ACS Symposium Series – serie

The book will give an overview of the current state-of-the-art concerning the activation and dissolution of cellulose in a broad variety of solvents. Research on this topic can lead to new pathways for the utilization of the most abundant terrestrial biomolecule and may therefore be the basis for new green strategies towards advanced materials. Leading scientists in the field show different conceptions for the solubilization of cellulose. The long history andgroundbreaking developments in the field of polymer chemistry, which are related to this subject, have lead to timely alternatives to already established methods. In addition to discussing attempts for the optimization of known dissolving procedures, this book also details new solvent systems. New solventsinclude inorganic and organic salt melts (ionic liquids), new aqueous media, multi-component organic solvents and the dissolution under partial derivatization of the polysaccharide. The opportunities and the limitations of the solvents are demonstrated, with a particular emphasis on the stability of the solutions and a possible recycling of the solvent components. This book illustrates that the new procedures for cellulose dissolution can lead to a huge number of unconventional superstructures of regenerated cellulose material, such as fibers and polymer layers with a thickness in the nanometer range or aerogels, i.e. regenerates with a highly porous character and a large surface. Moreover, cellulose blends can be generated via solutions. The book also contains chapters that show the amazing potential of solvents for defined modification reactions on thecellulose backbone. On one hand, it is possible to synthesize known cellulose derivatives with new substitution patterns both on the basis of the repeating unit and along the polymer chain. On the other hand, completely new derivatives are presented which are hardly accessible via heterogeneousreactions. Consequently, the book is intended to give a comprehensive overview of procedures for dissolution of cellulose. It is of interest for scientists new in the field but is also a timely summary of trends for experts who are looking for new approaches for problems related to cellulose shaping or chemical modification.

This new volume brings together scientists from a variety of disciplines to present, summarize, review, and update information related to bioherbicides. Among the topics covered are pathogens with potential as bioherbicides, phylloplane-pathogen interactions, aspects of soil microorganisms, formulation and commercialization of microbes as bioherbicides, genetic aspects of pathogens for weed control, and chemistry and biochemistry of microbial-plant interactions. Avaluable source of information for researchers involved in both biological weed control and herbicide development.

Low-Energy Nuclear Reactions and New Energy is a summary of selected experimental and theoretical research performed over the last 19 years that gives profound and unambiguous evidence for low energy nuclear reaction (LENR), historically known as cold fusion. In 1989, the subject was announced with great fanfare, to the chagrin of many people in the science community. However, the significant claim of its discoverers, Martin Fleischmann and Stanley Pons, excess heat without harmful neutron emissions or strong gamma radiation, involving electrochemical cells using heavy water and palladium, has held strong. In recent years, LENR, within the field of condensed matter nuclear science, has begun to attract widespread attention and is regarded as a potential alternative and renewable energy source to confront climate change and energy scarcity. The aim of the research is to collect experimental findings for LENR in order to present reasonable explanations and a conclusive theoretical and practical working model. The goal of the field is directed toward the fabrication of LENR devices with unique commercial potential demonstrating an alternative energy source that does not produce greenhouse gases, long-lived radiation or strong prompt radiation. The idea of LENR has led to endless discussions about the kinetic impossibility of intense nuclear reactions with high coulomb barrier potential. However, recent theoretical work may soon shed light on this mystery. Understanding this process is one of the most challenging and perhaps important issues in the scientific world. This book includes previously unpublished studies, new and controversial theories to approach LENR with access to new sources and experimental results. The book offers insight into this controversial subject and will help readers re-evaluate their perspective on LENR as a possible alternative energy source.

Nanoscale Materials in Chemistry describes research on the development of catalysts and adsorbents based on nanoscale materials. It includes new fundamental research and applications, beginning with a review of research on the development of nanoscale metal oxides that have environmental applications. Information on product development is described for selected products that have been developed and commercialized.This book is for scientists and engineers who are engaged in research, development, and commercialization of nanoscale materials for environmental applications. Those interested in the pathway from idea to product will find this book valuable to them. Those interested in sustainable indoor environments will find new information on in room devices that may be able to reduce energy use in buildings. Toxicology and product safety are included as well.

