Handbook of Functionalized Nanomaterials for Industrial Applications

Prof. Chaudhery Mustansar Hussain, PhD, is an adjunct professor and director of laboratories in the Department of Chemistry & Environmental Sciences at the New Jersey Institute of Technology (NJIT), Newark, New Jersey, United States. His research focuses on sustainability, the applications of nanotechnology and advanced materials, environmental management, analytical chemistry and other various industries. Dr. Hussain is the author of numerous papers in peer-reviewed journals as well as a prolific author and editor of around 200 books, including scientific monographs and handbooks in his research areas. He has published with ELSEVIER, American Chemical Society, Royal Society of Chemistry, John Wiley & Sons, CRC Press, and Springer.

• List of contributors Preface Section 1Different kinds of functionalized nanomaterial forindustrial use nanomaterials1. Functionalization of nanomaterials for industrialapplications: recent and future perspectives Sukanchan Palit and Chaudhery Mustansar Hussain1.1 Introduction 1.2 The vision of the study 1.3 Nanotrends in industrial development 1.4 Potential of nanomaterials 1.5 What are functionalized nanomaterials? 1.6 The use of functionalized nanomaterials in industry 1.7 Current research on nanomaterials 1.8 Recent scientific research in the field of functionalizednanomaterials 1.9 The scientific vision of energy and environmentalsustainability 1.10 Recent research in environmental protection and industrialecology 1.11 Integrated water resource management and human factorengineering 1.12 Groundwater remediation and nanotechnology 1.13 Future research trends in nanotechnology and nanomaterials 1.14 Conclusion and future perspectives References Further reading 2. Mixed-matrix membranes incorporated withfunctionalized nanomaterials for water applications Woon-Chan Chong, Chai-Hoon Koo and Woei-Jye Lau2.1 Introduction 2.2 Mixed-matrix membranes incorporated with carbon-basednanomaterials 2.3 Mixed-matrix membranes incorporated with titania-basednanomaterials 2.4 Mixed-matrix membranes incorporated with othernanomaterials 2.5 Adsorptive mixed-matrix membranes for heavy-metal removal 2.6 Conclusion and future remarks References Section 2Functionalized nanomaterial for catalysis industry3. Photocatalytic oxygen evolution reaction for energyconversion and storage of functional nanomaterials K. Kaviyarasu, C. Maria Magdalane, A. Raja, N. Matinise,N. Mayedwa, N. Mongwaketsi, Douglas Letsholathebe, G.T. Mola,Naif AbdullahAl-Dhabi, Mariadhas Valan Arasu, G. Ramalingam,S.B. Mohamed, Abdulgalim B. Isaev, K. Kanimozhi, A.K.H. Bashir,J. Kennedy and M. Maaza3.1 Introduction 3.2 Conclusion References 4. Functionalized metal-based nanoelectrocatalystsfor water splitting R.M.P.I. Rajakaruna and I.R. Ariyarathna4.1 Introduction 4.2 Functionalized nanoelectrocatalysts for HER 4.3 OER catalysts 4.4 Bifunctional electrocatalysts 4.5 Summary References 5. Functionalized nanographene for catalysis Santosh Bahadur Singh and Chaudhery Mustansar Hussain5.1 Nanographene: an introduction 5.2 Functionalization of nanographene 5.3 Catalytic properties and applications of functionalizednanographene 5.4 Industrial, environmental, and health issues of nanographene 5.5 Conclusions and future aspects References Section 3Functionalized nanomaterials for biomedical,pharmaceutical, agriculture, and agri-food industrySection Functionalized nanomaterial and biology6. Biocompatible nanodelivery systems for thedelivery of bioactive compounds H. Turasan and J.L. Kokini6.1 Introduction 6.2 Fabrication methods of biopolymer-based nanodeliverysystems 6.3 Conclusions References 7. Biopolymer-based nanomaterials for food, nutrition,and healthcare sectors: an overview on theirproperties, functions, and applications Mohammad Reza Kasaai7.1 Introduction 7.2 Sources, structure, and characteristics 7.3 Preparation of biopolymer-based nanomaterials 7.4 Applications of biopolymer-based nanomaterials 7.5 Conclusions 7.6 Future perspectives Funding Conflict of interests References Further reading 8. Surface functionalization of PLGA nanoparticles fordrug delivery Joana A.D. Sequeira, Irina Pereira, Anto´ nio J. Ribeiro,Francisco Veiga and Ana Cl´audia Santos8.1 Introduction: background and driving forces 8.2 Active targeting by surface functionalization of PLGAnanoparticles 8.3 Noncovalent functionalization of PLGA nanoparticles 8.4 Nucleic acid-functionalized PLGA 8.5 Concluding remarks Acknowledgements References 9. Biomedical-related applications of functionalizednanomaterials Mafalda R. Almeida, M´ arcia C. Neves, Sergio Morales-Torres,Mara G. Freire, Joaquim L. Faria, Vale´ ria C. Santos-Ebinuma,Cl´audia G. Silva and Ana P.M. Tavares9.1 Introduction 9.2 Functionalized nanoparticles