationMore than 1,000 references enable readers to explore individual topics in greater depth.Green Carbon Dioxide offers engineers, chemists, and managers in the chemical and energy and fuel industries a remarkable new perspective, demonstrating how CO2 can play a significant role in the development of a sustainable Earth.

Enables readers to use plasma technology in the ammonia and NOx production process for greater efficiency, resiliency, and sustainability Bridging the gap between chemistry, physics, and engineering, Plasma-Assisted Nitrogen Fixation for Sustainable Process Industries provides in-depth insights into plasma-assisted nitrogen fixation, plasma technology, plasma reactors, and ammonia and NOx production, covering fundamental principles, advanced topics, economic viability, and emerging trends. Real-world applications and case studies are included throughout to elucidate key concepts and help readers put theory into practice in order to increase efficiency, sustainability, and industrial resilience. Plasma-Assisted Nitrogen Fixation for Sustainable Process Industries discusses: Reactor designs and industrial feasibility, including decentralized production to make nitrogen fixation accessible to remote areas and smaller-scale operationsThe Haber-Bosch process and its limitations and alternatives and plasma generation, ionization, and applicationsPlasma-assisted NOx synthesis with a focus on reaction pathways, energy efficiency, and the role of catalystsCutting-edge innovations such as microplasma technology, plasma-liquid interactions for nitrogen fixation, and plasma-electrochemistry for nitrate-to-ammonia conversionPlasma-based fertilizer applications and analytical methods in plasma diagnostics as a tool to enable innovation Plasma-Assisted Nitrogen Fixation for Sustainable Process Industries is an essential reference on the subject for engineers, plant managers, and decision-makers seeking to optimize their ammonia and NOx manufacturing processes.

As the annual production of carbon Dioxide (CO2) reaches 30 billion tones, the growing issue of the greenhouse effect has triggered the development of technologies for CO2 sequestration, storage and use as a reactant. Collecting together the reports of the Congress at University of Rome (Campus Bio-medico) held 16th April 2012, CO2: A Valuable Source of Carbon presents and discusses promising technologies for the industrial exploitation of CO2.  Divided into two parts, the current technology is evaluated and summarized before European and national projects are presented. The focus on CO2 recovery, particularly in value-added production, proposes applicable methods to develop sustainable practices  and even to mitigate greenhouse gas emission from large-scale fossil fuels usage. Including current data and real-world examples, CO2: A valuable source of carbon  provides students, engineers, researchers and industry professional with up-to-date material and potential areas for development and research.

As the annual production of carbon Dioxide (CO2) reaches 30 billion tones, the growing issue of the greenhouse effect has triggered the development of technologies for CO2 sequestration, storage and use as a reactant.

Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.

The general scenario of the chemical production in the world is gradually changing under the unavoidable pressure generated in the last twenty years by the need to produce in a sustainable and environmentally friendly way. The natural targets of the book are the basic and advanced courses in industrial chemistry, but it can also serve as a basis to treat only basic aspects or specific topics. The text is divided into two parts: the first defines the basic principles of industrial chemistry (from gas properties to catalysis, to energy and mass balances, to reactor design) with a focus on sustainability. The second part of the book analyses a selection of processes in all their aspects. Rather than giving a general overview of chemical processes, for which there are valuable encyclopedias that are regularly updated, it is of greater educational interest to focus the attention on a few specific cases, illustrative of the principles presented in the first part.

There are various books on green chemistry on the market, but without focus on sustainable industrial processes. This resource provides an overview of the new trends and hot topics in process design, describing the challenge of designing industrial chemical processes that are up-to-date, sustainable, and economically feasible. The industrial applications are presented directly by the companies – a veritable "Who's Who" of the chemical industry – that developed these innovative technologies. It provides an essential reference for chemical engineers, chemists in industry, process engineers, catalytic chemists, materials scientists, and environmental chemists.

This book disseminates and discusses relevant best case examples and research practices that show how nanomaterial research and related engineering concepts may provide answers and viable solutions to a variety of socioeconomic issues and concerns. The first section is dedicated to the development of new materials and their characterization. The second section addresses modeling and scale transition (from and to nanoscale) processes, and the third section presents applications in the environmental and energy sectors.Nanoporous Materials for Energy and the Environment covers a wide selection of subjects ranging from modeling and material design to the preparation and use of nanoporous catalysts, adsorbents, and membranes. The topics discussed include proton exchange membranes; carbon nanotube (CNT)-based electrodes for fuel cells; advanced design of lithium batteries and supercapacitors using CNTs; multifunctional catalyst for biomass conversion; advanced characterization and modeling of nanomaterials and membranes (including gas transport and multiscale modeling); use of membranes in energy applications, gas treatment, and separations; and development of multifunctional photoactive membranes and of nanoordered 2D photoactive titania films and membranes.