Dalton's theory of the atom is generally considered to be what made the atom a scientifically fruitful concept in chemistry. To be sure, by Dalton's time the atom had already had a two-millenium history as a philosophical idea, and corpuscular thought had long been viable in natural philosophy (that is, in what we would today call physics). Atoms in Chemistry will examine episodes in the evolution of the concept of the atom, particularly in chemistry, from Dalton's day to our own. It begins with an overview of scientific atomic theories from the 17th through 20th centuries that analyzes corpuscular theories of matter proposed or entertained by natural philosophers in the 17th century. Chapters will focus on philosophical and religious conceptions of matter, 19th-century organic structural theories, the debate surroundingthe truth of the atomic-molecular theory, and physical evidence accumulated in the late 19th and early 20th centuries that suggested that atoms were actually real, even if they were not exactly as Dalton envisioned them. The final chapter of this book takes the reader beyond the atom itself to some of theplaces associated with the history of scientific atomism. As a whole, this volume will serve as a passport to important episodes from the more than 200-year history of atoms in chemistry.

The role of the Maillard reaction in forming flavors from amino acid and sugar precursors has been studied for many years. To establish the basic chemistry of the reaction, researchers have used model systems, often solutions of a single amino acid with a single sugar. Despite the apparent simplicity of the system, heating such a solution can generate tens if not hundreds of compounds, which requires careful and time-consuming analysis to identify and quantify eachcomponent. Data from the model systems has allowed researchers to study the pathways that lead to flavor formation, and various schemes have been proposed to identify the main "routes" that lead to flavor compounds. Such schemes have led to one of the main control principles, namely an understanding of the role of amino acids in forming some characteristic aromas, e.g., bread flavor from proline, as well as an appreciation of the role of C5 and C6 sugars in controlling the rate of reaction. Recently, the formation of taste compounds through the Maillard reaction has been investigated and new potent compounds have been discovered that can contribute to the overall flavor formed during the Maillard reaction. These findings also offer the potential for control and manipulation of the Maillard reaction to form specific types of flavor. Although the nature of the end-products of the Maillard reaction in both food and model systems are well documented, applying these principles tocontrol flavor formation in real foods has proved difficult. This book describes recent research and developments related to the control of the Maillard reaction to give optimum flavor quality. These include kinetic modeling of the reaction, the effect of physical parameters (temperature, time, moisture content, pH), and the effect of chemical parameters (amino acid and sugar composition, the presence of other components). The topics covered relate to real food systems and reaction product flavorings, as well as model systems. Contributors from academiaand industry have come together to provide an up to date overview of progress in this important area of flavor research.

The Protection of Subjects in Human Research rule by the USEPA, including the establishment of the Human Studies Review Board (HSRB), has resulted in changes to both study design and study evaluation processes, particularly with respect to ethical considerations. Non-Dietary Human Exposure and Risk Assessment is a compilation of the presentations given in a symposium of the same name at the 238th ACS National Meeting in Washington D.C. The purpose of thesymposium was to provide a forum for scientists from industry, academia, and government to share investigative methods used to generate data for use in non-dietary human risk assessments and to share methodology for performing and evaluating those assessments.This compilation is intended to provide the reader with a concise overview of the current status of both the scientific and regulatory aspects of non-dietary human exposure and risk assessment as applied to pesticides. It is the hope of the editors that it will also be the starting point for discussions leading to the further refinement of study and risk assessment design, data evaluation, and regulatory harmonization. Three major areas are covered in this symposium edition. The first area is regulatory issues including the development of the Protection of Subjects in Human Research rule and the HSRB, statistical procedures involved in designing human exposure studies, handling of the data generated in those studies, and quality assurance processes related to worker exposure studies. The second area, study design, includes processes for the identification and recruitment of volunteers for human exposurestudies, overviews of several studies that have been recently performed, the development of procedures for evaluating the resulting data by Regulatory Agencies, and efforts towards international cooperation in the generation and use of exposure data. The final area, methodology, includes examples of thedevelopment of methods for the analysis of samples generated in non-dietary human exposure studies with particular emphasis on the use of hyphenated techniques and the development of a model for determining greenhouse exposures that is currently being used in Europe.

