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    1. Naturvetenskap och teknik
    2. Teknik och industri
    3. Tillverkningsteknik

    Physico-chemical Aspects of Textile Coloration

    AvStephen M. Burkinshaw

    Inbunden, Engelska, 2016

    Del i serien SDC-Society of Dyers and Colourists

    1 512 kr

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    Beskrivning

    The production of textile materials comprises a very large and complex global industry that utilises a diverse range of fibre types and creates a variety of textile products. As the great majority of such products are coloured, predominantly using aqueous dyeing processes, the coloration of textiles is a large-scale global business in which complex procedures are used to apply different types of dye to the various types of textile material. The development of such dyeing processes is the result of substantial research activity, undertaken over many decades, into the physico-chemical aspects of dye adsorption and the establishment of ‘dyeing theory’, which seeks to describe the mechanism by which dyes interact with textile fibres.Physico-Chemical Aspects of Textile Coloration provides a comprehensive treatment of the physical chemistry involved in the dyeing of the major types of natural, man-made and synthetic fibres with the principal types of dye. The book covers: fundamental aspects of the physical and chemical structure of both fibres and dyes, together with the structure and properties of water, in relation to dyeing;dyeing as an area of study as well as the terminology employed in dyeing technology and science;contemporary views of intermolecular forces and the nature of the interactions that can occur between dyes and fibres at a molecular level;fundamental principles involved in dyeing theory, as represented by the thermodynamics and kinetics of dye sorption;detailed accounts of the mechanism of dyeing that applies to cotton (and other cellulosic fibres), polyester, polyamide, wool, polyacrylonitrile and silk fibres;non-aqueous dyeing, as represented by the use of air, organic solvents and supercritical CO2 fluid as alternatives to water as application medium.The up-to-date text is supported by a large number of tables, figures and illustrations as well as footnotes and widespread use of references to published work. The book is essential reading for students, teachers, researchers and professionals involved in textile coloration.

    Produktinformation

    • Utgivningsdatum:2016-02-05
    • Mått:213 x 305 x 33 mm
    • Vikt:1 678 g
    • Format:Inbunden
    • Språk:Engelska
    • Serie:SDC-Society of Dyers and Colourists
    • Antal sidor:640
    • Förlag:John Wiley & Sons Inc
    • ISBN:9781118725696

    Utforska kategorier

    • Tillverkningsteknik inom Naturvetenskap och teknik

    Mer om författaren

    Professor Stephen Burkinshaw is a Professor of Textile Chemistry at the University of Leeds. His research interests include the chemistry and application of dyes and pigments to natural and man-made fibres, colour measurement and textile finishing. He is the author of ~200 publications including a textbook on dyeing theory (Chemical Principles of Synthetic Fibre Dyeing, Springer, 1995.) and section editor for the Springer publication, Encyclopedia of Colour Science and Technology, which is due for publication in 2013.As both a tutor of part-time students sitting ASDC Paper C: Properties of Materials and Finished Products and Fundamental Mechanisms of Industrial Processes and examiner of ASDC Paper C (1994-1999), as well as the person responsible for teaching and examining all three undergraduate years in Dyeing Theory within the Department of Colour Science at Leeds University, Professor Burkinshaw has first-hand, tangible experience of how students view and use this particular book.

