Smart Materials Series – serie

Traditionally, most synthetically developed materials are hardened by heating them to an elevated temperature, a process requiring large amounts of energy and space. Interest in photo cured materials using UV-light is growing due to simplifications in manufacturing and growing environmental concerns; it is expected photocuring could reduce electricity consumption by 90% compared to traditional curing. Photocured materials also reduce evaporation of volatile organic components, curing time and waste, thereby enhancing productivity and reducing work space.The materials technologies based on photocuring are gaining momentum, and this will be the first book to provide an in-depth focus on the subject. This book summarises the fundamentals required to understand the field, characterises the use of novel materials and the development of synthetic aspects, and discusses the future of the technology.The comprehensive review chapters are suitable for a broad readership from diverse backgrounds including chemistry, physics, materials science and engineering, medical science, pharmacy, biotechnology and biomedical engineering. Photocured Materials will be of interest to students, researchers, scientists, engineers and professors.

There is great interest in metallosupramolecular materials because of their use in magnetic, photonic and electronic materials. Functional Metallosupramolecular Materials focuses on the applications of these materials covering the chemistry underlying the synthesis of a variety of ligands to coordinate various metal ions and the generation of 2D and 3D materials based on these constructs.The book starts by looking at different metallosupramolecular systems including naturally occurring functional metallosupramolecular materials; DNA-based metallosupramolecular materials; metallopolymers; metallogels as well as functional materials based on MOFs. Subsequent chapters then systematically cover the different applications such as molecular computation, spin-crossover, light harvesting and as photocatalysts for the production of solar fuels.The book provides an overview of functional metallosupramolecular materials that will be of interest to graduate students, academics and industrial chemists interested in supramolecular chemistry, materials science and the materials applications.

Smart materials stimulated by chemical or biological signals are of interest for their many applications including drug delivery, as well as in new sensors and actuators for environmental monitoring, process and food control, and medicine. In contrast to other books on responsive materials, this volume concentrates on materials which are stimulated by chemical or biological signals. Chemoresponsive Materials introduces the area with chapters covering different responsive material systems including hydrogels, organogels, membranes, thin layers, polymer brushes, chemomechanical and imprinted polymers, nanomaterials, silica particles, as well as carbohydrate- and bio-based systems. Many promising applications are highlighted, with an emphasis on drug delivery, sensors and actuators. With contributions from internationally known experts, the book will appeal to graduate students and researchers in academia, healthcare and industry interested in functional materials and their applications.

The development of smart materials for environmental applications is a highly innovative and promising new approach to meet the increasing demands from society on water resources and pollution remediation. Smart materials with surfaces that can reversibly respond to stimuli from internal and external environments by changing their properties show great promise as solutions for global environmental issues. Many of these functional materials are inspired by biological systems, that use sophisticated material interfaces to display high levels of adaptability to their environment. Leading researchers present the latest information on the current and potential applications of omniphobic slippery coatings, responsive particle stabilized emulsions and self-healing surfaces among other functional materials. The book contains a section dedicated to water treatment and harvesting, describing and explaining strategies such as use of copolymer membranes and surfaces with patterned wettability. It provides a valuable source of information for environmental, materials, polymer and nano-scientists interested in environmental applications of functional material surfaces.

Recent years have seen fast development in the field of self-cleaning coatings towards varied applications, such as solar cells, flat display panels, smart cellular phones, building windows, oil pipelines, vehicle coatings and optical devices. The field has been rapidly gaining attention, not only from research and teaching scientists, but also from a growing population of college and graduate students. Self-cleaning coatings describes this interesting field, providing details of natural counterparts with self-cleaning functions, theoretical aspects of self-cleaning phenomena, fabrication strategies and methods, applications and industrial impacts. Edited and written by world-renowned scientists in the field, this book will provide an excellent overview of this field and will be of interest to materials and polymer scientists working in industry and academia.

Conducting polymers are organic, conjugated materials that offer high electrical conductivity through doping by oxidation and a wide range of unique electromechanical and electrochromic characteristics. These properties can be reversibly tuned through electrochemical reactions, making this class of materials good biomimetic models and ideal candidates for the development of novel flexible and transparent sensing devices.This book comprehensively summarises the current and future applications of conducting polymers, with chapters focussing on electrosynthesis strategies, theoretical models for composition dependent allosteric and structural changes, composition dependent biomimetic properties, novel biomimetic devices and future developments of zoomorphic and anthropomorphic tools.Written by an expert researcher working within the field, this title will have broad appeal to materials scientists in industry and academia, from postgraduate level upwards.