Collaborations between scientists often transcend borders and cultural differences. The fundamental nature of science allows scientists to communicate using knowledge of their field but the institutions that support them are often hindered by financial and cultural barriers. As a result, science suffers. This book evolved from an August 2009 symposium at the 238th annual meeting of the American Chemical Society in Washington, DC. Its focus is on chemistry studentsand professors interested in developing a global approach to teaching chemistry, by participating in an international exchange program or incorporating culturally inclusive techniques into their classroom. The book has three broad themes; education research with a globalized perspective, experiences ofteaching and learning in different countries, and organizations that support a global view of chemical education and chemistry.

Compelling evidence exists to support the hypothesis that both formal and informal mentoring practices that provide access to information and resources are effective in promoting career advancement, especially for women. Such associations provide opportunities to improve the status, effectiveness, and visibility of a faculty member via introductions to new colleagues, knowledge of information about the organizational system, and awareness of innovative projects andnew challenges. This volume developed from the symposium "Successful Mentoring Strategies to Facilitate the Advancement of Women Faculty" held at the 239th National Meeting of the American Chemical Society in San Francisco in March 2010. The organizers of the symposium, also serving as the editors of this volume, aimed to feature an array of successful mechanisms for enhancing the leadership, visibility, and recognition of academic women scientists using various mentoring strategies. It was their goal to havecontributors share creative approaches to address the challenge of broadening the participation and advancement of women in science and engineering at all career stages and from a wide range of institutional types. Inspired by the successful outcomes of the editors' own NSF-ADVANCE project thatinvolved the formation of horizontal peer mentoring alliances, this book is a collection of valuable practices and insights to both share how their horizontal mentoring strategy has impacted their professional and personal lives and to learn of other effective mechanisms for advancing women faculty.

This book discusses the combined fields of Intellection Property and Information Science. At this crossroads of these two disciplines are lawyers, educators, intellectual property specialists, searchers, librarians, and consultants, each requiring a lengthy list of skills necessary for the job. The results of the work they do is used for business and legal decisions across many sectors of our society, including industry, academia, government, and non-profits, to namea few. This book originated from the American Chemical Society (ACS) Symposium entitled "IP to IP: Intellection Property for Information Professionals", presented in Washington DC on August 19th, 2009. It was organized to highlight the specialty training and education required to work in this field.The book is targeted towards Information Scientists learning about Intellectual Property. Traditional education sources such as universities are represented, and are specialty offerings from the pharmaceutical sector and the United States Patent and Trademark Office (USPTO). The original six sessions from the Symposium are included in this text as separate chapters: Education and Certification of Patent Information Professionals in Europe; The PERI Patent Information Course; Law Librarianship: Exploring current trends in the 21st century; The USPTO: Education of the Inventor Community; Copyright Basics; Recent Developments in Patent Reform. Additional chapters and content have been added to more fully develop this text. Although this Symposium captured several intellectual property topics with current information for mid-2009, this content should still prove to be a valuable resource to the reader in future years. This book is an resource for students or others looking to take the next step into intellectual property as a new career choice.

