The U.S. Army is in the process of destroying the nation''s stockpile of aging chemical weapons stored at eight locations in the continental United States and on Johnston Atoll in the Pacific. Originally, incineration was chosen for the destruction of these stores, but this method has met with public opposition, and Congress directed the Army to develop alternative technologies for destroying the stockpiles in Pueblo, CO and Richmond, KY. To assist the Army in this process, the NRC was asked to evaluate the engineering design study of the three Blue Grass candidates. This book presents an analysis of various issues pertaining to the proposed engineering design package for the Blue Grass facility.

By direction of Congress, the U.S. Department of Defense''s (DoD''s) program manager for the Assembled Chemical Weapons Assessment (PMACWA) asked the National Research Council (NRC) Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (the ACW II committee) to conduct an independent scientific and technical assessment of three alternative technologies (referred to as Demo II) under consideration for the destruction of assembled chemical weapons at U.S. chemical weapons storage sites. The three technologies are AEA Technologies Corporation''s (AEA''s) electrochemical oxidation process; the transpiring-wall supercritical water oxidation and gasphase chemical reduction processes of Foster Wheeler/Eco Logic/Kvaerner (FW/EL/K); and Teledyne-Commodore''s solvated electron process. Each of these technologies represents an alternative to incineration for the complete destruction of chemical agents and associated energetic materials. The demonstration tests were approved by the PMACWA after an initial assessment of each technology. The results of that initial assessment were reviewed by an earlier NRC committee, the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (the ACW I committee).

For the present review, the committee conducted an indepth examination of each technology provider''s data, analyses, and demonstration test results for the critical components tested. This review report supplements the ACW I report and considers the demonstration performance of the Demo II candidate technologies and their readiness for advancement to pilot-scale implementation. Because testing in these areas is ongoing, the committee decided to cut short its fact-finding efforts for input to this report as of March 30, 2001.

The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee''s scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo.

The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.

The U.S. Army is in the process of destroying the nation''s stockpile of aging chemical weapons stored at eight locations in the continental United States and on Johnston Atoll in the Pacific. Originally, incineration was chosen for the destruction of these stores, but this method has met with public opposition, and Congress directed the Army to develop alternative technologies for destroying the stockpiles in Pueblo, CO and Richmond, KY. To assist the Army in this process, the NRC was asked to evaluate the engineering design study of the three Blue Grass candidates. This book presents an analysis of various issues pertaining to the proposed engineering design package for the Blue Grass facility.

The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee''s scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo.

The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.

By direction of Congress, the U.S. Department of Defense''s (DoD''s) program manager for the Assembled Chemical Weapons Assessment (PMACWA) asked the National Research Council (NRC) Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (the ACW II committee) to conduct an independent scientific and technical assessment of three alternative technologies (referred to as Demo II) under consideration for the destruction of assembled chemical weapons at U.S. chemical weapons storage sites. The three technologies are AEA Technologies Corporation''s (AEA''s) electrochemical oxidation process; the transpiring-wall supercritical water oxidation and gasphase chemical reduction processes of Foster Wheeler/Eco Logic/Kvaerner (FW/EL/K); and Teledyne-Commodore''s solvated electron process. Each of these technologies represents an alternative to incineration for the complete destruction of chemical agents and associated energetic materials. The demonstration tests were approved by the PMACWA after an initial assessment of each technology. The results of that initial assessment were reviewed by an earlier NRC committee, the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (the ACW I committee).

For the present review, the committee conducted an indepth examination of each technology provider''s data, analyses, and demonstration test results for the critical components tested. This review report supplements the ACW I report and considers the demonstration performance of the Demo II candidate technologies and their readiness for advancement to pilot-scale implementation. Because testing in these areas is ongoing, the committee decided to cut short its fact-finding efforts for input to this report as of March 30, 2001.

The U.S. Army is in the process of destroying the nation''s stockpile of aging chemical weapons stored at eight locations in the continental United States and on Johnston Atoll in the Pacific. Originally, incineration was chosen for the destruction of these stores, but this method has met with public opposition, and Congress directed the Army to develop alternative technologies for destroying the stockpiles in Pueblo, CO and Richmond, KY. To assist the Army in this process, the NRC was asked to evaluate the engineering design study of the three Blue Grass candidates. This book presents an analysis of various issues pertaining to the proposed engineering design package for the Blue Grass facility.

By direction of Congress, the U.S. Department of Defense''s (DoD''s) program manager for the Assembled Chemical Weapons Assessment (PMACWA) asked the National Research Council (NRC) Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (the ACW II committee) to conduct an independent scientific and technical assessment of three alternative technologies (referred to as Demo II) under consideration for the destruction of assembled chemical weapons at U.S. chemical weapons storage sites. The three technologies are AEA Technologies Corporation''s (AEA''s) electrochemical oxidation process; the transpiring-wall supercritical water oxidation and gasphase chemical reduction processes of Foster Wheeler/Eco Logic/Kvaerner (FW/EL/K); and Teledyne-Commodore''s solvated electron process. Each of these technologies represents an alternative to incineration for the complete destruction of chemical agents and associated energetic materials. The demonstration tests were approved by the PMACWA after an initial assessment of each technology. The results of that initial assessment were reviewed by an earlier NRC committee, the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (the ACW I committee).

For the present review, the committee conducted an indepth examination of each technology provider''s data, analyses, and demonstration test results for the critical components tested. This review report supplements the ACW I report and considers the demonstration performance of the Demo II candidate technologies and their readiness for advancement to pilot-scale implementation. Because testing in these areas is ongoing, the committee decided to cut short its fact-finding efforts for input to this report as of March 30, 2001.

The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee''s scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo.

The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.

The U.S. Army is in the process of destroying the nation''s stockpile of aging chemical weapons stored at eight locations in the continental United States and on Johnston Atoll in the Pacific. Originally, incineration was chosen for the destruction of these stores, but this method has met with public opposition, and Congress directed the Army to develop alternative technologies for destroying the stockpiles in Pueblo, CO and Richmond, KY. To assist the Army in this process, the NRC was asked to evaluate the engineering design study of the three Blue Grass candidates. This book presents an analysis of various issues pertaining to the proposed engineering design package for the Blue Grass facility.

The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee''s scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo.

The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.

By direction of Congress, the U.S. Department of Defense''s (DoD''s) program manager for the Assembled Chemical Weapons Assessment (PMACWA) asked the National Research Council (NRC) Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (the ACW II committee) to conduct an independent scientific and technical assessment of three alternative technologies (referred to as Demo II) under consideration for the destruction of assembled chemical weapons at U.S. chemical weapons storage sites. The three technologies are AEA Technologies Corporation''s (AEA''s) electrochemical oxidation process; the transpiring-wall supercritical water oxidation and gasphase chemical reduction processes of Foster Wheeler/Eco Logic/Kvaerner (FW/EL/K); and Teledyne-Commodore''s solvated electron process. Each of these technologies represents an alternative to incineration for the complete destruction of chemical agents and associated energetic materials. The demonstration tests were approved by the PMACWA after an initial assessment of each technology. The results of that initial assessment were reviewed by an earlier NRC committee, the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (the ACW I committee).

For the present review, the committee conducted an indepth examination of each technology provider''s data, analyses, and demonstration test results for the critical components tested. This review report supplements the ACW I report and considers the demonstration performance of the Demo II candidate technologies and their readiness for advancement to pilot-scale implementation. Because testing in these areas is ongoing, the committee decided to cut short its fact-finding efforts for input to this report as of March 30, 2001.