Polymer-clay nanocomposites have flame-retardant, antimicrobial, anticorrosion and self-healing properties, they are biocompatible and environmentally benign. Multiple types of clay minerals may be exfoliated or individually dispersed and then used as natural nanoparticle additives of different size and shape for composite formation. Loading polymers with clays increases their strength, however, it is only recently that such composites were prepared with controlled nanoscale organization allowing for the enhancement of their mechanical properties and functionality. Edited by pioneers in the field, this book will explain the great potential of these materials and will bring together the combined physico-chemical, materials science and biological expertise to introduce the reader to the vibrant field of nanoclay materials. This book will provide an essential text for materials and polymers scientists in industry and academia.

In recent years there has been tremendous progress in the area of tissue engineering research. This book focusses on the fundamental principles underpinning these recent advances in the materials science developed for tissue engineering purposes. Smart materials for tissue engineering are produced by modifying the physicochemical and biological properties of the scaffolds with response to external stimuli to enhance the tissue regeneration. The functions of living cells can be regulated by smart materials which respond to changes in the surrounding microenvironment. This book comprehensively documents the recent advancements in smart materials for tissue engineering and will provide an essential text for those working in materials science and materials engineering, in academia and industry.

Inorganic 2D nanomaterials, or inorganic graphene analogues, are gaining great attention due to their unique properties and potential energy applications. They contain ultrathin nanosheet morphology with one-dimensional confinement, but unlike pure carbon graphene, inorganic two-dimensional nanomaterials have a more abundant elemental composition and can form different crystallographic structures. These properties contribute to their unique chemical reaction activity, tunable physical properties and facilitate applications in the field of energy conversion and storage.Inorganic Two-dimensional Nanomaterials details the development of the nanostructures from computational simulation and theoretical understanding to their synthesis and characterization. Individual chapters then cover different applications of the materials as electrocatalysts, flexible supercapicitors, flexible lithium ion batteries and thermoelectrical devices.The book provides a comprehensive overview of the field for researchers working in the areas of materials chemistry, physics, energy and catalysis.

Ionic polymer metal composites (IPMCs) can generate a voltage when physically deformed. Conversely, an applied small voltage or electrical field can induce an array of spectacular large deformation or actuation behaviours in IPMCs, such as bending, twisting, rolling, twirling, steering and undulating. An important smart material, IPMCs have applications in energy harvesting and as self-powered strain or deformation sensors, especially suitable for monitoring the shape of dynamic structures. Other uses include soft actuation applications and as a material for biomimetic robotic soft artificial muscles in industrial and medical contexts. This comprehensive set on ionic polymer metal composites provides a broad coverage of the state of the art and recent advances in the field written by some of the world’s leading experts on various characterizations and modeling of IPMCs. The first two chapters cover the fundamentals of IPMCs and methodologies for their manufacture, followed by specific chapters looking at different aspects of actuation and sensing of IPMCs. These include uses in electrochemically active electrodes, electric energy storage devices, soft biomimetic robotics artificial muscles, multiphysics modeling of IPMCs, biomedical applications, IPMCs as dexterous manipulators and tactile sensors for minimally invasive robotic surgery, self-sensing, miniature pumps for drug delivery, IPMC snake-like robots, IPMC microgrippers for microorganisms manipulations, Graphene-based IPMCs and cellulose-based IPMCs or electroactive paper actuators (EAPap). Edited by the leading authority on IMPCs, the broad coverage of this book will appeal to researchers from chemistry, materials, engineering, physics and medical communities interested in both the material and its applications.

Reactive inkjet printing uses an inkjet printer to dispense one or more reactants onto a substrate to generate a physical or chemical reaction to form a product in situ. Thus, unlike traditional inkjet printing, the printed film chemistry differs to that of the initial ink droplets. The appeal of reactive inkjet printing as a chemical synthesis tool is linked to its ability to produce droplets whose size is both controllable and predictable, which means that the individual droplets can be thought of as building blocks where droplets can be added to the substrate in a high precision format to give good control and predictability over the chemical reaction.The book starts by introducing the concept of using reactive inkjet printing as a building block for making materials. Aspects such as the behaviour of printed droplets on substrate and their mixing is discussed in the first chapters. The following chapters then discuss different applications of the technique in areas including additive manufacturing and silk production, production of materials used in solar cells, printed electronics, dentistry and tissue engineering.Edited by two leading experts, Reactive Inkjet Printing: A Chemical Synthesis Tool provides a comprehensive overview of this technique and its use in fabricating functional materials for health and energy applications. The book will appeal to advanced level students in materials science.