The conditions of our overpopulated planet with ever-growing energy needs, fossil fuels in limited supplies, and inefficient energy use world-wide, are creating a global crisis. Science has a responsibility, as well as a grand opportunity, to solve these energy-based problems of society. Science's new nanotechnologies, and the creativity they bring, are particularly appropriate to solve these problems. For example, energy-saving lighting, coupled with improvedharvesting and conversion of sunlight into electric energy, will have a great impact on society's energy needs. Also, development of energy efficient and low cost fuel cells, which could eventually replace car engines, has a potential to improve everyday life greatly. Nanomaterials offer an opportunity to develop new low-cost materials as environmentally friendly solutions and renewable energy sources, in order to meet society's energy needs. Fortunately, a wide spectrum of the scientific community has become interested in developing these nanomaterials in order to solve the above energy challenges. Nanomaterials offer unique mechanical, catalytic, electronic, and optical features, which are different from those of the analogous bulk material (1). This isbecause nanomaterials have scale-dependent properties, due to quantum size effects, which means the nanomaterial size (10 - 100 nm) is smaller than the mean free path of their electrons. Thus, nanomaterials have great promise for use in harvesting solar energy, hydrogen production and storage, fuelcells, catalysis, chemical, optical sensors, drug delivery systems (such as liposomes), and nanothermite reactions (2-4). Fluorine-containing nanomaterials generally have certain unique properties which are often improved relative to the analogous non-fluorinated nanomaterials, and which therefore could be engineered. Although fluorine has the highest electronegativity of all the elements, which means that bonds to fluorine are generally quite polar, it is also in the second period of theperiodic table, so it also has a small atomic radius and forms strong bonds. This produces the following properties, which also are characteristic of and bring great advantages to fluorine nanomaterials: high thermal and chemical stability, resistance to degradation by solvents, low flammability, lowmoisture absorption, low surface tension or energy, low dielectric constant, and serving as a strong oxidant under high energy conditions (5). However, little attention has been given to fluorine-containing organic and inorganic nanomaterials, which are predicted to have these unusual characteristics. This book presents examples of four diverse classes of these nanomaterials.

Energy, water, affordable healthcare and global warming are four major concerns resulting from resource depletion, record high oil prices, clean water shortages, high costs of pharmaceuticals, and changing climate conditions. Among many potential solutions, advance in membrane technology is one of the most direct, effective and feasible approaches to solve these sophisticated issues. This membrane book presents cutting-edge membrane research and development for waterreuse and desalination, energy development including biofuels, CO2 capture, pharmaceutical purification and separation, and biomedical applications.

Polymeric materials have been and continue to be a focus of research in the development of materials for energy conversion, storage and delivery applications (fuel cells, batteries, photovoltaics, capacitors, etc.). Significant growth in this field started in the early 1990s and has continued to grow quite substantially since that time. Polymeric materials now have a prominent place in energy research. For polymers, particularly polyelectrolytes, being used in fuel cell and battery applications, the importance of chain microstructure, chain dynamics, and nanoscale morphology on the overall performance characteristics of these materials cannot be overstated. As further advancements are made in polymer chemistry, control of nanostructure and characterization, there is a necessity for organized forums that foster cross-fertilization of knowledge and ideas between experts in polymer chemistry,chemical engineering, and polymer physics. This volume is the result of such a forum. Most of the chapters in this book are based on a cross-section of the oral presentations in a symposium on Polymers for Energy Storage and Delivery held in March of 2011 as part of the 241st ACS National Meeting & Exposition (Anaheim, CA). The book contains 17 chapters presented in two parts. Part one focuses on polymers for battery applications and will cover theory and modeling, novel materials, and materials characterization. Professor Janna Maranas has provided an excellent review ofthe current state of understanding in polyelectrolytes as ion conductors in batteries. Part two will focus on polymers for fuel cells and will cover novel materials, transport, and materials characterization with a brief introduction into the history of polyelectrolytes for fuel cells and the classes ofmaterials being pursued. Realizing the common role that nanostructure plays in both battery and fuel cell applications, Professor Moon Jeong Park and coworkers have also contributed a chapter demonstrating the role of nanostructured polyelectrolyte systems in energy storage and delivery. In addition, the editors are pleased to have a chapter-contributed by Professor Howard Wang and staff scientists of the NIST Center for Neutron Research-on the most state-of-art, in-situ neutron methods forstudying lithium ion batteries.

