Cambridge Solid State Science Series – serie

The theory of how metals conduct electronically had for a long time been confined to metals that are crystalline with the constituent atoms in regular arrays. The discovery of how to make solid amorphous alloys led to an explosion of measurements of the electronic properties of these new materials, and the emergence of a range of interesting low temperature phenomena. This 1995 book describes in physical terms the theory of the electrical conductivity, Hall coefficient, magnetoresistance and thermopower of disordered metals and alloys. The author begins by showing how conventional Boltzmann theory can be extended and modified when the mean free path of the conduction electrons becomes comparable with their wavelength and interionic separation. The consequence of this is explored and the theory tested by application to experimental data on metallic glasses. Designed as a self-contained review, the book will appeal to non-specialist physicists, metallurgists and chemists with an interest in disordered metals.

This book provides an in-depth treatment of the instrumentation, physical bases and applications of X-ray photoelectron spectroscopy (XPS) and static secondary ion mass spectroscopy (SSIMS) with a specific focus on the subject of polymeric materials. XPS and SSIMS are widely accepted as the two most powerful techniques for polymer surface chemical analysis, particularly in the context of industrial research and problem solving. In this book, the techniques of XPS and SSIMS are described and in each case the author explains what type of information may be obtained. The book also includes details of case studies emphasising the complementary and joint application of XPS and SSIMS in the investigation of polymer surface structure and its relationship to the properties of the material. This book will be of value to academic and industrial researchers interested in polymer surfaces and surface analysis.

This book describes the properties and device applications of hydrogenated amorphous silicon. It covers the growth, the atomic and electronic structure, the properties of dopants and defects, the optical and electronic properties which result from the disordered structure and finally the applications of this technologically very important material. There is also an important chapter on contacts, interfaces and multilayers. The main emphasis of the book is on the new physical phenomena which result from the disorder of the atomic structure. The book will be of major importance to those who are researching or studying the properties and applications of a-Si:H. It will have a wider interest for anyone working in semiconductor physics and electronic engineering in general.

This book addresses the issue of designing the microstructure of fiber composite materials in order to obtain optimum performance. Besides the systematic treatment of conventional continuous and discontinuous fiber composites, the book also presents the state-of-the-art of the development of textile structural composites as well as the nonlinear elastic finite deformation theory of flexible composites. The author's experience during twenty years of research and teaching on composite materials is reflected in the broad spectrum of topics covered, including laminated composites, statistical strength theories of continuous fiber composites, short fiber composites, hybrid composites, two- and three-dimensional textile structural composites and flexible composites. This book provides the first comprehensive analysis and modeling of the thermo-mechanical behavior of fiber composites with these distinct microstructures. Overall, the inter-relationships among the processing, microstructures and properties of these materials are emphasized throughout the book. The book is intended as a text for graduate or advanced undergraduate students, but will also be an excellent reference for all materials scientists and engineers who are researching or working with these materials.

This 1997 book describes advances in the field of superplasticity. This is the ability of certain materials to undergo very large tensile strains, a phenomenon that has increasing commercial applications, but also presents a fascinating scientific challenge in attempts to understand the physical mechanisms that underpin it. The authors emphasise the materials aspects of superplasticity. They begin with a brief history of the phenomenon. This is followed by a description of the two major types of superplasticity - fine-structure and internal-stress superplasticity - together with a discussion of their operative mechanisms. In addition, microstructural factors controlling the ductility and fracture in superplastic materials are presented. The observations of superplasticity in metals (including aluminium, magnesium, iron, titanium and nickel), ceramics (including monoliths and composites), intermetallics (including iron, nickel, and titanium base), and laminates are thoroughly described. The technological and commercial applications of superplastic forming and diffusion bonding are presented and examples given.

