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    1. Naturvetenskap och teknik
    2. Teknik och industri
    3. Tillverkningsteknik

    Surfactants from Renewable Resources

    AvMikael Kjellin,Ingegärd Johansson

    Inbunden, Engelska, 2010

    Del i serien Wiley Series in Renewable Resource

    1 786 kr

    Beställningsvara. Skickas inom 5-8 vardagar. Fri frakt över 249 kr.

    Beskrivning

    Most modern surfactants are readily biodegradable and exhibit low toxicity in the aquatic environment, the two criteria for green surfactants. However the majority are synthesised from petroleum, so over the past decade the detergent industry has turned its attention to developing greener routes to create these surfactants via renewable building blocks. Surfactants from Renewable Resources presents the latest research and commercial applications in the emerging field of sustainable surfactant chemistry, with emphasis on production technology, surface chemical properties, biodegradability, ecotoxicity, market trends, economic viability and life-cycle analysis.Reviewing traditional sources for renewable surfactants as well as recent advances, this text focuses on techniques with potential for large scale application.Topics covered include: Renewable hydrophobes from natural fatty acids and forest industry by-productsRenewable hydrophiles from carbohydrates, amino acids and lactic acidNew ways of making renewable building blocks; ethylene from renewable resources and complex mixtures from waste biomassBiosurfactantsSurface active polymersThis book is a valuable resource for industrial researchers in companies that produce and use surfactants, as well as academic researchers in surface and polymer chemistry, sustainable chemistry and chemical engineering.

    Produktinformation

    • Utgivningsdatum:2010-01-26
    • Mått:177 x 252 x 24 mm
    • Vikt:737 g
    • Format:Inbunden
    • Språk:Engelska
    • Serie:Wiley Series in Renewable Resource
    • Antal sidor:352
    • Förlag:John Wiley & Sons Inc
    • ISBN:9780470760413

    Utforska kategorier

    • Tillverkningsteknik inom Naturvetenskap och teknik

    Mer om författaren

    Dr Mikael Kjellin is based at the Institute for Surface Chemistry, Stockholm, Sweden, which works with many industrial branches including pharmaceuticals, personal care products, biotech, food, industrial chemicals, household products, engineering and materials industries, pulp and paper, coatings, adhesives, paints, and printing.In addition, Dr Kjellin is the coordinator of the research centre SNAP, which aims to build from an industrial need, long-term knowledge and experience relating to new environmentally safe surfactants derived entirely or partly from natural products. Ingegard.Johansson is a research scientists based at Akzo Nobel Surfactants Europe in Sweden.

    Recensioner i media

    "The book is highly concentrated on technical aspects with big expertise in the different production technologies, it aims to be used as a chemical and technical reference for industrial and academic researchers in this field." (Encyclopedia of Industrial Biotechnology, 30 August 2011)