Cereal grains have been the principal component of human diet for thousands of years and have played a major role in shaping human civilization. Around the world, rice, wheat, and maize, and to a lesser extent, sorghum and millets, are important staples critical to daily survival of billions of people. More than 50% of world daily caloric intake is derived directly from cereal grain consumption. Most of the grain used for human food is milled to remove the bran(pericarp) and germ, primarily to meet sensory expectations of consumers. The milling process strips the grains of important nutrients beneficial to health, including dietary fiber, phenolics, vitamins and minerals. Thus, even though ample evidence exists on the health benefits of whole grain consumption,challenges remain to developing food products that contain significant quantities of whole grain components and meet consumer expectations. This book presents some of the latest research endeavors that aim to improve our understanding of how the chemistry of various grain components can be manipulated to improve contribution of cereals to human health. Most of the topics are based on the Cereal Grains Symposium, at the 2011 American Chemical Society held in Anaheim, CA, March 27-31.

This book is meant to be a companion volume for the ACS Symposium Series Book entitled Nuts and Bolts of Chemical Education Research. In the Nuts and Bolts book (edited by Diane M. Bunce and Renee Cole), readers were presented with information on how to conduct quality chemical education research. In the Myth book, exemplars of chemical education research are featured. In the cases where the chapter in the book is describing research that has already been published(typically in the Journal of Chemical Education), additional information is provided either in terms of research questions investigated that were not reported in the published article or background information on decisions made in the research that helped the investigation. The main focus of this typeof discussion is to engage the reader in the reality of doing chemical education research including a discussion of the authors' motivation. It is expected that these two books could be used as textbooks for graduate chemical education courses showing how to do chemical education research and then providing examples of quality research.

This volume consists of written chapters taken from the presentations at the symposium "100+ Years of Plastics: Leo Baekeland and Beyond", held March 22, 2010, at the 239th ACS National Meeting in San Francisco. The symposium celebrates the 100th anniversary of the formation of General Bakelite Corp., which was preceded by Leo Baekland's synthesis of Bakelite in 1907 and the unveiling of the Bakelite process in 1909. It is quite reasonable to use the synthesis ofBakelite as the starting point of the Age of Plastics. Indeed, Time magazine in its June 14, 1999, issue on the 100 most influential people of the 20th century chose Leo Baekeland and his Bakelite synthesis as the sole representative of chemistry. Leo Baekeland and Bakelite are the topics of the first four chapters of this volume. The first two chapters come from the perspective of Baekeland family members. Carl Kaufmann is related to the Baekeland family through marriage and is the author of the only full-length biography of Baekeland, published as a master's thesis from the University of Delaware. As a family member Kaufmann had access to all of Baekeland's papers. This first chapter (Leo H. Baekeland) is not only a biographicalsketch, but an exploration of Baekeland's effect on the chemical industry. Hugh Karraker is Baekeland's great-grandson, and his chapter (A Portrait of Leo H. Baekeland) provides a family picture of the great inventor. Gary Patterson's chapter (Materia Polymerica: Bakelite) goes into the history of Bakelitechemistry, while Burkhard Wagner's contribution (Leo Baekeland's Legacy-100 Years of Plastics) covers the history of Bakelite manufacture through time and space, finishing with a description of another Baekeland legacy, the Baekeland Award given through the North Jersey Section of the ACS. In later chapters, Les Sperling (History of Interpenetrating Polymer Networks Starting with Bakelite-Based Compositions) covers the improvements in interpenetrating networks. James Economy and Z. Parkar (Historical Perspectives on Phenolic Resins and High-Temperature Aromatic Polyesters of p-Hydroxybenzoic Acid and Their Copolyesters) follow the paths of resoles, novolaks, and related chemicals.