This book is an authoritative and comprehensive account of the principles and practice of NMR spectroscopy of solids as applied to polymeric materials to determine their structure and dynamics at a molecular level. NMR spectroscopy has been applied to the characterization of polymers in solid state for over 40 years. The past few decades have seen the development of many new NMR capabilities, including high-resolution techniques for solids, multi-dimensional methods, deuterium NMR and others. All of these developments have contributed to a dramatic increase in the power and applicability of NMR for the characterization, at a molecular level, of the dynamics and structural organization of polymeric solids. The applications chapters emphasize the polymer types and properties. The authors have included an introduction to all the main principles of the technique involved in its application to solid polymers. Rigorous and detailed analytical treatment of all main areas is also available.

This book, first published in 2000, deals with the micromechanical characterization of polymer materials. Particular attention is given to microhardness as a technique capable of detecting a variety of morphological and textural changes in polymers. A comprehensive introduction to the microhardness of polymers is provided, including descriptions of the various testing methods in materials science and engineering. The book also includes the micromechanical study of glassy polymers and discusses the relevant aspects of microhardness of semicrystalline polymers. The volume also presents selected application examples of the microhardness technique for the characterization of polymeric materials, including the influence of polymer processing, the use in weathering tests, the characterization of modified polymer surfaces, and others. This book will be of use to graduate-level materials science students, as well as research workers in materials science, mechanical engineering and physics departments interested in the microindentation hardness of polymer materials.

The theory of how metals conduct electronically had for a long time been confined to metals that are crystalline with the constituent atoms in regular arrays. The discovery of how to make solid amorphous alloys led to an explosion of measurements of the electronic properties of these new materials, and the emergence of a range of interesting low temperature phenomena. This 1995 book describes in physical terms the theory of the electrical conductivity, Hall coefficient, magnetoresistance and thermopower of disordered metals and alloys. The author begins by showing how conventional Boltzmann theory can be extended and modified when the mean free path of the conduction electrons becomes comparable with their wavelength and interionic separation. The consequence of this is explored and the theory tested by application to experimental data on metallic glasses. Designed as a self-contained review, the book will appeal to non-specialist physicists, metallurgists and chemists with an interest in disordered metals.

This book was first published in 1980. A great number of metallic materials in practical use owe their strength to the presence in their microstructure of particles of a hard precipitated phase. The text emphasises the importance of scientific rather than empirical methods in attempting to develop particle-hardened alloys. The author progresses from an elementary knowledge of metallurgy to theories relating to the deformation and fracture of alloys of this type. He also discusses the use of such theories to describe observations on both model materials and practical metals. After a discussion of the microstructures of these alloys, how they form and how to describe them quantitatively, their deformation and fracture behaviour at both low and elevated temperatures are examined.

The aim of this 1981 book, designed for senior undergraduates, postgradutes and professionals, is to draw together in one unified presentation a number of the phenomena associated with polymer surfaces. The author begins by describing the theory of surface tension in terms of intermolecular forces and then goes on to consider the practical problem of the factors involved when a liquid wets a polymeric surface and forms a bond to it. An account of polymeric adhesives and their different spheres of application follows, and an examination of the mechanism of failure of adhesive joints leads to a discussion of joint design for optimum strength and environmental resistance. A chapter on friction is closely related to that on adhesion, and the final chapter is devoted to specific frictional mechanisms associated with high hysteresis polymers as well as an introductory discussion of wear.

The nature of the solid-liquid interface, the mechanism associated with its movement, and its preferential morphologies, impose important boundary conditions on the technology of crystal growth from the melt. This 1973 book sets out to describe these basic physical changes which underlie all of the important range of melt growth techniques irrespective of the special problems of individual materials and particular experimental techniques. It will be of particular value to senior undergraduates and graduate students of the science of materials. Dr Woodruff begins by considering Gibbs's 1878 work on the basic thermodynamics of an interface, and moves on to examine experimental aspects of the solid-liquid interfacial free energy. The theory of the morphological stability of the interface is also studied, along with the kinetics of crystal growth, and there is a useful chapter on eutectic growth. Throughout, the macroscopic properties of the materials under discussion are linked to relevant theory.