    Innehållsförteckning

    • Society of Dyers and Colourists xi Preface xiii1 Fundamental Aspects of Textile Fibres 11.1 Textiles 11.1.1 Yarn 21.1.2 Fabric 41.1.3 Textile Markets 61.2 Textile Fibres 61.2.1 Textile Fibre Classification 71.2.2 Textile Usage 91.2.3 The History and Development of Textile Fibres 91.2.4 Textile Polymers 121.2.5 Textile Fibre Morphology and Fine Structure 161.3 General Physical and Mechanical Characteristics of Textile Fibres 271.3.1 Length 271.3.2 Fineness 271.3.3 Twist 321.3.4 Fibre Specific Surface Area, Sm or Sv 331.3.5 Cross-Sectional Shape 331.4 Properties of Textile Fibres 351.4.1 Mechanical Properties 351.4.2 Thermal Properties 371.4.3 Optical Properties 48References 512 Dyes 65Introduction 652.1 Dyes 652.1.1 Historical Aspects 662.1.2 Classification of Colorants 712.1.3 Colour and Constitution 752.1.4 Commercial Dye Forms 752.1.5 Commercial Dye Names 762.1.6 Global Dye Consumption 76References 763 The Role of Water in Aqueous Dyeing 81Introduction 813.1 Water Structure 823.2 Water Availability and Global Consumption 843.2.1 Water Footprint 853.3 Water Use in Dyeing 863.3.1 Water Used in Cotton Production 863.3.2 Water Used in Fibre Processing 873.3.3 Water Used in Dyeing 873.4 Water and Textile Fibres 913.4.1 Hydrophilicity and Hydrophobicity 933.4.2 Moisture Sorption 943.4.3 The Porous Nature of Fibres 1033.4.4 Wetting and Wicking 1053.4.5 Swelling 1093.4.6 Water Plasticisation 1103.5 Water and Dyes 1163.5.1 Solvation 1173.5.2 Dye Solubility 1203.5.3 Dye Aggregation in Solution 1233.5.4 Dye Aggregation in the Fibre 1293.5.5 Aqueous Dye Dispersions 1293.6 pH and pK 1343.6.1 Water Ionisation (Ionic Product of Water) 1343.6.2 The pH Scale 1353.6.3 pKa and pKb 1363.6.4 Buffer Systems and the Henderson–Hasselbalch Equation 136References 1374 Fundamentals of Dyeing 153Introduction 1534.1 Dye–Fibre Systems 1544.2 Fundamental Principles of Dyeing 1564.2.1 Dye–Fibre Substantivity 1564.2.2 Driving Force for Dyeing 1574.2.3 Dye Exhaustion 1574.2.4 Rate of Dyeing 1584.2.5 Depth of Shade 1594.2.6 Liquor Ratio 1594.2.7 Dye Fixation 1604.2.8 Wash-Off 1614.2.9 Fastness 1624.2.10 Dyeing Auxiliaries 163References 1645 Dye–Fibre Interactions 167Introduction 1675.1 Intermolecular Interactions (or Forces) between Atoms and Molecules 1675.1.1 Covalent Bonds 1695.1.2 Ion–Ion Interactions (aka Charge–Charge, Coulomb, Electrostatic Interactions) 1695.1.3 Ion–Dipole Interactions (aka Charge–Dipole, Monopole–Dipole) 1695.1.4 Van der Waals Interactions (aka van der Waals Forces) 1705.1.5 Hydrogen Bonds 1725.1.6 Hydrophobic Effect and Hydrophobic Interactions 1725.1.7 Total (Attractive and Repulsive) Intermolecular Potentials 1735.1.8 Aromatic Interactions (aka π-Interactions, π-Effects) 1735.2 Intermolecular Interactions (or Forces) between Macromolecules and Surfaces 1765.2.1 Dispersion Interactions 1765.2.2 Electrostatic Forces 1785.3 Intermolecular Forces in the Context of Textile Fibres and Dyes 1905.3.1 Intermolecular Forces in Textile Polymers 1905.3.2 Intermolecular Forces between Dyes and Fibres 1915.4 Solubility Parameter 1925.4.1 Hildebrand Solubility Parameter 1935.4.2 Hansen Solubility Parameters 1935.4.3 Solubility Parameters and Dye–Fibre Substantivity 1945.4.4 Carriers 1945.5 Fibre