Nikos Hadjichristidis - Böcker

The field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications.The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are introduced chapter by chapter in the book. In particular, the book also emphasizes the topic of synthetic breakthroughs by living/controlled polymerization since 2000.Furthermore, renowned authors contribute on special topics such as helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, which have attracted considerable interest as novel polymer materials with potential future applications. In addition, recent advances in reactive blending achieved with well-defined end-functionalized polymers are discussed from an industrial point of view. Topics on polymer-based nanotechnologies, including self-assembled architectures and suprastructures, nano-structured materials and devices, nanofabrication, surface nanostructures, and their AFM imaging analysis of hetero-phased polymers are also included. Provides comprehensive coverage of recently developed advanced architectural materialsCovers hot new areas such as: click chemistry; chain walking; polyhomologation; ADMETEdited by highly regarded scientists in the fieldContains contributions from 26 leading experts from Europe, North America, and AsiaResearchers in academia and industry specializing in polymer chemistry will find this book to be an ideal survey of the most recent advances in the area. The book is also suitable as supplementary reading for students enrolled in Polymer Synthetic Chemistry, Polymer Synthesis, Polymer Design, Advanced Polymer Chemistry, Soft Matter Science, and Materials Science courses.Color versions of selected figures can be found at www.wiley.com/go/hadjichristidis

Polymers may be classified as either homopolymers, consisting of one single repeating unit, or copolymers, consisting of two or more distinct repeating units. Block copolymers contain long contiguous blocks of two or more repeating units in the same polymer chain. Covering one of the hottest topics in polymer chemistry, Block Copolymers provides a coherent overview of the synthetic routes, physical properties, and applications of block copolymers.This pioneering text provides not only a guideline for developing synthetic strategies for creating block copolymers with defined characteristics, but also a key to the relationship between the physical properties of block copolymers and the structure and dynamics of materials. Covering features of the chemistry and physics of block copolymers that are not found in comparable texts, Block Copolymers illustrates the structure-activity relationship of block copolymers and offers suggestions for the design of specific applications. Divided into five sections-Block Copolymers includes chapters on:* Block Copolymers by Chemical Modification of Precursor Polymers* Nonlinear Block Copolymers* Adsorption of Block Copolymers at Solid-Liquid Interfaces* Theory of Block Copolymer Segregation* Phase Transformation Kinetics* Block Copolymer Morphology* Block Copolymer Dynamics Polymer chemists, physicists, chemical engineers, and materials scientists, as well as graduate students in polymer science, will find Block Copolymers to be an invaluable text.

Macromolecular Engineering Complete and Thorough Resource on Macromolecular Engineering for Researchers and Industry Professionals This book covers the entire field of macromolecular engineering, from design and preparation of well-defined macromolecules, to precise characterization, all the way to optimization for specific functions and applications. It provides background information, comparative advantages and limitations, the most recent advances of numerous synthetic approaches, characterization techniques, and potential applications. The second edition has been completely updated and edited by a world-class team of editors led by K. Matyjaszewski. Sample topics covered within the work include: Synthetic tools to precisely control various aspects of macromolecular structure including chain composition, microstructure, functionality, and topologyModern characterization techniques at the molecular and macroscopic level for various properties of well-defined (co)polymers in solution, bulk and at surfacesThe correlation of molecular structure with macroscopic properties additionally affected by processingSelf-healing polymers, renewable resources, photopolymerization, click chemistry, organocatalysis, hierarchical self-assembly, nanocarbon, and ionic liquidsPolymer chemists and engineers, materials scientists, and professionals in the plastics and pharmaceutical industries will be able to use Macromolecular Engineering as a completely comprehensive reference work to understand macromolecular engineering and its many practical applications.

This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.