This book is an introduction to polymers and focuses on the synthesis, structure and properties of the individual molecules that constitute polymeric materials. It approaches polymeric materials from a molecular basis on the belief that there is a common core of knowledge and principles concerning polymer molecules that can be set out in an introductory work. Subjects treated include an introductory overview of synthesis, an introduction of the concept and definition of molecular weight and its distribution, experimental methods for measuring molecular weight, a more detailed view of polymerization including kinetics and mechanism, and the three-dimensional architecture of polymers as determined by conformation and stereochemistry. The statistical description of the conformational disorder of the molecules is covered and then built upon in treating rubber elasticity and polymer solutions.

This book provides an in-depth treatment of the instrumentation, physical bases and applications of X-ray photoelectron spectroscopy (XPS) and static secondary ion mass spectroscopy (SSIMS) with a specific focus on the subject of polymeric materials. XPS and SSIMS are widely accepted as the two most powerful techniques for polymer surface chemical analysis, particularly in the context of industrial research and problem solving. In this book, the techniques of XPS and SSIMS are described and in each case the author explains what type of information may be obtained. The book also includes details of case studies emphasising the complementary and joint application of XPS and SSIMS in the investigation of polymer surface structure and its relationship to the properties of the material. This book will be of value to academic and industrial researchers interested in polymer surfaces and surface analysis.

This book addresses the issue of designing the microstructure of fiber composite materials in order to obtain optimum performance. Besides the systematic treatment of conventional continuous and discontinuous fiber composites, the book also presents the state-of-the-art of the development of textile structural composites as well as the nonlinear elastic finite deformation theory of flexible composites. The author's experience during twenty years of research and teaching on composite materials is reflected in the broad spectrum of topics covered, including laminated composites, statistical strength theories of continuous fiber composites, short fiber composites, hybrid composites, two- and three-dimensional textile structural composites and flexible composites. This book provides the first comprehensive analysis and modeling of the thermo-mechanical behavior of fiber composites with these distinct microstructures. Overall, the inter-relationships among the processing, microstructures and properties of these materials are emphasized throughout the book. The book is intended as a text for graduate or advanced undergraduate students, but will also be an excellent reference for all materials scientists and engineers who are researching or working with these materials.

McKeever gives us a comprehensive survey of thermoluminescence, an important, versatile, and widely used experimental technique. Bringing together previously isolated specialized approaches, he stresses the importance of the solid state aspects of the phenomenon. The book contains chapters on analysis and special properties, on instrumentation, and on the variety of defect reaction - using the alkali halides and SiO2 as examples - that can take place within a material to yield thermoluminescence. Three chapters concerning applications discuss the features of the solid state reactions to expain some of the properties observed in practice.

This book describes the properties and device applications of hydrogenated amorphous silicon. It covers the growth, the atomic and electronic structure, the properties of dopants and defects, the optical and electronic properties which result from the disordered structure and finally the applications of this technologically very important material. There is also an important chapter on contacts, interfaces and multilayers. The main emphasis of the book is on the new physical phenomena which result from the disorder of the atomic structure. The book will be of major importance to those who are researching or studying the properties and applications of a-Si:H. It will have a wider interest for anyone working in semiconductor physics and electronic engineering in general.

Modern technology depends on materials with precisely controlled properties. Ion beams are a favoured method to achieve controlled modification of surface and near-surface regions. In every integrated circuit production line, for example, there are ion implantation systems. In addition to integrated circuit technology, ion beams are used to modify the mechanical, tribological and chemical properties of metal, intermetallic and ceramic materials without altering their bulk properties. Ion-solid interactions are the foundation that underlies the broad application of ion beams to the modification of materials. This text is designed to cover the fundamentals and applications of ion-solid interactions and is aimed at graduate students and researchers interested in electronic devices, surface engineering, reactor and nuclear engineering and material science issues associated with metastable phase synthesis.

Now in paperback, this comprehensive book is the first text devoted to the problem of understanding the electrical properties of metals and alloys. Dr Rossiter, well-known for his work on the electrical resistivity of alloys, has written a book which blends results and theory, but does not rely on a strong grounding in quantum mechanics. After an introduction to the basic ideas, the concepts of atomic and magnetic correlations and their microstructural consequences are explained. Later chapters then deal with the effects of such correlations on electrical resistivity. Examples and applications of the concepts derived are given in discrete sections, allowing the uninterrupted development of theory for each specific problem, and enhancing the value of the book for a wide range of readers from theoretical and experimental solid state physicists to metallurgists and materials scientists. Anyone with an interest in the electrical conduction process or in the application of resistivity measurements to the study of alloy configuration will find this essential reading.

