Chemical Industries – serie

The third edition of Bubbles, Drops, and Particles in Non-Newtonian Fluids provides comprehensive coverage of the scientific foundations and the latest advances in particle motion in non-Newtonian media.Thoroughly updating and expanding its best-selling predecessor, this edition addresses numerical and experimental developments in non-Newtonian particulate systems. It includes a new chapter on heat transfer in non-Newtonian fluids in the free and mixed convection regimes and thus covers forced convection regimes separately in this edition.Salient Features:Demonstrates how dynamic behavior of single particles can yield useful information for modeling transport processes in complex multiphase flowsAddresses heat transfer in Generalized Newtonian Fluid (GNF), visco-plastic and visco-elastic fluids throughout the book and outlines potential strategies for heat transfer enhancementProvides a new detailed section on the effect of confinement on heat transfer from bluff-bodies in non-Newtonian fluidsWritten in a clear and concise manner, this book remains an excellent handbook and reference. It is essential reading for students and researchers interested in exploring particle motion in different types of non-Newtonian systems encountered in disciplines across engineering and the sciences.

Introduction to Process Control, Third Edition continues to provide a bridge between traditional and modern views of process control by blending conventional topics with a broader perspective of integrated process operation, control, and information systems. Updated and expanded throughout, this third edition addresses issues highly relevant to today’s teaching of process control: Discusses smart manufacturing, new data preprocessing techniques, and machine learning and artificial intelligence concepts that are part of current smart manufacturing decisions Includes extensive references to guide the reader to the resources needed to solve modeling, classification, and monitoring problems Introduces the link between process optimization and process control (optimizing control), including the effect of disturbances on the optimal plant operation, the concepts of steady-state and dynamic back-off as ways to quantify the economic benefits of control, and how to determine an optimal transition policy during a planned production change Incorporates an introduction to the modern architectures of industrial computer control systems with real case studies and applications to pilot-scale operations Analyzes the expanded role of process control in modern manufacturing, including model-centric technologies and integrated control systems Integrates data processing/reconciliation and intelligent monitoring in the overall control system architectureDrawing on the authors’ combined 60 years of teaching experiences, this classroom-tested text is designed for chemical engineering students but is also suitable for industrial practitioners who need to understand key concepts of process control and how to implement them. The text offers a comprehensive pedagogical approach to reinforce learning and presents a concept first followed by an example, allowing students to grasp theoretical concepts in a practical manner and uses the same problem in each chapter, culminating in a complete control design strategy. A vast number of exercises throughout ensure readers are supported in their learning and comprehension.Downloadable MATLAB® toolboxes for process control education as well as the main simulation examples from the book offer a user-friendly software environment for interactively studying the examples in the text. These can be downloaded from the publisher’s website. Solutions manual is available for qualifying professors from the publisher.

"Covers the chemistry, process chemistry, technology, engineering, and economics of methane conversion, including its environmental impact and commercial exploitation. Begins with methane's availability and increasing importance as an environmentally acceptable natural resource alternative and feedstock."

"Examines all known industrial processes using shape selective zeolites. Second Edition contains new, up-to-date information on the specific features that make zeolites shape selective, the role shape selective catalysis can play providing environmentally clean fuels, 12-membered oxygen ring systems, mesopore systems, and more."

This work provides a practical, step-by-step guide to the preparation, production and operation of all commercially used catalysts, taking into account general safety considerations and up-to-date regulations from the Occupational Health Administration and the Environmental Protection Agency. This second edition contains updated and expanded material on the regeneration, reactivity and recovery of used catalysts; problems related to environmental catalysis; a unique CO oxidation catalyst; and more.;This work is intended for chemical, plant, automotive, petroleum, fuel and design engineers; and upper-level graduate and graduate students in these disciplines.

This work is based on the proceedings of the American Institute of Chemical Engineers' Spring National Meeting in Houston, Texas, March 28 to April 1, 1993. It details various facets of residue upgrading and distillate hydrotreating, stressing the importance of selective catalysts in aromatics reduction. New aromatics saturation processes for the production of very low-aromatic distillates are introduced.

This volume provides an overview of the applications of modern solid-state nuclear magnetic resonance (NMR) techniques to the study of catalysts, catalytic processes, species adsorbed on catalysts and systems relevant to heterogeneous catalysis. It characterizes the structure of catalytic materials and surfaces.

This volume is a collection of the papers presented at the Twelfth Conference on the Catalysis of Organic Reactions, where all phases of catalysis, including heterogeneous catalytic hydrogenation, catalytic oxidation, homogeneous catalysis, carbonylation, and amination have been discussed.