Magnetic nanomaterials have undergone a significant evolution during the past decade, with supramolecular nanoparticle organization reaching unprecedented levels of complexity and the materials providing new approaches to treating cancer. Magnetic Nanomaterials will provide a comprehensive overview of the latest research in the area of magnetic nanoparticles and their broad applications in synthesis, catalysis and theranostics.The book starts with an introduction to magnetism in nanomaterials and magnetic nanoparticle design followed by individual chapters which focus on specific uses. Applications covered include drug delivery, theranostic agents for cancer treatment as well as catalysis, biomass conversion and catalytic enhancement of NMR sensitivity.The reader will have the opportunity to learn about the frontier of magnetic nanotechnology from scientists that have shaped this unique and highly collaborative field of research. Written and edited by experts working within the field across the world, this book will appeal to students and researched interested in nanotechnology, engineering and physical sciences.

Nanogel-based systems have gained tremendous attention due to their diverse range of applications in tissue engineering, regenerative medicine, biosensors, orthopaedics, wound healing and drug delivery. Nanogels for Biomedical Applications provides a comprehensive overview of nanogels and their use in nanomedicine.The book starts with the synthesis, methods and characterization techniques for nanogel-based smart materials followed by individual chapters demonstrating the different uses of the materials. Applications covered include anticancer therapy, tuberculosis diagnosis and treatment, tissue engineering, gene delivery and targeted drug delivery.The book will appeal to biologists, chemists, and nanotechnologists interested in translation research for personalized nanomedicine for health care.

The applications of ionic liquids can be enormously expanded by arranging the organic ions in the form of a polymer architecture. Polymerized ionic liquids (PILs), also known as poly(ionic liquid)s or polymeric ionic liquids, provide almost all features of ionic polymers plus a rare versatility in design. The mechanical properties of the solid or solid-like polymers can also be controlled by external stimuli, the basis for designing smart materials.Known for over four decades, PILs are a member of the ionic polymers family. Although the previous forms of ionic polymers have a partial ionicity, PILs are entirely composed of ions. Therefore, they offer a better flexibility for designing a responsive architecture as smart materials. Despite the terminology, PILs can be synthesized from solid organic ionic salts since the monomer liquidity is not a requirement for the polymerization process. Ionicity can also be induced to a neutral polymer by post-polymerization treatments.This is indeed an emerging field whose capabilities have been somehow overshadowed by the popularity of ionic liquids. However, recent reports in the literature have shown impressive potentials for the future. Written by leading authors, the present book provides a comprehensive overview of this exciting area, discussing various aspects of PILs and their applications as smart materials. Owing to the novelty of this area of research, the book will appeal to a broad readership including students and researchers from materials science, polymer science, chemistry, and physics.

The global ageing society has significantly increased the need for implant materials, which not only replace damaged or lost tissue but are also able to regenerate it. The field of bioactive glasses has been expanding continuously over recent years as they have been shown to bond with hard and soft tissue, release therapeutically active ions, and be capable of enhancing bone formation and regeneration. In addition, they are successfully being used to re-mineralise teeth, thereby making bioactive glasses highly attractive materials in both dentistry and medicine. Understanding the multidisciplinary requirements set by the human body’s environment and the special characteristics of the different families of bioactive glasses is a key in developing new compositions to novel clinical applications. Bioactive Glasses aims to bridge the different scientific communities associated with the field of bioactive glasses with focus on the materials science point of view.  Emerging applications covered include soft tissue regeneration, wound healing, vascularisation, cancer treatment and drug delivery devices. This book provides a comprehensive overview of the latest applications of bioactive glasses for material scientists.

In recent years there has been tremendous progress in the area of tissue engineering research. This two-volume set, containing Smart Materials for Tissue Engineering: Fundamental Principles and Smart Materials for Tissue Engineering: Applications, provides a complete overview of the field. Volume one covers the fundamental principles underpinning the materials science developed for enhancing tissue regeneration, as well as those used for regulating the functions of living cells. Volume two focuses on the applications of different materials for replacing or facilitating tissue regeneration. It also provides examples of new materials that have been developed to control cell behaviours and tissue formation by biomimetic topography which closely replicate the natural extracellular matrix. This set comprehensively documents the recent advancements in smart materials for tissue engineering and provides an essential text for those working in materials science and materials engineering, in academia and industry.Please see the webpages for the individual volumes in the set to access the eBook versions.

