Robert J. Gale - Böcker

It has been always an incentive for students to find out whether his or her efforts to solve exercises have provided correct results, or to find tips for problems that he or she finds more difficult. These are the main reasons for the appearance of this book. As part of the textbook "Modern Electrochemistry 1: Ionics", "A Guide to Problems in Modern Electrochemistry: Part 1: Ionics" compiles many of the solutions to the exercises and problems presented in the text, as well as many new problems.

The intention of this monograph has been to assimilate key practical and theoretical aspects of those spectroelectrochemical techniques likely to become routine aids to electrochemical research and analysis. Many new methods for interphasial studies have been and are being developed. Accordingly, this book is restricted in scope primarily to in situ methods for studying metal! electrolyte or semiconductor! electrolyte systems; moreover, it is far from inclusive of the spectroelectrochemical techniques that have been devised. However, it is hoped that the practical descriptions provided are sufficiently explicit to encourage and enable the newcomer to establish the experimental facilities needed for a particular problem. The chapters in this text have been written by international authorities in their particular specialties. Each chapter is broadly organized to review the origins and historical background of the field, to provide sufficiently detailed theory for graduate student comprehension, to describe the practical design and experimental methodology, and to detail some representative application examples. Since publication of Volume 9 of the Advances in Electrochemistry and Electrochemical Engineering series (1973), a volume devoted specifically to spectroelectrochemistry, there has been unabated growth of these fields. A number of international symposia-such as those held at Snowmass, Colorado, in 1978, the proceedings of which were published by North-Holland (1980); at Logan, Utah in 1982, published by Elsevier (1983); or at the Fritz Haber Institute in 1986-have served as forums for the discussion of nontraditional methods to study interphases and as means for the dissemination of a diversity of specialist research papers.

The physicist Kamerlingh Onnes, who was the first to liquify helium (1908), had written on the walls of his laboratory in Leiden: "From measur­ ing to knowing." As true as this is at very low temperatures, it is just as applicable at the high temperatures of molten salts. Only on the basis of exact measurements by a plethora of experimental methods can any real understanding be reached of both classes of liquids. In both temperature ranges experimental difficulties are much greater than those encountered around ambient temperature. Molten salts often present a formidable challenge to the experimen­ talist, for example, because of corrosion and other materials problems. Applications of molten salts were for a long time based on empirical knowledge alone. This was true for the first application of molten salts in 1807, when Davy obtained sodium and potassium by electrolysis of the molten hydroxides. For 100 years the winning of aluminum has been based on the very nearly simultaneous invention by Hall and Heroult (1886) of the electrolysis of molten cryolite. The process, though essentially unchanged, has since been perfected owing to an improvement in our understanding of what actually happens, based on difficult measurements ofthe many variables. However, even now there are gaps in our knowledge.