Addressing key issues in the instrumentation of powder handling processes, this up-to-date volumeserves as an excellent source of new ideas for designing on-line instruments, as well as a helpfulguide for understanding and applying measurement principles.Describing physical and chemical principles in clear, simple language, Powder and BulkSolids Handling Processes provides substantial background material that lists related industrialfields and the physical representation of powder properties . . . focuses on instrumentation,reviewing state variables in powder processes . . . discusses the sampling of particles from apowder bed or suspension flow as a basic method for evaluating powder handling processes ... andpresents incisive information on various methods and instruments used for on-line measurement ofpowder flow rate, particle concentration in suspension, level of powder in storage vessels, andmore.Complete with references, equations, illustrations, and tables, this volume is essential reading forchemical, mechanical, systems, ceramic, and civil engineers, instrumentation engineers in powderand bulk solid processes, and upper-level undergraduate and graduate students in chemical andmechanical engineering.

This book discusses the mechanisms that have been proposed for the main corrosion phenomena, providing a thorough discussion of the pros and cons of the various corrosion mechanisms with support by experimental and theoretical results.

This guide discusses the principles and theory of temperature-programmed reduction (TPR) used for sold materials characterization. It describes the recent trends, instrumentation needed, as well as the application of TPR in heterogeneous catalysis, materials science, and analytical chemistry.

The most comprehensive and up-to-date survey of five industrially important areas ofcatalysis, Catalysis and Surface Science focuses on chemicals from methanol ... hydrotreatingof hydrocarbons . . . catalyst preparation ... monomers and polymers ... andphotocatalysis and photovoltaics.In each of these significant topics, this useful collection of articles traces state-of-the-artdevelopments in fundamental science ... in current exploratory and applied research ...and in current technology. It outlines future trends in catalytic research and technology,and gathers together and synthesizes-into one, single, handy reference-the informationcontained in voluminous, widely scattered articles, books, and patents. As added referencefeatures, this authoritative source provides a wealth of illustrations, including photographs,charts, tables, and line drawings .. . plus useful, detailed bibliographies for further research.Written by 32 leading authorities on all aspects of catalysis, Catalysis and Surface Scienceis essential reading for chemical, industrial process, petrochemical, and electronicengineers, as well as industrial, polymer, and materials chemists. It is also a useful text forgraduate students in chemistry and chemical engineering.

The author of this bestselling handbook introduces readers to the science and technology of petroleum, beginning with its formation in the ground and culminating in the production of a wide variety of products and petrochemical intermediates. The new edition has been updated with the latest developments in the refining industry, including new processes as well as updates on evolving processes and various environmental regulations. The book contains figures and tables, including chemical structures and process flow sheets making it a useful reference for scientists and engineers in the petroleum industry as well as in the catalyst manufacturing industry.Key Features:Covers new approaches to optimize efficiency and throughoutDiscusses the environmental aspects of refiningExamines the changing character of refinery feedstocksAddresses changes in product specifications due to environmental regulations

Petroleum refining involves refining crude petroleum as well as producing raw materials for the petrochemical industry. This book covers current refinery processes and process-types that are likely to come on-stream during the next three to five decades. The book includes (1) comparisons of conventional feedstocks with heavy oil, tar sand bitumen, and bio-feedstocks; (2) properties and refinability of the various feedstocks; (3) thermal processes versus hydroprocesses; and (4) the influence of refining on the environment.

Handbook of Refinery Desulfurization describes the operation of the various desulfurization process units in a petroleum refinery. It also explains the processes that produce raw materials for the petrochemical industry. It illustrates all the possible processes to lower the sulfur contents in petroleum and its fractions to decrease emissions of sulfur oxides.This book introduces you to desulfurization concepts, including biodesulfurization, as well as technology, giving guidance on how to accomplish desulfurization in various refining processes. It contains background chapters on the composition and evaluation of feedstocks and includes diagrams and tables of feedstocks and their respective produce. It also outlines how to decide which method should be employed to remove sulfur from different feedstocks.A practical and thorough discussion of the field, Handbook of Refinery Desulfurization gives you a strong grasp of the various processes involved with industrial desulfurization while giving you pointers on which procedures to use under certain conditions.