Interest in and attention on electrochromic technology has been growing since the 1970s, with the advent of numerous electrochromic devices in commercial and industrial settings. Many laboratory-based colour-changing electrochromic device prototypes have surfaced following research breakthroughs in recent years, and the consumer market has been expanding continuously. Electrochromic devices have a wide range of applications, such as displays, self-dimming mirrors for automobiles, electrochromic e-skins, textiles, and smart windows for energy-efficient buildings. Electrochromic Smart Materials covers major topics related to the phenomenon of electrochromism, including fundamental principles, different classes and subclasses of electrochromic materials, and device processing and manufacturing. It also highlights a broad range of existing and potential applications of electrochromic devices, with an analysis of the current market needs and future trends. Providing a comprehensive overview of the field, this book will serve as introductory reading to those new to this area, as well as a resource providing detailed, in-depth knowledge and insights to the seasoned audience. Featuring contributions from researchers across the globe, it will be of interest to postgraduate students and researchers in both academia and industry interested in smart design, materials science and engineering.

Polyurethane nanocomposites present an attractive and sustainable way for designing smart materials that can be used in packaging, health and energy applications.Biobased Smart Polyurethane Nanocomposites brings together the most recent research in the field from the basic concepts through to their applications. Special emphasis is given to sustainable biodegradable polyurethane nanocomposites with hyperbranched architecture. The book introduces biobased polyurethanes and the nanomaterials that can be used as nanocomposites followed by the resulting polyurethane nanocomposites. The second part then explores important applications in paints and surface coatings, shape memory, self-healing, self-cleaning, biomaterials and packaging materials.Written by a leading expert on polyurethane nanocomposites, the book is a great introduction to this smart material and its applications.

Ionic liquids are attractive because they offer versatility in the design of organic salts. As ion-rich media, ionic liquids can control the systems properties by tuning the size, charge, and shape of the composing ions. Whilst the focus has mainly been on the potential applications of ionic liquids as solvents, they also provide innovative opportunities for designing new systems and devices. Limitations from the high viscosity and expensive purification of the ionic liquids are also not a barrier for applications as devices.Written by leading authors, Ionic Liquid Devices introduces the innovative applications of ionic liquids. Whilst the first chapters focus on their characterization, which can be difficult in some instances, the rest of the book demonstrates how ionic liquids can play substantial roles in quite different systems from sensors and actuators to biomedical applications.The book provides a comprehensive resource aimed at researchers and students in materials science, polymer science, chemistry and physics interested in the materials and inspire the discovery of new applications of ionic liquids in smart devices.

The considerable interest in graphene and 2D materials is sparking intense research on layered materials due to their unexpected physical, electronic, chemical, and optical properties. This book will provide a comprehensive overview of the recent and state-of-the-art research progress on layered materials for energy storage and other applications. With a brief introduction to layered materials, the chapters of this book gather various fascinating topics such as electrocatalysis for fuel cells, lithium-ion batteries, sodium-ion batteries, photovoltaic devices, thermoelectric devices, supercapacitors and water splitting. Unique aspects of layered materials in these fields, including novel synthesis and functionalization methods, particular physicochemical properties and consequently enhanced performance are addressed. Challenges and perspectives for layered materials in these fields will also be presented. With contributions from key researchers, Layered Materials for Energy Storage and Conversion will be of interest to students, researchers and engineers worldwide who want a basic overview of the latest progress and future directions.

Smart materials constructed through supramolecular assemblies have been receiving considerable attention because of their potential applications, which include self-healing materials, energy storage, photonic devices, sensors and theranostics. Host–guest chemistry of various macrocyclic receptors with organic guests provides a unique way to control tailor-made nanoarchitectures for the formation of pre-designed functional materials. Cucurbituril-based Function Materials provides an overview of this fascinating macrocycle, cucurbituril (CB) homologues and derivatives-based supramolecular nanostructured materials. Chapters cover the synthesis, properties and application of CB-based smart materials and nanostructures. With contributions from key researchers, this book will be of interest to students and researchers working in materials science, as well as those working on cucurbituril-based materials in organic and physical chemistry.

Ambipolar materials represent a class of materials where positive and negative charge carriers can both transport concurrently. In recent years, a diverse range of materials have been synthesized and utilized for implementing ambipolar charge transport, with applications in high‐density data storage, field effect transistors, nanotransitors, photonic memory, biomaterial-based memories and artificial synapses. This book highlights recent development of ambipolar materials involving materials design, fundamental principles, interface modifications, device structures, ambipolar characteristics and promising applications. Challenges and prospects for investigating ambipolar materials in electronics and optoelectronics are also discussed. With contributions from global leaders in the field, this title will appeal to graduate students and researchers who want to understand the design, materials characteristics, device operation principles, specialized device application and mechanisms of the latest ambipolar materials.

Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.