Chirality as an environmental phenomenon was dealt with in a thorough and interesting manner in a series of three symposia entitled "Modern Chiral Pesticides: Enantioselectivity and Its Consequences", sponsored by the Agrochemical Division of the American Chemical Society and held in Washington, DC (2005), Boston, MA (2007) and San Francisco, CA (2010). All three symposia included speakers from industry, government and academia, representing several Europeancountries, China, and the United States. Corresponding to this broad group of countries, institutions and speakers, the range of topics touched on almost all facets of chirality as it is manifested in environmental and human exposure and toxicity. The 40 oral and 20 poster presentations indeed approachedcomprehensive coverage: analysis of enantiomers and other stereoisomers; preparative separation of enantiomers; stereoselective occurrences of chiral pesticides in environment soil and water and in wildlife and human tissues and fluids; stereoselective degradation and metabolism of chiral pesticides; and stereoselective toxicity. This book is a result of manuscript contributions by some of the oral and poster presenters to the third symposium in 2010. In addition to symposium participants, invitations were extended to the environmental chiral chemistry community in general, including most of the speakers in the 2005 and 2007 symposia, in an attempt to attain good coverage of this rather broad topic. Thus, this ACS Symposium book will generate many new ideas from interested readers and inform them of useful techniquesfor experimental exploration of the somewhat exotic, but important, area of chiral chemistry of pesticides.

As the global climate changes, scientists anticipate that the distribution of animal populations and disease vectors will expand. In the case of arthropods, such efforts hold immense significance as they have the potential to increase human mortality and suffering from arboviruses above current levels. The 238th American Chemical Society National Meeting and Exposition in Washington, D.C. on August 16-20, 2009, offered an opportunity for researchers to present anddiscuss new findings in invertebrate repellents research, regulations, and technology development.Recently efforts have been made to understand the role of chemicals in arthropod behavior, and screening programs are starting to incorporate repellency testing into their battery of bioassays. The lack of standardized protocols for measuring and comparison of repellents has remained a significant obstacle in arthropod research. Oftentimes studies report variable measures of success, and comparison of results across studies is not always consistent. Progress in the standardization of arthropodtest methods for repellents would be valuable to many groups including academic researchers working in the field, contract labs supplying test results, government research laboratories, regulatory bodies in the process of developing guidelines for product registration, as well as companies looking toinvest in new technologies. Perhaps one complicating factor in this process has been that research and technology haven't moved fast enough to meet the demand for effective arthropod repellents. Issues such as pest arthropod resurgence and insecticide/repellent resistance to chemical can create new challenges and add pressure for researchers.The collection of chapters in this book covers a range of applied and basic research on arthropod repellents. An overview of the state of arthropod repellents research is provided at the start. In the chapters that follow, there is a selection of papers demonstrating research on new repellent technologies at different stages of development. The scope of basic and applied research methods described in these chapters on new repellent technologies presents the range of testing that is oftennecessary to move a repellent technology forwardin development. The transition from newly developed technologies to registered products is achieved in perspective of a growing market for natural arthropod repellents. New technologies that are completely developed and have gone through registration need to be accompanied by successful commercialization. The growing market for natural arthropod repellents presents such an example and highlights new opportunities in this area. The concluding chapter discusses the public entomology landscape,past and future opportunities for the development of chemical protectants.

Now more than ever we are facing pressing world challenges of energy (identifying alternate energy), food (ensuring the food supply), water (providing clean water), and human health (enabling individualized medicine); and to solve these challenges will require chemistry and the related chemical sciences. Integrating sustainability into everything we do from instituting responsible operations, to selecting partners for change and innovating sustainable solutions.Industry needs academe to prepare their graduates to ascend the ladder with skill and agility. This can only be done by integrating sustainability expeditiously into chemistry curricula.

This book is the first volume in a two-volume compilation on controlled/living radical polymerization. It combines all important aspects of controlled radical polymerization: from synthetic procedures, to rational selection of reaction components, to understanding of the reaction mechanisms, to materials and applications.This book is focused on recent progress in the rapidly developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, 944, 1023, and 1024. Volume 1100 deals with the mechanistic aspects of controlled radical polymerization and describes the recent advances in the most important techniques, whereas Volume 1101 contains chapters on new materials prepared by controlled radical polymerization as well as applications of thesematerials.