in the biopharmaceutical sector 9.3 Types and synthesis procedures of functionalizednanomaterials 9.4 Immobilization of functionalized nanomaterials inmembranes 9.5 Functionalized nanoparticles as drug delivery systems 9.6 Conclusions and future trends Acknowledgments References 10. Functionalized nanomaterials for biomedical andagriculture industries P. Chandra Kanth, Sandeep Kumar Verma and Nidhi Gour10.1 Introduction 10.2 Strategies for functionalization of nanomaterials 10.3 Functionalized nanomaterials for biomedical andpharmaceutical applications 10.4 Application of functionalized nanomaterials inagriculture and agroindustry 10.5 Conclusion References Further reading Section 4Functionalized Nanomaterials for Electronics,Electrical and Energy Industry 11. Functionalized nanomaterials for electronics andelectrical and energy industries Shrabani De and Rashmi Madhuri11.1 Introduction 11.2 Industrial applications 11.3 Conclusion Author declaration References Section 5Functionalized nanomaterial inenvironmental industry12. Functionalization of graphene oxide with metal oxidenanomaterials: synthesis and applications for theremoval of inorganic, toxic, environmental pollutantsfrom waterShraban Ku Sahoo and G. Hota12.1 Introduction 12.2 Preparation of metal oxides functionalized GOnanocomposites 12.3 Removal of inorganic pollutants from water using metaloxide-functionalized GO_nanosubstrates 12.4 Conclusions References 13. Remediation of organic pollutants by potentialfunctionalized nanomaterialsManviri Rani and Uma Shanker13.1 Introduction 13.2 Environmental concern of organic pollutants 13.3 Green synthesis in FNMs 13.4 Necessity of functionalization of NMs for remediation oforganic contaminants 13.5 Working mechanism of FNPs 13.6 Importance of green synthesis in FNMs 13.7 Organic dyes 13.8 Degradation of OP pesticides by FNMs 13.9 Toxicity and functionalized nanoparticles 13.10 Conclusions and future perspectives References Further Reading 14. Implications of surface coatings on engineerednanomaterials for environmental systems: status quo,challenges, and perspectivesNdeke Musee, Samuel Leareng, Lemme Kebaabetswe, GosaitseTubatsi, Ntombikayise Mahaye and Melusi Thwala14.1 Introduction 14.2 Implications of coatings for engineered nanomaterialtransformation in environmental systems 14.3 Influence of engineered nanomaterial coatings on cellularorganisms toxicity 14.4 Molecular approaches to toxicity of engineerednanomaterials: effects of coatings 14.5 Concluding remarks and perspectives References 15. Functionalized halloysite nanotubes: an "ecofriendly"nanomaterial in environmental industry Gaurav Pandey, Maithri Tharmavaram and Deepak Rawtani15.1 Introduction 15.2 Functionalization techniques for halloysite nanotubes 15.3 Applications of functionalized halloysite nanotubes inenvironmental industry 15.4 Conclusion and future prospects References 16. Functionalized nanomaterials for chemical sensorapplications Sing Muk Ng16.1 Introduction 16.2 General characteristics of NMs for chemical-sensingapplications 16.3 The engineering aspects for functionalization of NMs 16.4 Sensing applications 16.5 Summary and future perspectives References 17. Porous nanocomposites for water treatment: past,present, and future Xiaolin Zhang, Zhixian Li, Ziniu Deng and Bingcai Pan17.1 Introduction 17.2 Nanocomposite adsorbents 17.3 Nanocomposite membranes for water purification 17.4 Nanocomposite catalysts 17.5 Summary and perspectives References 18. Impact of functionalized nanomaterials toward theenvironmental remediation: challenges and futureneeds Aashima and S.K. Mehta18.1 Introduction 18.2 Implementation of functionalized nanomaterial:water pollution remediation 18.3 Implementation of functionalized nanomaterial: airpollution remediation 18.4 Implementation of functionalized nanomaterial: soilpollution remediation 18.5 Conclusion 18.6 Future scope and challenges 18.7 Acknowledgment References Section 6Functionalized nanomaterial in surfaces andcoatings (consumer products)19. Natural-based consumer health nanoproducts:medicines, cosmetics, and food supplements Ana Henriques Mota, Alexandra Sousa, Mariana Figueira, MarianaAmaral, Bruno Sousa, Joa˜o Rocha, Elias Fattal, Anto´ nio Jose´ Almeidaand Catarina Pinto Reis19.1 Natural sources 19.2 Nanotechnology in medicines 19.3 Nanoproducts in food supplements 19.4 Natural products, nanotechnology, and skin 19.5 Conclusions References Section 7Functionalized nanomaterial in textiles industry20. Functional nanofibers: fabrication, functionalization,and potential applications Nabil A. Ibrahim, Moustafa M.G. Fouda and Basma M. Eid20.1 Introduction 20.2 Electrospinning 20.3 Fabrication steps 20.4 Polymers used in electrospun NFs 20.5 Functional NFs 20.6 Potential applications 20.7 Future trends Abbreviations