Applications of Metal-Organic Frameworks and Their Derived Materials

Inamuddin, PhD, is an assistant professor at King Abdulaziz University, Jeddah, Saudi Arabia and is also an assistant professor in the Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India. He has published about 150 research articles in various international scientific journals, 18 book chapters, and 60 edited books with multiple well-known publishers. Rajender Boddula, PhD, is currently working for the Chinese Academy of Sciences President's International Fellowship Initiative (CAS-PIFI) at the National Center for Nanoscience and Technology (NCNST, Beijing). He has numerous honors, book chapters, and academic papers to his credit and is an editorial board member and a referee for several reputed international peer-reviewed journals. Mohd Imran Ahamed, PhD, received his PhD from Aligarh Muslim University, Aligarh, India in 2019. He has published several research and review articles in various international scientific journals, and his research work includes ion-exchange chromatography, wastewater treatment, and analysis, bending actuator and electrospinning. Abdullah M. Asiri is the Head of the Chemistry Department at King Abdulaziz University and the founder and Director of the Center of Excellence for Advanced Materials Research (CEAMR). He is the Editor-in-Chief of the King Abdulaziz University Journal of Science. He has received numerous awards, and serves on the editorial boards of multiple scientific journals and is the Vice President of the Saudi Chemical Society (Western Province Branch). He holds multiple patents, has authored ten books, more than one thousand publications in international journals, and multiple book chapters.

• Preface xiii1 Application of MOFs and Their Derived Materials in Sensors 1Yong Wang, Chang Yin and Qianfen Zhuang1.1 Introduction 11.2 Application of MOFs and Their Derived Materials in Sensors 31.2.1 Optical Sensor 31.2.1.1 Colorimetric Sensor 31.2.1.2 Fluorescence Sensor 71.2.1.3 Chemiluminescent Sensor 111.2.2 Electrochemical Sensor 131.2.2.1 Amperometric Sensor 131.2.2.2 Impedimetric, Electrochemiluminescence, and Photoelectrochemical Sensor 161.2.3 Field-Effect Transistor Sensor 191.2.4 Mass-Sensitive Sensor 211.3 Conclusion 22Acknowledgments 23References 232 Applications of Metal–Organic Frameworks (MOFs) and Their Derivatives in Piezo/Ferroelectrics 33H. Manjunatha, K. Chandra Babu Naidu, N. Suresh Kumar, Ramyakrishna Pothu and Rajender Boddula2.1 Introduction 342.1.1 Brief Introduction to Piezo/Ferroelectricity 342.2 Fundamentals of Piezo/Ferroelectricity 342.3 Metal–Organic Frameworks for Piezo/Ferroelectricity 402.4 Ferro/Piezoelectric Behavior of Various MOFs 402.5 Conclusion 52References 533 Fabrication and Functionalization Strategies of MOFs and Their Derived Materials “MOF Architecture” 63Demet Ozer3.1 Introduction 633.2 Fabrication and Functionalization of MOFs 653.2.1 Metal Nodes 653.2.2 Organic Linkers 683.2.3 Secondary Building Units 763.2.4 Synthesis Methods 773.2.4.1 Hydrothermal and Solvothermal Method 773.2.4.2 Microwave Synthesis 783.2.4.3 Electrochemical Method 803.2.4.4 Mechanochemical Synthesis 813.2.4.5 Sonochemical (Ultrasonic Assisted) Method 813.2.4.6 Diffusion Method 823.2.4.7 Template Method 823.2.5 Synthesis Strategies 833.3 MOF Derived Materials 893.4 Conclusion 90References 904 Application of MOFs and Their Derived Materials in Molecular Transport 101Arka Bagchi, Partha Saha, Arunima Biswas and SK Manirul Islam4.1 Introduction 1024.2 MOFs as Nanocarriers for Membrane Transport 1024.2.1 MIL-89 1034.2.2 MIL-88A 1034.2.3 MIL-100 1044.2.4 MIL-101 1044.2.5 MIL-53 1044.2.6 ZIF-8 1044.2.7 