The supply of petroleum continues to dwindle at an alarming rate, yet it is the source of a range of products — from gasoline and diesel to plastic, rubber, and synthetic fiber. Critical to the future of this commodity is that we learn to use it more judiciously and efficiently. Fundamentals of Petroleum and Petrochemical Engineering provides a holistic understanding of petroleum and petrochemical products manufacturing, presented in a step-by-step sequence of the entire supply chain.Filled with crucial information relevant to a range of applications, the book covers topics such as: The essential preliminaries for the exploration and production of crude petroleum oil and gasAnalysis of crude oil and its petroleum productsThe processing of petroleum in refineriesThe fundamentals of lubricating oil and greasePetrochemicals — their raw materials and end products, and manufacturing principles of industrially important productsTheories and problems of unit operations and the processes involved in refineries and petrochemical plantsAutomatic operations in plantsStart up, shutdown, maintenance, fire, and safety operationsCommercial and managerial activities necessary for the ultimate success of a refining or manufacturing business Due to the advancement of technology, new petrochemicals are being invented and will continue to be relevant to the petroleum industry in the near future. Those entering the industry need a firm grasp of the basics as the field continues to open up new avenues of possibility, while at the same time being cognizant of the challenges that exist through the heightened focus on sustainable energy.

Rising oil costs have stimulated significant interest in the Fischer-Tropsch synthesis (FTS) as a method for producing a synthetic petroleum substitute. Drawn from the proceedings at a symposium held during the 236th meeting of the American Chemical Society in Philadelphia in August 2008, Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis explores the recent developments in Fischer-Tropsch technology, which holds great promise in the area of renewable resources.Expert contributors explore a range of issuesThe book focuses on three main themes: catalyst preparation and activation, reaction mechanism, and process-related topics. A panel of expert contributors discusses synthesis of catalysts, carbon nanomaterials, nitric oxide calcinations, the influence of carbon, catalytic performance issues, chelating agents, and Cu and alkali promoters. They also explore Co/silica catalysts, thermodynamic control, the Two Alpha model, co-feeding experiments, internal diffusion limitations, Fe-LTFT selectivity, and the effect of co-fed water. Lastly, the book examines cross-flow filtration, kinetic studies, reduction of CO2 emissions, syncrude, and low-temperature water-gas shift.Attaining the maximum catalytic activity and catalyst lifeThe themes explored in the book demonstrate that while the Fischer-Tropsch synthesis (FTS) has advanced in maturity, many issues remain concerning the preparation of increasingly active catalysts and the method of activation to attain the maximum catalytic activity and catalyst life. The book includes coverage of the structural features, their changes, and the application of increasingly sophisticated characterization techniques, shedding light on the reaction mechanism and providing a glimpse into the processes and reaction rates under realistic commercial process conditions.

Although there is a shortage of light petroleum, there is plenty of heavy petroleum rich in macromolecules available, creating an increasing interest for processes that can convert heavy oils to light oils. Process Chemistry of Petroleum Macromolecules provides the scientific basis for such processes, presenting methods to determine improvement potential. Topics include characterization, thermal kinetics, phase behavior, and separation. Revealing that the science of petroleum macromolecules is simpler and more exciting than imagined, it also discusses macromolecules that self-associate, liquid crystalline phases, reactions triggered by phase separation, and both dispersed and dissolved solutes.

With mounting pressure to extract petroleum from oil sands and other unconventional sources, oil refineries must adapt their processing methods to handle increasingly heavy crude oils. Unlike traditional crude oils, the properties of heavier crude oils include higher viscosity, metal, salt, and acid content. This causes their interfacial properties to deteriorate, leading to problems such as sedimentation, foaming, emulsification, rust, and corrosion—all of which make the manufacture, transportation, and storage of petroleum products more difficult.Interfacial Properties of Petroleum Products examines conventional and non-conventional processing techniques for crude oils and documents their effects on the composition and properties of petroleum products at the oil/solid, oil/air, oil/water and oil/metal interfaces. Focusing on surface activity, the author examines the undesirable effects of processes such as solvent extraction, desalting, dewaxing, catalyst deactivation, and hydroprocessing as well as trace element and water contamination. With each process, the author presents methods for improving interfacial properties, including the use of surface-active additives, demulsifiers, antifoaming agents, and corrosion/rust inhibitors. A distinctive and up-to-date source of materials published together for the first time, Interfacial Properties of Petroleum Products will help engineers design more cost-effective and resource-efficient processing methods for heavier crude oils, based on the properties of the crude oil extracted.

