Reactivity and Structure: Concepts in Organic Chemistry – serie
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29 produkter
d-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur
Häftad, 2012
1084 kr
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This book was undertaken for the purpose of bringing together the widely diverse lines of experimental work and thinking which has been expressed but has often been unheard on the title question. It will be clear to the reader that a critical viewpoint has been maintained in assembling the material …
Phase Transfer Catalysis in Organic Synthesis
Av William P. Weber, George W. Gokel
Häftad, 2012
1084 kr
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The field of phase transfer catalysis is a tribute to the chemists involved in process development research. Phase transfer catalysis is a solution to numerous cost and yield problems encountered regularly in industrial laboratories. In fact, much of the early work in this area was conducted by …
Chemistry of Rotational Isomers
Häftad, 2012
546 kr
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Rotation about the Carbon-Carbon single bond is generallyregarded to be unrestricted. About 50 years ago, rotationalisomers were found to exhibit optical activity: substitutedbiphenyl derivatives. However, the author has investigatedother classes of compounds that have stable rotationalisomers at …
Theory of Orientation and Stereoselection
Av K. Fukui
Häftad, 2012
546 kr
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Many organic chemists will agree with me that the old "electronic theory" has for a long time been inadequate for the interpretation of various new findings in chemistry, particularly for those of reactivity. Considering the outstanding progress which has been made during the past 20 years in the …
Organic Synthesis by Means of Transition Metal Complexes
A Systematic Approach
Av Jiro Tsuji
Häftad, 2011
1084 kr
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In 1970 I wrote a review article for "Topics in Current Chemistry", surveying the general reaction patterns of transition-metal complexes from the standpoint of organic synthesis. The article seems to have evoked wide interest, and I therefore thought it appropriate to treat the subject more …
Cyclodextrin Chemistry
Häftad, 2011
546 kr
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Chemistry was at one time completely described in terms of collision theo ry, in which one molecule collided with another, sometimes producing reac tion. Then came the realization that enzymes which are highly efficient ca talysts, work by way of prior complexation, often stereospecific, which …
Free Radicals in Organic Synthesis
Av D. I. Davies, M. J. Parrott
Häftad, 2011
1084 kr
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Free Radical Chemistry has a comparatively long history. Before the accep- tance of the quadrivalence of carbon, various attempts were made to prepare trivalent carbon species like methyl and ethyl. Initial investigations involving reaction between alkyl iodides and zinc were thought to be …
Aspects of the Merrifield Peptide Synthesis
Av C. Birr
Häftad, 2011
1084 kr
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This book was written in the context of the daily confrontation with problems in the utilization of polymeric supports for the synthesis of pep tides. Therefore, views and experiences which usually are not mentioned in scientific journals are collected in these pages. The author has deliberately …
Metal Vapour Synthesis in Organometallic Chemistry
Häftad, 2011
1084 kr
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Metal Vapour Synthesis (MVS) can be defined as; "The use in synthesis of high temper ature gaseous species such as metal atoms by their reactions with themselves or other materials in a condensed phase. " This short book, covering the literature up to the middle of 1979, describes MVS in organic …
New Syntheses with Carbon Monoxide
Av J. Falbe
Häftad, 2011
546 kr
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More than a decade has passed since the appearance of the last edition of the book "Carbon Monoxide in Organic Synthesis". During the intervening period, the signi ficance of carbon monoxide chemistry has become even more evident. The oil crisis and the ever-present awareness of the constant …
Organic Synthesis with Palladium Compounds
Av Jiro Tsuji
Häftad, 2011
1084 kr
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Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been …
Light Absorption of Organic Colorants
Theoretical Treatment and Empirical Rules
Av J. Fabian, H. Hartmann
Häftad, 2012
546 kr
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Although studies on synthetic dyes have been performed for more than 100 years, their detailed elucidation requires further extensive research. The discovery of novel high polymers, the necessity of supplying a whole range of shades and increasing require ments for dyestuffs of high fastness …
Macrocyclic Polyether Syntheses
Av G. W. Gokel, S. H. Korzeniowski
Häftad, 2011
1084 kr
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It seems likely that no project of this magnitude is undertaken in the absence of several motivations. This book is no exception. There are, from our perspective, at least two rational reasons for conducting this cataloging and organizational effort. The first of these is the obvious fact that a …
Silicon Reagents for Organic Synthesis
Häftad, 2011
546 kr