Modification to Enhance Dye–Fibre Substantivity 1955.5.1 Mercerisation 1955.5.2 Plasma 1975.5.3 Pre-treatment with Cationic Compounds 1995.5.4 Nucleophilic Dyes on Modified Substrates 200References 2006 Dyeing Theory 209Introduction 2096.1 Background 2106.2 Dyeing Systems at Equilibrium (the Thermodynamics of Dyeing) 2116.2.1 Adsorption 2136.2.2 Standard Affinity, Standard Heat and Standard Entropy of Dyeing 2166.3 Kinetics of Dyeing 2216.3.1 Diffusion 2226.3.2 Steady-State and Non-Steady-State Diffusion 2236.3.3 Fick’s Laws of Diffusion 2236.3.4 Experimental Methods for Determining Diffusion Coefficient 2246.3.5 Approximate Solutions to Diffusion Equations 2286.3.6 Characterisation of the Rate of Dyeing 2286.3.7 Apparent Diffusion Coefficient 2296.3.8 Boundary Layers in Diffusion 2316.3.9 Effect of Temperature on Dye Diffusion 2336.3.10 Influence of Fibre Structure on Diffusion 2356.3.11 Influence of Dye Structure on Diffusion 237References 2417 Cellulosic Fibres 249Introduction 2497.1 Cotton 2497.2 Viscose Fibres 2507.2.1 Skin–Core Structure 2517.3 Lyocell Fibres 2527.4 CA and CTA Fibres 2547.5 Cellulose Chemistry and Molecular Structure 2567.5.1 Crystal Forms 2577.6 Cellulosic Fibre Fine Structure 2607.7 Hydroxyl Groups in Cellulosic Fibres 2617.7.1 Accessibility 2617.8 Water/Cellulose Interactions 2637.8.1 Moisture Sorption 2637.8.2 Free and Bound Water 2657.8.3 Pore Structure 2667.8.4 Swelling 2677.8.5 Bleaching of Cotton and Other Cellulosic Fibres 2707.8.6 Plasticisation 2707.9 Dye Classes Used on Cellulosic Fibres 2727.10 The Role of Electrolyte in Cellulosic Fibre Dyeing 2737.10.1 Nature of the Charged Cellulosic Fibre 2747.10.2 Zeta Potential of Cellulosic Fibres 2747.10.3 The Amount of Electrolyte Required to ‘Neutralise’ the Negative Surface Charge 2797.10.4 Effect of Electrolyte on Dye Aggregation and Dye Solubility 2807.11 Direct Dyes 2817.11.1 Classification of Direct Dyes 2827.11.2 Thermodynamics of Dyeing 2837.11.3 Kinetics of Dyeing 2977.11.4 Aftertreatment 3017.12 Sulphur Dyes 3027.12.1 Fundamentals of the Chemistry and Application of Sulphur Dyes for Cellulosic Fibres 3037.12.2 Dye Application 3047.13 Vat Dyes 3057.13.1 Fundamentals of the Chemistry and Application of Vat Dyes for Cellulosic Fibres 3067.13.2 Reduction 3087.13.3 Adsorption of the Leuco Derivative (Dyeing) 3127.13.4 Kinetics of Leuco Vat Application 3177.13.5 Oxidation of the Adsorbed Dye 3187.13.6 Soaping 3197.14 Reactive Dyes 3197.14.1 Fundamentals of the Chemistry and Application of Reactive Dyes for Cellulosic Fibres 3207.14.2 Mechanism of Dyeing 3257.14.3 Wash-Off 3347.14.4 Aftertreatment 3377.15 Azoic Colorants 3377.15.1 Naphtholation 3387.15.2 Development 3387.15.3 Wash-Off 3397.16 Disperse Dyes 340References 3408 Polyester Fibres 359Introduction 3598.1 PES Fibres 3598.1.1 Fibre Production and Properties 3608.1.2 Physical Structure 3618.1.3 Oligomers 3638.1.4 Sheath/Core Structure 3658.1.5 Transitions (Relaxations) 3658.1.6 PES/Water Interactions 3668.1.7 Dyeing of PES Fibres 3678.2 PLA Fibres 4038.2.1 Polymer Synthesis 4048.2.2 PLA Biodegradability 4058.2.3 Fibres 405References 4139 Polyamide Fibres 427Introduction 4279.1 Aliphatic Polyamide Fibres 4279.1.1 Nomenclature and Types of Polyamides 4279.1.2 PA 6 and PA 66 4299.1.3 