The field of quantum chemistry has grown so immensely that the importance of some of the earliest work and the earliest pioneers of quantum chemistry is unfamiliar to many of today's youngest scientists in the field. Thus, this book is an attempt to preserve some of the very valuable, early history of quantum chemistry, providing the reader with not only a perspective of the science, but a perspective of the early pioneers themselves, some of whom were quiteinteresting characters. The symposium on which this book is based came about because one of the co-editors (ETS) came to a conviction that the contributions such as those by George Wheland to quantum chemistry and Otto Schmidt to free electron theory should be better appreciated and known. He organized asymposium in which quantum chemistry pioneers, both those celebrated by everyone and those seemingly overlooked by posterity, would be recognized. While this volume is certainly not a history of quantum chemistry, it does cover many highlights over a period of about sixty years. This volume consists of chapters based upon ten of the presentations at the symposium "Pioneers of Quantum Chemistry" held March 28, 2011, at the 241st ACS National Meeting in Anaheim, CA.

The chapters in this monograph are contributions from the Advances in Quantum Monte Carlo symposium held at Pacifichem 2010, International Chemical Congress of Pacific Basin Societies. The symposium was dedicated to celebrate the career of James B. Anderson, a notable researcher in the field.Quantum Monte Carlo provides an ab initio solution to the Schroedinger equation by performing a random walk through configuration space in imaginary time. Benchmark calculations suggest that its most commonly-used variant, "fixed-node" diffusion Monte Carlo, estimates energies with an accuracy comparable to that of high-level coupled-cluster calculations. These two methods, each having advantages and disadvantages, are complementary "gold-standards" of quantum chemistry.There are challenges facing researchers in the field, several of which are addressed in the chapters in this monograph. These include improving the accuracy and precision of quantum Monte Carlo calculations; understanding the exchange nodes and utilizing the simulated electron distribution; extending the method to large and/or experimentally-challenging systems; and developing hybrid molecular mechanics/dynamics and Monte Carlo algorithms.

We are becoming increasingly aware of the overwhelming pollution of our limited water resources on this planet. And while many contaminants originate from Mother Earth, most water pollution comes as a direct result of anthropogenic activities. This problem has become so immense that it threatens the future of all humanity. If effective measures to reduce and/or remediate water pollution and its sources are not found, it is estimated by UN that 2.7 billion people willface water shortage by 2025 as opposed to 1.2 billion people who do not have access to clean drinking water now. Therefore, development of novel green technologies to address this major problem represents a priority of the highest importance. This book discusses green chemistry and other novelsolutions to the water pollution problems which includes some interesting applications of nanoparticles. Novel Solutions to Water Pollution is a useful and informative text for those engaged in issues of water quality and water pollution remediation at operational, administrative, academic, or regulatory levels.

This ACS Symposium Series is the product of a symposium held at the 241st National Meeting of the American Chemical Society in Anaheim, CA on March 27-31, 2011. It includes chapters on new biobased building blocks such as the furandicarboxylic acid, polyesters and polyamides from adipic, succinic and sebacic acids with aliphatic diols such as 1,3-propylene glycol, 1,4-butanediol, 1,12-dodecylenediol and isosorbide. The conversion of hydroxymethylfurfural, thedehydration product of hexose sugars, to succinic acid and 1,4-butanediol to produce poly(butylene succinate) is described in one chapter. Also the synthesis of new polymers from plant-derived olefinic monomers such as tulipalin A and studies of composites from cotton by-products are featured in otherchapters. There is a strong emphasis on biocatalytic synthesis and polymerization within the book. Chapter topics include the synthesis of ?-hydroxyfatty acids and polymers therefrom, an interesting discussion on the structural differences of the products of the biocatalytic and chemical catalytic synthesis of polyesters from oleic diacid and glycerol and the ability to produce polylactic acid (PLA) and PLA-PHA copolyesters within a "microbial cell factory".Other areas of interest explored in other chapters include recent developments of biobased polymer fibers and oleate-based pressure sensitive adhesives and composites. One chapter describes a large increase in cold-drawn fiber tensile strength by the blending of a small amount of ultrahigh molecular weight (MW) poly(3-hydroxybutyrate) with a much lower MW 3-hydroxybutyrate polymer. The addition of a rubber and inorganic fillers to normally brittle PLA was found to dramatically improve itsductility. Finally, there are several chapters on seed oil-based polyurethanes, one on fibers from soy proteins and composites from starch.