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The application of silicon reagents in organic synthesis has grown at an increasingly rapid rate over the last twenty years. This has been the result of truly international interest. Signifi- cant contributions have been made by Japanese, Russian, Ger- man, French, English, American, Swiss and …
Anomeric Effect and Related Stereoelectronic Effects at Oxygen
Av A. J. Kirby
Häftad, 2012
1300 kr
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The anomeric effect is a well-defined and much studied example of a deep- seated and very general effect in organic chemistry. It involves a fundamental interaction between the lone pair electrons of oxygen and the antibonding orbitals of adjacent bonds, which can control not only conformation but …
Carbanion Chemistry
Häftad, 2012
546 kr
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This book was prepared with the idea of collecting some of the multitudinous new literature on carbanions and pre- senting it along with the fundamentals of carbanion chemi- stry. Some 400 papers from the period 1976 to 1982 have been assimilated into the book along with about an equal number of …
Intramolecular Diels-Alder and Alder Ene Reactions
Häftad, 2011
546 kr
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The Diels-Alder reaction has long been a powerful tool in organic synthesis. In recent years, the Alder ene reaction has also achieved some prominence. From the beginning, it was apparent that the intramolecular variants of these reactions would be feasible. Many such have been reported, but the …
Chromium Oxidations in Organic Chemistry
Häftad, 2011
1084 kr
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Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a …
Electroorganic Chemistry as a New Tool in Organic Synthesis
Häftad, 2011
1084 kr
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Although the first electroorganic reaction used in organic synthesis is probably the famous Kolbe electrolysis published in 1849, no other remarkable reactions have been found until the reductive dimerization of acrylonitrile to adipo nitrile was developed by Dr. M. M. Baizer of Monsanto Co. in …
Organomercury Compounds in Organic Synthesis
Av R.C. Larock
Häftad, 2011
1084 kr
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The field of organometallic chemistry has enjoyed explosive growth in recent years. During this time a rapidly increasing number of metals have found utility in organic synthesis as the corresponding organometallic compounds. The sub ject of "Organic Synthesis by Means of Transition Metal …
Organotitanium Reagents in Organic Synthesis
Häftad, 2011
546 kr
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Titanium has been used to perform many kinds of reactions in organic and inorganic chemistry. The present book is concerned primarily with a new development in titanium chemistry which is useful in organic synthesis. In 1979/80 it was discovered that the titanation of classical carbanions using …
Chemiluminescence in Organic Chemistry
Av Karl-Dietrich Gundermann, Frank McCapra
Häftad, 2011
1084 kr
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The appearance of the first review in 1965 [1] and the first monograph in 1968 [2] on chemiluminescence demonstrated the extent of the phenomenon of light emission from the reaction of organic compounds in solution. Since then the num ber of chemiluminescent compounds has greatly increased, …
Electron Transfer Reactions in Organic Chemistry
Häftad, 2011
1084 kr
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The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of …
Polyquinane Chemistry
Syntheses and Reactions
Av Leo A. Paquette, Annette M. Doherty
Häftad, 2012
546 kr
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New methods for the construction of condensed five-membered ring systems continue to be developed at an accelerated pace. The challenges underlying this tremendous current upsurge of interest arise from several directions. One stems from the desire to elucidate and resolve those special problems …
Ultrasound in Synthesis
Av Steven V. Ley, Caroline M.R. Low m. fl.
Häftad, 2011
546 kr
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The effects of heat and light on chemical reactions have long been known and un derstood. Ultrasound has been known to promote chemical reactions for the past 60 years, but despite this, it did not attract the attention of synthetic chemists until recently. This arose historically from early …
Stereodirected Synthesis with Organoboranes
Häftad, 2011
546 kr
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This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling sterochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors …
Ordering Concept on the Basis of Alternative Principles in Chemistry
Design of Chemicals and Chemical Reactions by Differentiation and Compensation
Av Paul Heimbach, Tamas Bartik m. fl.
Häftad, 2011
1084 kr
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Considering aspects of symmetry rules in chemistry, one is faced with con tradictory terms as for example, "90 % concertedness" sometimes being used in literature. To accept conservation of orbital symmetry to be as controlled as inversion by alternative principles seems far more promising. The …
Barbier Reaction and Related One-Step Processes
Häftad, 2012
546 kr
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The significant increase in applications of Barbier and Barbier-type reactions in (in-) organic synthesis over the past twenty-five years, combined with repeated stimulation on the part of Springer-Verlag (Dr. R. Stumpe) were strong in centives for me to write this book. My earliest activities in …