Physical Structure 4309.2 Dyeing of Aliphatic Polyamides 4459.2.1 Effect of Physical Processing on Dyeing 4469.2.2 Barré Effects 4469.2.3 Levelling Agents 4479.3 Acid Dyes 4479.3.1 Non-metallised Acid Dyes 4489.3.2 Pre-metallised Acid Dyes (Aka Metal Complex Dyes) 4649.3.3 Aftertreatment 4659.4 Disperse Dyes 4679.5 Mordant Dyes 4679.6 Direct Dyes 4689.7 Reactive Dyes 4689.7.1 Anionic Reactive Dyes 4699.7.2 Disperse Reactive Dyes 4709.8 Sulphur Dyes 4709.9 Vat Dyes 4719.10 Azoic Colorants 4719.11 Microfibres 4719.12 Semi-Aromatic Polyamides 4739.13 Aromatic Polyamides 4749.13.1 Fine Structure 4759.13.2 Water/Aramid Interactions 4769.13.3 Dyeing of Aromatic Polyamide Fibres 478References 47910 Wool Fibres 491Introduction 49110.1 Wool Chemistry and Molecular Structure 49110.1.1 Proteins and Amino Acids 49110.1.2 Fibre Morphology 49410.1.3 Fine Structure 49610.1.4 Water/Wool Interactions 49710.1.5 Swelling and Heat of Sorption 49810.1.6 Sorption of Acids and Alkalis 49910.1.7 Water Plasticisation 49910.1.8 Effect of Physical and Chemical Properties on Dyeing 50010.2 Dyes for Wool 50010.3 Non-metallised Acid Dyes 50110.3.1 Thermodynamics of Dyeing 50110.3.2 Effect of Electrolyte on Dye Adsorption 50910.3.3 Affinities of Acids and Dye Anions 51110.3.4 Kinetics of Dyeing 51310.4 Pre-metallised Acid Dyes (Aka Metal Complex Dyes) 51610.4.1 1 : 1 Metal Complex Dyes 51710.4.2 1 : 2 Metal Complex Dyes 51810.5 Mordant Dyes 51910.5.1 Mechanism of Chroming 52010.6 Reactive Dyes 52110.6.1 Historical Aspects 52110.6.2 Chemistry and Application of Reactive Dyes 52110.6.3 Levelling Agents 522References 52411 Acrylic (polyacrylonitrile) Fibres 531Introduction 53111.1 Fibre Production and Properties 53111.2 Physical Structure 53211.2.1 Crystallinity or Pseudocrystallinity 53311.2.2 Transitions (Relaxations) 53311.2.3 Theories of Fine Structure 53311.3 PAN/Water Interactions 53511.3.1 Water Plasticisation 53511.4 Dyes for PAN Fibres 53611.5 Basic Dyes 53611.5.1 Historical Aspects 53611.5.2 General Characteristics of Basic Dyes 53711.5.3 Thermodynamics of Dyeing 53811.5.4 Kinetics of Dyeing 54311.5.5 Effect of Electrolytes on Dyeing 54511.5.6 Effect of pH on Dyeing 54711.5.7 Effect of Temperature on Dyeing 54811.5.8 Retarding Agents 55011.5.9 Dyes in Admixture 55011.5.10 Carriers 55111.6 Disperse Dyes 55111.6.1 Thermodynamics of Dyeing 55211.6.2 Kinetics of Dyeing 552References 55312 Silk Fibres 55912.1 Fibre Morphology 55912.2 Silk Chemistry and Molecular Structure 55912.3 Fine Structure 56012.4 Silk/Water Interactions 56412.4.1 Water Plasticisation 56412.5 Dyes for Silk 56512.5.1 Acid Dyes 56612.5.2 Reactive Dyes 567References 56813 Non-aqueous Dyeing 571Introduction 57113.1 Dyeing from Air (Vapour-Phase Dyeing; Thermofixation) 57113.1.1 General Introduction 57113.1.2 Thermodynamics of Dyeing 57113.1.3 Kinetics of Dyeing 57313.2 Dyeing from Supercritical Carbon Dioxide 57513.2.1 General Introduction 57513.2.2 Properties of Supercritical CO2 Fluids 57513.2.3 Solubility of Dyes in Supercritical CO2 57713.2.4 Effect of Supercritical CO2 on Fibres 57913.2.5 Dyeing from Supercritical CO2 58213.3 Dyeing from Liquid (Non-aqueous) Solvents 59213.3.1 PER Dyeing 59213.3.2 Solvent-Assisted Dyeing 594References 594Colorants Index 601Subject Index 605