This is an advanced text for higher degree materials science students and researchers concerned with the strength of highly brittle covalent-ionic solids, principally ceramics. It is a reconstructed and greatly expanded edition of a book first published in 1975. The book presents a unified continuum, microstructural and atomistic treatment of modern day fracture mechanics from a materials perspective. Particular attention is directed to the basic elements of bonding and microstructure that govern the intrinsic toughness of ceramics. These elements hold the key to the future of ceramics as high-technology materials - to make brittle solids strong, we must first understand what makes them weak. The underlying theme of the book is the fundamental Griffith energy-balance concept of crack propagation. The early chapters develop fracture mechanics from the traditional continuum perspective, with attention to linear and nonlinear crack-tip fields, equilibrium and non-equilibrium crack states. It then describes the atomic structure of sharp cracks, the topical subject of crack-microstructure interactions in ceramics, with special focus on the concepts of crack-tip shielding and crack-resistance curves, and finally deals with indentation fracture, flaws, and structural reliability.

This book describes the theory and practice of infrared and Raman spectroscopy as applied to the study of the physical and chemical characteristics of polymers. Its purpose is to give the beginning researcher in the field a firm foundation and a starting point for the study of more-advanced literature. To this end the book concentrates on the fundamentals of the theory and nomenclature, and on the discussion of well-documented illustrations of these fundamental principles, including many now-classic studies in the subject. No previous knowledge of either polymers or vibrational spectroscopy is assumed. The book will be of value to anyone beginning research on the vibrational spectroscopy of polymers, either from a physics or a chemistry background. It is intended to be especially suitable for use in undergraduate courses in physics, chemistry or materials science at both universities and polytechnics.

The second edition of this textbook, popular amongst students and faculty alike, investigates the various causes of thermodynamic instability in metallic microstructures. Materials theoretically well designed for a particular application may prove inefficient or even useless unless stable under normal working conditions. The authors examine current experimental and theoretical understanding of the kinetics behind structural change in metals. The entire text has been updated in this new edition, and a completely new chapter on highly metastable alloys has been added. The degree to which kinetic stability of the material outweighs its thermodynamic instability is very important, and dictates the useful working life of the material. If the structure is initially produced to an optimum, such changes will degrade the properties of the material. This comprehensive and well-illustrated text, accompanied by ample references, will allow final year undergraduates, graduate students and research workers to investigate in detail the stability of microstructure in metallic systems.

This is a fully revised and expanded edition of a very successful and widely used book. It describes the physical basis of all the principal, and most of the more specialised, techniques currently employed in the study of well-characterised solid surfaces. The coverage of each technique, illustrated with selected examples, is underpinned by discussion of the relevant physical principles, and the complementary aspects of the various methods are also described. Throughout, the emphasis is on understanding the concepts involved, rather than on an exhaustive review of applications. The book will be of great use to final year undergraduate and postgraduate students in physics, chemistry and materials science. It will also be valuable to established researchers in any area of surface science concerned with the acquisition and analysis of experimental data.

Metal matrix composites constitute a new class of materials, now starting to make a major industrial impact in fields as diverse as aerospace, automotives and electronics. This book gives a comprehensive, integrated coverage of these materials, including the background to analytical-, experimental-, production and application-oriented aspects. Clear pictorial descriptions are given of the basic principles governing various properties and characteristics; these encompass mechanical, thermal, electrical, environmental and wear behaviour. Coverage also extends to material processing and component fabrication aspects and to a survey of commercial usage. This book is aimed primarily at scientists, engineers, production managers and all those involved in research on new materials in general, and metal matrix composites in particular, but may also be suitable for use as a text in beginning graduate and advanced undergraduate courses.