Advances in processing methods are not only improving the quality and yield of lubricant base stocks, they are also reducing the dependence on more expensive crude oil starting materials. Process Chemistry of Lubricant Base Stocks provides a comprehensive understanding of the chemistry behind the processes involved in petroleum base stock production from crude oil fractions.This book examines hydroprocessing technologies that, driven by the demand for higher performance in finished lubricants, have transformed processing treatments throughout the industry. The author relates the properties of base stocks to their chemical composition and describes the process steps used in their manufacture. The book highlights catalytic processes, including hydrocracking, hydrofinishing, and catalytic dewaxing. It also covers traditional solvent-based separation methods used to remove impurities, enhance performance, and improve oxidation resistance. The final chapters discuss the production of Food Grade white oils and paraffins and the gas-to-liquids processes used to produce highly paraffinic base stocks via Fischer-Tropsch chemistry. Process Chemistry of Lubricant Base Stocks provides historical and conceptual background to the technologies used to make base stocks, thorough references, and a unique emphasis on chemical, not just engineering, aspects of lubricant processing—making this book an ideal and practical reference for scientists across a wide range of disciplines.

Many oil refineries employ hydroprocessing for removing sulfur and other impurities from petroleum feedstocks. Capable of handling heavier feedstocks than other refining techniques, hydroprocessing enables refineries to produce higher quality products from unconventional — and formerly wasted — sources. Hydroprocessing of Heavy Oils and Residua illustrates how to obtain maximum yields of high-value products from heavy oils and residue using hydroprocessing technologies.While most resources on hydroprocessing concentrate ongas oil and lower boiling products, this book details the chemistry involved and the process modifications required for the hydroprocessing of heavy crude oils and residua. Emphasizing the use of effective catalysts to ensure cleaner and more efficient industrial fuel processes, the book presents key principles of heterogeneous catalyst preparation, catalyst loading, and reactor systems. It explains how to evaluate and account for catalysts, reactor type, process variables, feedstock type, and feedstock composition in the design of hydroprocessing operations. The text concludes with examples of commercial processes and discusses methods of hydrogen production. To meet the growing demand for transportation fuels and fuel oil, modern oil refineries must find ways to produce high quality fuel products from increasingly heavy feedstocks. Hydroprocessing of Heavy Oils and Residua contains the fundamental concepts, technologies, and process modifications refineries need to adapt current hydroprocessing technologies for processing heavier feedstocks.

Interest in structured catalysts is steadily increasing due to the already proven, as well as potential, advantages of these catalysts. Updating the comprehensive coverage of the first edition published in 1998 with the latest science and applications, Structured Catalysts and Reactors, Second Edition gives detailed information on all aspects of structured catalysts and reactors, including: materials, mass transfer, selectivity, activity, and stability; catalyst preparation, design, and characterization; process development; modeling and optimization; reactor design; and operation costs and considerations.The book first examines how monolithic catalysts are used to clean exhaust gas from gasoline engines, treat industrial off-gases, burn fuels in commercial settings, and synthesize chemicals in two- and three-phase processes. It discusses configurations, microstructure, physical properties, and manufacture of ceramic and metallic monoliths before directing its focus to arranged catalysts and structured packings in terms of mass transfer. The book then explores catalytically active membranes and filters, featuring metallic membranes, permeation mechanisms, preparation and modeling, commercial membranes, and the latest applications, such as zeolitic membranes. Finally, several chapters present techniques for incorporating catalytic species into the structured catalyst support and controlling catalyst nanoporosity. This book conveys the scientific as well as economic advantages of using these unconventional catalytic techniques. With over 1500 references, tables, drawings, and photographs, as well as in-depth discussions and a new approach to catalytic processes, Structured Catalysts and Reactors, Second Edition is an essential reference for anyone working with or studying catalysis.

In the past two decades, new modeling efforts have gradually incorporated more molecular and structural detail in response to environmental and technical interests. Molecular Modeling in Heavy Hydrocarbon Conversions introduces a systematic molecule-based modeling approach with a system of chemical engineering software tools that can automate the entire model building, solution, and optimization process.Part I shows how chemical engineering principles provide a rigorous framework for the building, solution, and optimization of detailed kinetic models for delivery to process chemists and engineers. Part II presents illustrative examples that apply this approach to the development of kinetic models for complex process chemistries, such as heavy naphtha reforming and gas oil hydroprocessing.Molecular Modeling in Heavy Hydrocarbon Conversions develops the key tools and best possible approaches that process chemists and engineers can use to focus on the process chemistry and reaction kinetics for performing work that is repetitive or prone to human-error accurately and quickly.