Zn-TATAT 1054.2.8 BioMOF-1 (Zn) 1054.2.9 UiO (Zr) 1054.3 Conclusion 106References 1065 Role of MOFs as Electro/-Organic Catalysts 109Manorama Singh, Ankita Rai, Vijai K. Rai, Smita R. Bhardiya and Ambika Asati5.1 What Is MOFs 1095.2 MOFs as Electrocatalyst in Sensing Applications 1115.3 MOFs as Organic Catalysts in Organic Transformations 1145.4 Conclusion and Future Prospects 115References 1166 Application of MOFs and Their Derived Materials in Batteries 121Rituraj Dutta and Ashok Kumar6.1 Introduction 1226.2 Metal–Organic Frameworks 1266.2.1 Classification and Properties of Metal–Organic Frameworks 1276.2.2 Potential Applications of MOFs 1306.2.3 Synthesis of MOFs 1336.3 Polymer Electrolytes 1356.3.1 Historical Perspectives and Classification of Polymer Electrolytes 1366.3.2 MOF Based Polymer Electrolytes 1396.4 Ionic Liquids 1426.4.1 Properties of Ionic Liquids 1436.4.2 Ionic Liquid Incorporated MOF 1456.5 Ion Transport in Polymer Electrolytes 1476.5.1 General Description of Ionic Conductivity 1476.5.2 Models for Ionic Transport in Polymer Electrolytes 1486.5.3 Impedance Spectroscopy and Ionic Conductivity Measurements 1526.5.4 Concept of Mismatch and Relaxation 1556.5.5 Scaling of ac Conductivity 1566.6 IL Incorporated MOF Based Composite Polymer Electrolytes 1576.7 Conclusion and Perspectives 166References 1687 Fine Chemical Synthesis Using Metal–Organic Frameworks as Catalysts 177Aasif Helal7.1 Introduction 1777.2 Oxidation Reaction 1797.2.1 Epoxidation 1797.2.2 Sulfoxidation 1817.2.3 Aerobic Oxidation of Alcohols 1827.3 1,3-Dipolar Cycloaddition Reaction 1837.4 Transesterification Reaction 1837.5 C–C Bond Formation Reactions 1847.5.1 Heck Reactions 1847.5.2 Sonogashira Coupling 1867.5.3 Suzuki Coupling 1867.6 Conclusion 187References 1878 Application of Metal Organic Framework and Derived Material in Hydrogenation Catalysis 193Tejaswini Sahoo, Jagannath Panda, Jnana Ranjan Sahu and Rojalin Sahu8.1 Introduction 1938.1.1 The Active Centers in Parent MOF Materials 1958.1.2 The Active Centers in MOF Catalyst 1958.1.3 Metal Nodes 1968.2 Hydrogenation Reactions 1978.2.1 Hydrogenation of Alpha–Beta Unsaturated Aldehyde 1978.2.2 Hydrogenation of Cinnamaldehyde 1988.2.3 Hydrogenation of Nitroarene 1998.2.4 Hydrogenation of Nitro Compounds 2018.2.5 Hydrogenation of Benzene 2028.2.6 Hydrogenation of Quinoline 2058.2.7 Hydrogenation of Carbon Dioxide 2068.2.8 Hydrogenation of Aromatics 2078.2.9 Hydrogenation of Levulinic Acid 2078.2.10 Hydrogenation of Alkenes and Alkynes 2088.2.11 Hydrogenation of Phenol 2108.3 Conclusion 210References 2119 Application of MOFs and Their Derived Materials in Solid-Phase Extraction 219Adrián Gutiérrez-Serpa, Iván Taima-Mancera, Jorge Pasán, Juan H. Ayala and Verónica Pino9.1 Solid-Phase Extraction 2209.1.1 Materials in SPE 2239.2 MOFs and COFs in Miniaturized Solid-Phase Extraction (μSPE) 2259.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-μSPE) 2329.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-μSPE) 2399.5 Concluding Remarks 249Acknowledgments 249References 24910 Anticancer and Antimicrobial MOFs and Their Derived Materials 263Nasser Mohammed Hosny10.1 Introduction 26310.2 Anticancer MOFs 26410.2.1 MOFs as Drug Carriers 26410.2.2 MOFs in Phototherapy 26910.3 Antibacterial MOFs 27210.4 Antifungal MOFs 278References 28011 Theoretical Investigation of Metal–Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Personal Care Products 287Jagannath Panda, Satya Narayan Sahu, Tejaswini Sahoo, Biswajit Mishra, Subrat Kumar Pattanayak and Rojalin Sahu11.1 Introduction 28811.2 General Synthesis Routes 29011.2.1 Hydrothermal Synthesis 29511.2.2 Solvothermal Synthesis of MOFs 29611.2.3 Room Temperature Synthesis 29611.2.4 Microwave Assisted Synthesis 29611.2.5 Mechanochemical Synthesis 29711.2.6 Electrochemical Synthesis 29711.3 Postsynthetic Modification in MOF 29711.4 Computational Method 29711.5 Results and Discussion 29911.