In this new edition of their classic work on Cellular Solids, the authors have brought the book completely up to date, including new work on processing of metallic and ceramic foams and on the mechanical, electrical and acoustic properties of cellular solids. Data for commercially available foams are presented on material property charts; two new case studies show how the charts are used for selection of foams in engineering design. Over 150 references appearing in the literature since the publication of the first edition are cited. The text summarises current understanding of the structure and mechanical behaviour of cellular materials, and the ways in which they can be exploited in engineering design. Cellular solids include engineering honeycombs and foams (which can now be made from polymers, metals, ceramics and composites) as well as natural materials, such as wood, cork and cancellous bone.

This 1997 book describes advances in the field of superplasticity. This is the ability of certain materials to undergo very large tensile strains, a phenomenon that has increasing commercial applications, but also presents a fascinating scientific challenge in attempts to understand the physical mechanisms that underpin it. The authors emphasise the materials aspects of superplasticity. They begin with a brief history of the phenomenon. This is followed by a description of the two major types of superplasticity - fine-structure and internal-stress superplasticity - together with a discussion of their operative mechanisms. In addition, microstructural factors controlling the ductility and fracture in superplastic materials are presented. The observations of superplasticity in metals (including aluminium, magnesium, iron, titanium and nickel), ceramics (including monoliths and composites), intermetallics (including iron, nickel, and titanium base), and laminates are thoroughly described. The technological and commercial applications of superplastic forming and diffusion bonding are presented and examples given.

This book is an introduction to polymers and focuses on the synthesis, structure and properties of the individual molecules that constitute polymeric materials. It approaches polymeric materials from a molecular basis on the belief that there is a common core of knowledge and principles concerning polymer molecules that can be set out in an introductory work. Subjects treated include an introductory overview of synthesis, an introduction of the concept and definition of molecular weight and its distribution, experimental methods for measuring molecular weight, a more detailed view of polymerization including kinetics and mechanism, and the three-dimensional architecture of polymers as determined by conformation and stereochemistry. The statistical description of the conformational disorder of the molecules is covered and then built upon in treating rubber elasticity and polymer solutions.

This book is a comprehensive introduction to the mechanical properties of ceramics, and is designed primarily as a textbook for undergraduate and graduate students in materials science and engineering. Over the past 25 years ceramics have become key materials in the development of many new technologies as scientists have been able to design these materials with new structures and properties. An understanding of the factors that influence their mechanical behavior and reliability is essential. This book will introduce the reader to current concepts in the field. It contains problems and exercises to help readers develop their skills. Although designed principally as a textbook for advanced undergraduates and graduate students, this book will also be of value as a supplementary text for more general courses and to industrial scientists and engineers involved in the development of ceramic-based products, materials selection and mechanical design.

Modern technology depends on materials with precisely controlled properties. Ion beams are a favoured method to achieve controlled modification of surface and near-surface regions. In every integrated circuit production line, for example, there are ion implantation systems. In addition to integrated circuit technology, ion beams are used to modify the mechanical, tribological and chemical properties of metal, intermetallic and ceramic materials without altering their bulk properties. Ion-solid interactions are the foundation that underlies the broad application of ion beams to the modification of materials. This text is designed to cover the fundamentals and applications of ion-solid interactions and is aimed at graduate students and researchers interested in electronic devices, surface engineering, reactor and nuclear engineering and material science issues associated with metastable phase synthesis.

The field of matter transport is central to understanding the processing of materials and their subsequent mechanical properties. While thermodynamics determines the final state of a material system, it is the kinetics of mass transport that governs how it gets there. This book, first published in 2000, gives a solid grounding in the principles of matter transport and their application to a range of engineering problems. The author develops a unified treatment of mass transport applicable to both solids and liquids. Traditionally matter transport in fluids is considered as an extension of heat transfer and can appear to have little relationship to diffusion in solids. This unified approach clearly makes the connection between these important fields. This book is aimed at advanced undergraduate and beginning graduate students of materials science and engineering and related disciplines. It contains numerous worked examples and unsolved problems. The material can be covered in a one semester course.