References 21. Nanoengineered textiles: from advanced functionalnanomaterials to groundbreaking high-performanceclothing Clara Pereira, Andre´ M. Pereira, Cristina Freire, Taˆnia V. Pinto,Rui S. Costa and Joana S. Teixeira21.1 Nanotechnology on textiles 21.2 Nanoengineered textiles: functionalization processes 21.3 Functional nanomaterials from production totextile applications 21.4 Future trends and prospects Acknowledgments References Section 8Functionalized nanomaterial in cosmetics industry22. Functional nanomaterials for the cosmetics industry Suman Singh_, Satish Kumar Pandey_ and Neelam Vishwakarma22.1 Introduction 22.2 Cosmetics: performance enhancement usingnanotechnology 22.3 Nanocosmetics: types and applications 22.4 Classification of nanocosmetics on the basis of formulationtechnologies 22.5 Nanocosmetics: some popular categories 22.6 Nanotechnology for UV protection 22.7 Formulation and manufacturing aspects 22.8 Guidance documents on nanomaterials in cosmetics 22.9 Safety assurance 22.10 Impurity profiling 22.11 Evaluation of nanomaterial toxicology 22.12 Toxicity testing 22.13 Conclusions Acknowledgment References 23. Naturally derived pyroxene nanomaterials: an orefor wide applications Gerardo Vitale, Ghada Nafie, Afif Hethnawi and Nashaat N. Nassar23.1 Introduction 23.2 Synthesis of iron_silicate-based nanomaterials by thehydrothermal method 23.3 Conclusions References 24. Nanomaterial-based cosmeceuticals Pravin Shende, Drashti Patel and Anjali Takke24.1 Introduction 24.2 Nanomaterials in cosmeceuticals 24.3 Classification of nanocosmeceuticals 24.4 Penetration of nanoparticles 24.5 Toxicity of nanocosmeceuticals 24.6 Safety of nanocosmeceuticals 24.7 Regulations of nanocosmeceuticals 24.8 Conclusions and future perspectives References Further reading Section 9Functionalized nanomaterials for aerospace,vehicle and sports industry25. Functionalized nanomaterials for the aerospace, vehicle,and sports industries Sadaf Abbasi, M.H. Peerzada, Sabzoi Nizamuddin and NabisabMujawar Mubarak25.1 Introduction 25.2 Types of nanomaterials 25.3 Properties of functional nanomaterials 25.4 Applications of functional nanomaterials 25.5 Benefits and challenges 25.6 Conclusion References Section 10Functionalized nanomaterial in construction industry26. Nanomaterials for enhancement of thermal energystorage in building and industrial applications Teng Xiong and Kwok Wei Shah26.1 Introduction 26.2 Nanometal enhancer 26.3 Nanometal oxide enhancer 26.4 Nanocarbon enhancer 26.5 Conclusions References 27. Application of functionalized nanomaterials in asphaltroad construction materials Henglong Zhang, Chongzheng Zhu, Chuanwen Wei,Haihui Duan and Jianying Yu27.1 Introduction 27.2 Application of organic layered silicate in asphalt 27.3 Application of surface modification inorganic nanoparticles inasphalt 27.4 Applications of multidimensional nanomaterials in asphalt 27.5 Future trends in research of functionalized nanomaterialmodifiedasphalt References Section 11Functionalized Nanomaterial in Wood &Paper-Related Applications28. Functional Rubber_Clay Nanotube Composites WithSustained Release of Protective Agents Ye Fu, Liqun Zhang and Yuri Lvov28.1 Introduction 28.2 Encapsulation and sustained release of chemical agents 28.3 Functional halloysite_rubber nanocomposites 28.4 Conclusions References Section 12Environmental, Legal, Health and Safety Issues ofFunctionalized Nanomaterials29. Handbook of surface-functionalized nanomaterials:safety and legal aspects Neil John Hunt29.1 Introduction 29.2 Different types of surface modification 29.3 Effect of surface on biological mechanisms 29.4 Substance-specific examples 29.5 Allotropes of carbon 29.6 Polymeric nanomaterials 29.7 Quantum dots 29.8 Inorganic elements and oxides 29.9 Regulatory and legal issues that impact surface-functionalizednanomaterials 29.10 Current REACH situation with nanomaterials 29.11 Board of appeal review 29.12 Amendments to the annexes of REACH (2019) 29.13 Other EU regulations 29.14 Other national regulations that impact nanomaterials 29.15 Conclusion References Further reading 30. Functional nanomaterials: selected legal andregulatory issues Md. Ershadul Karim30.1 Introduction 30.2 Functional nanomaterials: an overview 30.3 Functionalized nanomaterials: applications, human health,and environmental concerns 30.4 Functionalized nanomaterials: legal and regulatory aspects 30.5 Functionalized nanomaterials: highlights of legal andregulatory initiatives 30.6 Discussion 30.7 Conclusion References 31. Functional nanomaterials: selected occupationalhealth and safety concerns Md. Ershadul Karim31.1 Introduction 31.2 ENMs and OHS concerns 31.3 ENMs and OHS laws: an overview 31.4 Initiatives taken by the stakeholders 31.5 Evaluation 31.6 Conclusion References Index Contents xv