This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 59 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers.The chapters of this volume are devoted to the following topics:• Iron Catalysis in Synthetic Chemistry• A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites• Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA.• Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide• Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity• Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals• Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations