Carbohydrate Chemistry

Christian Vogel earned a PhD in organic chemistry–heterocyclic chemistry under the supervision of Professor Klaus Peseke at the University of Rostock in 1980. Since 1992, he has served as a professor in the Department of Organic Chemistry, University of Rostock.In addition to fucose chemistry, Dr. Vogel’s main interests are pectin fragment synthesis using the modular design principle, the synthesis of rare sugars for structural investigations, and C-nucleosides. Paul V. Murphy was appointed to the position of Established Professor of Chemistry at National University of Ireland Galway (NUI Galway) in 2008. He is from the West of Ireland (Turloughmore, Co. Galway). His group is engaged in the design and synthesis of bioactive compounds, with a focus on carbohydrates, maintaining a long tradition in carbohydrate research in Galway’s School of Chemistry.

'The contributors are the best scientists in the field and the series editor is highly respected. The volumes will ... be of use to undergraduates involved in carbohydrate workshops.'– Alexei Demchenko, Associate Professor of Chemistry and Biochemistry, Director of Graduate Studies, University of Missouri – St. Louis.‘This essential book series, focused on carbohydrate synthesis, starts with a dedication to Nobel Laureate Sir John W. Cornforth, who is credited with the first public criticism of what he pictured as ‘pouring a large volume of unpurified sewage into the chemical literature.’1 Unfortunately, this issue is not limited to the field of chemistry as many high profile cases of irreproducible experiments have led to alarms being set off even in the popular press.2 This series then serves as the much-needed water treatment plants – places where the reader can be guaranteed a good clean reproducible experiment. … at least now chemists with or without expertise in carbohydrates can count on finding reliable procedures to make sugar-based compounds at one scale – a major achievement. Not only should current practitioners gain back time lost in attempts to properly reconstruct experimental procedures, but these procedures should also allow more creative scientists to contribute to this growing area. Cornforth JW. Austr. J. Chem. 1993;46:157e70. For example, see Unreliable research: trouble at the lab. Econ. October 19, 2013.’– Nicola L.B. Pohl, Indiana University, Department of Chemistry, Bloomington, IN, USA, for Carbohydrate Research, http://dx.doi.org/10.1016/j.carres.2015.04.007.

• ForewordIntroductionEditorsSeries EditorContributorsSection I Synthetic MethodsChapter 1 Picoloyl-Protecting Group in Oligosaccharide Synthesis: Installation, H-Bond-Mediated Aglycone Delivery (HAD), and Selective RemovalMichael P. Mannino, Jagodige P. Yasomanee, Alexei V. Demchenko, and Venukumar PattetiChapter 2 Monomethoxytrityl (MMTr) as an Efficient S-Protecting Group in the Manipulation of Glycosyl ThiolsRaymond Smith, Xiangming Zhu, and Elena Calatrava-PérezChapter 3 One-Step Inversion of Configuration of a Hydroxy Group in CarbohydratesShino Manabe and Markus BlaukopfChapter 4 Formation and Cleavage of Benzylidene Acetals Catalyzed by NaHSO4∙SiO2Lifeng Sun, Xin-Shan Ye, and Xingdi WangChapter 5 Thiodisaccharides by Photoinduced Hydrothiolation of 2-Acetoxy GlycalsDániel Eszenyi, László Lázár, Anikó Borbás, andRuairi O. McCourtChapter 6 One-Step Preparation of Protected N-tert-Butanesulfinyl d-ribo and d-xylo Furanosylamines from Related Sugar HemiacetalsChloé Cocaud, Cyril Nicolas, Olivier R. Martin, and Jérôme DésiréChapter 7 An Alternative Preparation of Azides from Amines via Diazotransfer with Triflyl AzideYuqian Ye, Xin-Shan Ye, and Xingdi WangChapter 8 Simple Preparation of Dimethyldioxirane and Its Use as an Epoxidation Agent for the Transformation of Glycals to Glycosyl PhosphatesKatharina Kettelhoit, Daniel B. Werz, Aniruddha Sasmal, Xinyu Liu, and Philipp GritschChapter 9 Preparation of Glycosyl Bromides of α-d-Gluco-hept-2-ulopyranosonic Acid DerivativesVeronika Nagy, Katalin Czifrák, László Juhász, László Somsák, and Olena ApeltChapter 10 Preparation of 2,6-Anhydro-hept-2-enonic Acid Derivatives and Their 3-Deoxy Count