    Innehållsförteckning

    • Series Preface xiPreface xiiiAcknowledgements xviiList of Contributors xixPart 1 Renewable Hydrophobes 11 Surfactants Based on Natural Fatty Acids 3Martin Svensson1.1 Introduction and History 31.2 Fats and Oils as Raw Materials 41.3 Fatty Acid Soaps 51.4 Polyethylene Glycol Fatty Acid Esters 101.5 Polyglycerol Fatty Acid Esters 111.6 Conclusions 13References 152 Nitrogen Derivatives of Natural Fats and Oils 21Ralph Franklin2.1 Introduction 212.2 Manufacture of Fatty Nitrogen Derivatives 222.3 Production Data 302.4 Ecological Aspects 302.5 Biodegradation 312.6 Properties of Nitrogen-Based Surfactants 332.7 Applications 352.8 Conclusions 39References 403 Surface-Active Compounds as Forest-Industry By-Products 45Bjarne Holmbom, Anna Sundberg and Anders Strand3.1 Introduction 453.2 Resin and Fatty Acids 463.3 Sterols and Sterol Ethoxylates 543.4 Hemicelluloses 56Acknowledgements 58References 59Part 2 Renewable Hydrophiles 634 Surfactants Based on Carbohydrates and Proteins for Consumer Products and Technical Applications 65Karlheinz Hill4.1 Introduction 654.2 Raw Materials 654.3 Products and Applications 674.4 Conclusion 81Acknowledgements 81References 815 Amino Acids, Lactic Acid and Ascorbic Acid as Raw Materials for Biocompatible Surfactants 85Carmen Moran, Lourdes Perez, Ramon Pons, Aurora Pinazo and Maria Rosa Infante5.1 Introduction 855.2 Production of Raw Materials 865.3 Lysine-Based Surfactants 875.4 Lactic Acid-Based Surfactants 945.5 Ascorbic Acid-Based Surfactants 97References 100Part 3 New Ways of Making Renewable Building Blocks 1096 Ethylene from Renewable Resources 111Anna Lundgren and Thomas Hjertberg6.1 Introduction 1116.2 Why Produce Ethylene from Renewable Resources? 1136.3 Production of Ethylene from Renewable Feedstock 1156.4 Commercialization of Bioethylene 1216.5 Environmental Impact of Bioethylene 1236.6 Certificate of Green Carbon Content 1246.7 Concluding Remarks 125References 1257 Fermentation-Based Building Blocks for Renewable Resource-Based Surfactants 127Kris Arvid Berglund, Ulrika Rova and David B. Hodge7.1 Introduction 1277.2 Existing and Potential Classes of Surfactants from Biologically Derived Metabolites 1297.3 Fermentation-Based Building Blocks with Large Existing Markets 1317.4 New Fermentation-Based Building Blocks 1337.5 Conclusion 138References 138Part 4 Biosurfactants 1438 Synthesis of Surfactants Using Enzymes 145Patrick Adlercreutz and Rajni Hatti-Kaul8.1 Introduction 1458.2 Enzymes as Catalysts for Synthesis of Surfactants 1468.3 Enzymatic Synthesis of Polar Lipids Useful as Surfactants 1478.4 Carbohydrate Esters 1488.5 Fatty Amide Surfactants 1518.6 Amino Acid-Based Surfactants 1558.7 Alkyl Glycosides 1588.8 Future Prospects 160Acknowledgements 161References 1619 Surfactants from Waste Biomass 167Flor Yunuen García-Becerra, David Grant Allen and Edgar Joel Acosta9.1 Introduction 1679.2 Surfactants Obtained from Biological Transformation of Waste Biomass 1689.3 Surfactants Obtained from Chemical Transformation of Waste Biomass 1779.4 Summary and Outlook 185References 18510 Lecithin and Other Phospholipids 191Willem van Nieuwenhuyzen10.1 Introduction 19110.2 Sources and Production 19110.3 Composition 19510.4 Quality and Analysis of Lecithins 19610.5 Modification 19810.6 Emulsifying Properties 20310.7 Applications 20610.8 Legislation and Reach 20910.9 Conclusion 211References 21111 Sophorolipids and Rhamnolipids 213Dirk W. G. Develter and Steve J. J. Fleurackers11.1 Sophorolipids 21311.2 Derivatives of Native Sophorolipids 22411.3 Biosynthesis of Novel Sophorolipids 22711.4 Rhamnolipids 23011.5 Cleaning Applications Using Sophorolipids and Rhamnolipids 234References 23612 Saponin-Based Surfactants 239Wieslaw Oleszek and Arafa Hamed12.1 Introduction 23912.2 Molecular Properties 24012.3 Sources of Saponins 24212.4 Saponins as Emulsifiers and Surfactants 24212.5 Application of Saponins as Surfactants and Emulsifiers 245Acknowledgements 248References 248Part 5 Polymeric Surfactants/Surface-Active Polymers 25113 Surface-Active Polymers from Cellulose 253Leif Karlson13.1 Introduction 25313.2 Structure and Synthesis of Cellulose Ether 25413.3 Cellulose Ethers in Aqueous Solution 25713.4 Interaction with Surfactants 26213.5 Clouding 263References 26514 New Developments in the Commercial Utilization of Lignosulfonates 269Rolf Andreas Lauten, Bernt O. Myrvold and Stig Are Gundersen14.1 Introduction 26914.2 Lignosulfonates 26914.3 Lignosulfonate Production 27114.4 Environmental Issues 27214.5 Lignosulfonates as Stabilizers for Emulsions and Suspoemulsions 27414.6 Superplasticizers for Concrete 27914.7 Summary 280Acknowledgements 281References 28115 Dispersion Stabilizers Based on Inulin 285Tharwat Tadros and Bart Levecke15.1 Introduction 28515.2 Solution Properties of Long-Chain Inulin and Hydrophobically Modified Inulin (HMI) 28815.3 Interfacial Aspects of HMI at Various Interfaces 28915.4 Emulsions Stabilized Using HMI 29015.5 Emulsion Polymerization Using HMI 29315.6 Use of HMI for Preparation and Stabilization of Nanoemulsions 295References 300Index 303