Polymer Processing Instabilities: Control and Understanding offers a practical understanding of the various flows that occur during the processing of polymer melts. The book pays particular attention to flow instabilities that affect the rate of production and the methods used to prevent and eliminate flow instabilities in order to increase production rates and enhance manufacturing efficiency.Polymer Processing Instabilities: Control and Understanding summarizes experimental observations of flow instabilities that occur in numerous processing operations such as extrusion, injection molding, fiber spinning, film casting, and film blowing for a wide range of materials, including most commodity polymers that are processed as melts at temperatures above their melting point or as concentrated solutions at lower temperatures. The book first presents the fundamental principles in rheology and flow instabilities. It relates the operating conditions with flow curves, the critical wall shear stress for the onset of the instabilities, and new visualization techniques with numerical modeling and molecular structure. It reviews one-dimensional phenomenological relaxation/oscillation models describing the experimental pressure and flow rate oscillations, analyzes the gross melt fracture (GMF) instability, and examines how traditional and non-traditional processing aids eliminate melt fracture and improve polymer processability. It supplies a numerical approach for the investigation of the linear viscoelastic stability behavior of simplified injection molding flows and examines a newly discovered family of instabilities that occur in co-extrusion.Polymer Processing Instabilities: Control and Understanding is unique in that it fills a gap in the polymer processing literature where polymer flow instabilities are not treated in-depth in any book. It summarizes state-of-the-art developments in the field, particularly those of the last ten years, and contains significant data based on this research.

Catalytic Naphtha Reforming, Second Edition presents modern, crystal-clear explanations of every aspect of this critical process for generating high-octane reformate products for gasoline blending and production of benzene, toluene, and xylene (BTX) aromatics. The book details the chemistry of naphtha reforming, the preparation and characterization of catalysts, and the very latest commercial technologies and industrial applications. With more than 300 tables and figures, it addresses the development of new catalysts and revamp process improvements propelled by regulations on sulfur, benzene, and oxygenate content in gasoline and refinery pressure to maximize utilization of existing assets.

To meet changing market demands that have stringent emission standards and to ensure proper performance in refinery units, evaluation of novel catalyst designs and results from material characterization and testing of catalysts are of crucial importance for refiners as well as for catalyst manufacturers. This book highlights recent developments in the application of refinery catalysts in selected units such as fluid catalytic cracking (FCC), hydrogen production for hydroprocessing units, hydrotreating, hydrocracking, and sustainable processing of biomass into biofuels.

This reference details particle characterization, dynamics, manufacturing, handling, and processing for the employment of multiphase reactors, as well as procedures in reactor scale-up and design for applications in the chemical, mineral, petroleum, power, cement and pharmaceuticals industries. The authors discuss flow through fixed beds, elutriation and entrainment, gas distributor and plenum design in fluidized beds, effect of internal tubes and baffles, general approaches to reactor design, applications for gasifiers and combustors, dilute phase pneumatic conveying, and applications for chemical production and processing. This is a valuable guide for chemists and engineers to use in their day-to-day work.

Presenting strategies in control policies, this text uses a systems theory approach to predict, simulate and streamline plant operation, conserve fuel and resources, and increase workplace safety in the manufacturing, chemical, petrochemical, petroleum, biochemical and energy industries. Topics of discussion include system theory and chemical/biochemical engineering systems, steady state, unsteady state, and thermodynamic equilibrium, modeling of systems, fundamental laws governing the processes in terms of the state variables, different classifications of physical models, the story of chemical engineering in relation to system theory and mathematical modeling, overall heat balance with single and multiple chemical reactions and single and multiple reactions.

Interest in structured catalysts is steadily increasing due to the already proven, as well as potential, advantages of these catalysts. Updating the comprehensive coverage of the first edition published in 1998 with the latest science and applications, Structured Catalysts and Reactors, Second Edition gives detailed information on all aspects of structured catalysts and reactors, including: materials, mass transfer, selectivity, activity, and stability; catalyst preparation, design, and characterization; process development; modeling and optimization; reactor design; and operation costs and considerations.The book first examines how monolithic catalysts are used to clean exhaust gas from gasoline engines, treat industrial off-gases, burn fuels in commercial settings, and synthesize chemicals in two- and three-phase processes. It discusses configurations, microstructure, physical properties, and manufacture of ceramic and metallic monoliths before directing its focus to arranged catalysts and structured packings in terms of mass transfer. The book then explores catalytically active membranes and filters, featuring metallic membranes, permeation mechanisms, preparation and modeling, commercial membranes, and the latest applications, such as zeolitic membranes. Finally, several chapters present techniques for incorporating catalytic species into the structured catalyst support and controlling catalyst nanoporosity. This book conveys the scientific as well as economic advantages of using these unconventional catalytic techniques. With over 1500 references, tables, drawings, and photographs, as well as in-depth discussions and a new approach to catalytic processes, Structured Catalysts and Reactors, Second Edition is an essential reference for anyone working with or studying catalysis.