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone) 29911.6 Conclusion 303References 30412 Metal–Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds 313Shella Permatasari Santoso, Artik Elisa Angkawijaya, Vania Bundjaja, Felycia Edi Soetaredjo and Suryadi Ismadji12.1 Introduction 31412.2 VOCs and Their Potential Hazards 31512.2.1 Other Sources of VOCs 31912.3 VOCs Removal Techniques 32012.4 Fabricated MOF for VOC Removal 32412.4.1 MIL Series MOFs 32512.4.2 Isoreticular MOFs 32712.4.2.1 Adsorption Comparison of the Isoreticular MOFs 33012.4.3 NENU Series MOFs 33212.4.4 MOF-5, Eu-MOF, and MOF-199 33312.4.5 Amine-Impregnated MIL-100 33412.4.6 Biodegradable MOFs MIL-88 Series 33512.4.7 Catalytic MOFs 33512.4.8 Photo-Degradating MOFs 33612.4.9 Some Other Studied MOFs 33712.5 MOF Composites 33812.5.1 MIL-101 Composite With Graphene Oxide 33812.5.2 MIL-101 Composite With Graphite Oxide 33812.6 Generalization Adsorptive Removal of VOCs by MOFs 34012.7 Simple Modeling the Adsorption 34012.7.1 Thermodynamic Parameters 34012.7.2 Dynamic Sorption Methods 34112.8 Factor Affecting VOCs Adsorption 34412.8.1 Breathing Phenomena 34412.8.2 Activation of MOFs 34512.8.3 Applied Pressure 34612.8.4 Relative Humidity 34712.8.5 Breakthrough Conditions 34712.8.6 Functional Group of MOFs 34712.8.7 Concentration, Molecular Size, and Type of VOCs 34812.9 Future Perspective 349References 35013 Application of Metal–Organic Framework and Their Derived Materials in Electrocatalysis 357Gopalram Keerthiga, Peramaiah Karthik and Bernaurdshaw NeppolianList of Abbreviations 35813.1 Introduction 35813.2 Perspective Synthesis of MOF , and Their Derived Materials 36013.3 MOF for Hydrogen Evolution Reaction 36213.4 MOF for Oxygen Evolution Reaction 36313.5 MOF for Oxygen Reduction Reaction 36513.6 MOF for CO2 Electrochemical Reduction Reaction 36613.6.1 Electrosynthesis of MOF for CO2 Reduction 36613.6.2 Composite Electrodes as MOF for CO2 Reduction 36713.6.3 Continuous Flow Reduction of CO2 36913.6.4 CO2 Electrochemical Reduction in Ionic Liquid 36913.7 MOF for Electrocatalytic Sensing 37013.8 Electrocatalytic Features of MOF 37113.9 Conclusion 372Acknowledgment 372References 37214 Applications of MOFs and Their Composite Materials in Light-Driven Redox Reactions 377Elizabeth Rojas-García, José M. Barrera-Andrade, Elim Albiter, A. Marisela Maubert and Miguel A. Valenzuela14.1 Introduction 37814.1.1 MOFs as Photocatalysts 38114.1.2 Charge Transfer Mechanisms 38214.1.3 Methods of Synthesis 38514.2 Pristine MOFs and Their Application in Photocatalysis 38714.2.1 Group 4 Metallic Clusters 38714.2.2 Groups 8, 9, and 10 Metallic Clusters 39314.2.3 Group 11 Metallic Clusters 39314.2.4 Group 12 Metallic Clusters 40314.3 Metal Nanoparticles–MOF Composites and Their Application in Photocatalysis 41314.3.1 Ag–MOF Composites 41514.3.2 Au–MOF Composites 41714.3.3 Cu–MOF Composites 41714.3.4 Pd–MOF Composites 41814.3.5 Pt–MOF Composites 41914.4 Semiconductor–MOF Composites and Their Application in Photocatalysis 42114.4.1 TiO2–MOF Composites 42214.4.2 Graphitic Carbon Nitride–MOF Composites 42614.4.3 Bismuth-Based Semiconductors 42914.4.4 Reduced Graphene Oxide–MOF Composites 43014.4.5 Silver-Based Semiconductors 43614.4.6 Other Semiconductors 43814.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis 44214.5.1 Semiconductor–Semiconductor–MOF Composites 44214.5.2 Semiconductor–Metal–MOF Composites 44314.6 Conclusions 446References 448Index 463