Porphyrinoids are pyrrole-containing macrocycles with varied core sizes, which have found many applications beyond the original chemical and biological aspects. Porphyrin research has a long history, covering a wide variety of disciplines of natural sciences, including photosynthesis, P450-related biocatalysis, organic photovoltaic cells, photodynamic therapeutic agents, bioimaging probes, chemosensors, conductive organic materials, light-emitting materials, near-infrared dyes, nonlinear optical materials, information storage, molecular wires, and metal ligands. This book gives an overview of the applications and potential applications of porphyrins and related macrocycles as smart or functional materials. Chapters cover applications in fields such as energy storage and transfer, water purification, molecular electronics and imaging. With contributions from leading global researchers, this title will be of interest to graduate students and researchers across materials science, chemistry, physics and medicine.

Smart materials stimulated by chemical or by logical signals hold promise for many applications, including new sensors and actuators for medicine, environmental and process control. In contrast to other books on responsive materials which are restricted to sensing, this volume not only highlights fundamental chemical and physical principles but also focuses on the use of smart materials for applications such as drug delivery, wound healing, cell adhesion, tuneable vesicles, surface control, smart paints and glasses, separations, oil recovery and artificial muscles. In this completely updated and expanded edition, readers are introduced to the area with chapters reflecting the enormous expansion of the field in recent years. Different responsive material systems will be covered including hydrogels, membranes, thin layers, polymer brushes, chemomechanical and imprinted polymers, nanomaterials and silica particles. With contributions from internationally recognised experts, the book will appeal to graduate students and researchers in academia, healthcare and industry interested in functional materials and their applications.

In recent years, the use of renewable raw materials and natural biopolymers has increased significantly to overcome the issues associated with environmental pollution and dwindling fossil fuel resources. Lipids and proteins are inexpensive, renewable raw materials, which are considered ideal feedstock for the development of a variety of functional materials. This book provides an international viewpoint on recent developments in the utilisation of lipids and proteins together, for the development of functional materials in food engineering, environmental and industry applications. This book presents the cutting-edge research in the utilization of lipids and proteins in food, cosmetics, therapeutics, food packaging, water remediation, biofuels, lubricants, biomaterials, and composite preparations. Researchers, scientists, engineers and students working on lipids and proteins derived materials will benefit from this book, which is highly application oriented. Focusing on the latest developments in the field, this will be the first book to describe lipids and proteins together, allowing it to act as a single reference for researchers working in this area.

Named after the two-faced roman god, Janus particles have gained much attention due to their potential in a variety of applications, including drug delivery. This is the first book devoted to Janus particles and covers their methods of synthesis, how these particles self-assemble, and their possible uses. By following the line of synthesis, self-assembly and applications, the book not only covers the fundamental and applied aspects, but it goes beyond a simple summary and offers a logistic way of selecting the proper synthetic route for Janus particles for certain applications. Written by pioneering experts in the field, the book introduces the Janus concept to those new to the topic and highlights the most recent research progress on the topic for those active in the field.

Smart materials, which can change properties when an external stimulus is applied, can be used for the targeted drug delivery of an active molecule to a specific site in the correct dosage. Different materials such as liposomes, polymeric systems, nanomaterials and hydrogels can respond to different stimuli such as pH, temperature and light and these are all attractive for controlled release applications.With so many papers available on smart and stimuli-responsive materials for drug delivery applications it's hard to know where to start reading about this exciting topic. In two volumes, Smart Materials for Drug Delivery brings together the recent findings in the area and provides a critical analysis of the different materials available and how they can be applied to advanced drug delivery systems.With contributions from leading experts in the field, including a foreword from distinguished scientist Nicholas Peppas, The University of Texas at Austin, USA, the book will provide both an introduction to the key areas for graduate students and new researchers in the stimuli-responsive field as well as serving as a reference for those already working on fundamental materials research or drug delivery applications.

The inner architecture of a material can have an astonishing effect on its overall properties and is vital to understand when designing new materials. Nature is a master at designing hierarchical structures and so researchers are looking at biological examples for inspiration, specifically to understand how nature arranges the inner architectures for a particular function in order to apply these design principles into man-made materials. Materials Design Inspired by Nature is the first book to address the relationship between the inner architecture of natural materials and their physical properties for materials design. The book explores examples from plants, the marine world, arthropods and bacteria, where the inner architecture is exploited to obtain specific mechanical, optical or magnetic properties along with how these design principles are used in man-made products. Details of the experimental methods used to investigate hierarchical structures are also given.Written by leading experts in bio-inspired materials research, this is essential reading for anyone developing new materials.