This book makes a serious effort at bringing forth and synergistically combining the concepts of green chemistry,sustainability and nanotechnology and should motivate scientistsat all levels to think clearly and seriously about creating and optimizing novel and sustainable green approaches to nanotechnology. The chapters in this book can be divided into three broad categories: 1) Advancement in research on pollution control through the green chemistry principles of nanotechnology; 2) Emergence of nanomaterials in widespread applications in various scientific fields, including but not limited to sensorsand catalysts; 3) Extension of research into nanotechnology and green nanotechnology at a rapid pace. Review articles on the individual aspects of these diverse and complementary topics have become important resources for researchers, industry leaders, and regulators, both nationally andinternationally. This book contains a few chapters associated with these particular themes, and provides glimpses of the many difficulties and challenges faced by those who seek to not only understand but also regulate the new nanomaterials. Nanotechnology represents a unique field of science, and necessitates new and novel sustainable approaches to create usable end products for the market place with the primary goal of yielding less adverse effects upon both human health and theenvironment.

Even the most cursory survey of the chemical literature reveals that modern NMR spectroscopy has indeed fulfilled its potential as a powerful and indispensable tool for probing molecular structure, providing detail that is comparable to, and sometimes surpasses that, of X-ray crystallography. As NMR spectroscopy's 70th anniversary approaches, the diversity of chemical problems to which this technique can be applied continues to grow across many scientific fields.Beyond the laboratory setting, the technology underlying NMR is now a widely used and critical medical diagnostic technique, Magnetic Resonance Imaging (MRI). Unfortunately, the number of applications of NMR spectroscopy across so many STEM-related fields presents significant challenges in how best tointroduce this powerful technique in meaningful ways at the undergraduate level. Inspired by the development of the field, and building upon the work of previous symposia and an ACS symposium series book on this topic (3), a symposium was developed, entitled "NMR Spectroscopy in the Undergraduate Curriculum," for the 239th American Chemical Society National Meeting in San Francisco. This book brings together all of the presenters who have been successful in developing and successfullyintegrating NMR spectroscopy pedagogy across their undergraduate curriculums. Their knowledge and experiences will aid readers who are interested in expanding and invigorating their own curriculum.

This book is a collection of essays, written by an international group of historians of chemistry, about some of the most interesting chemists dating back into the 18th century. The contributing authors are well-established biographers, and their subjects make a diverse cast of chemistry characters. Among the chemists covered are Robert Bunsen, Joseph Black, John Dalton, Lucretia Borgia, William Crookes, and Humphry Davy. These chemists come from all over the world,and from different eras. Together, this collection truly is a celebration of the wide range of personalities and characters that have worked in chemistry over the centuries.

Increased energy prices and the growing attention on global warming are motivating the creation of economically viable alternatives to fossil fuels. Nanotechnologies have been recognized as one effective approach to solve energy problems. Therefore, to promote the improvement of research and to foster professional collaboration among researchers in energy-related nanotechnologies, we organized a symposium on "Nanotechnology for a Sustainable Energy Economy" as a partof the 243rd American Chemical Society National Meeting, which took place March 25-29, 2012 in San Diego, California, USA. Forty-four contributors from 12 countries presented their research works from industrial, university, and national laboratories in nanotechnology areas related to energy andfuel technologies. This ACS Symposium Series book was developed from this symposium. This book presents a very useful and readable collection of reviews and research papers in nanotechnologies for energy conversion, storage, and utilization, offering new results which are sure to be of interest to researchers, students, and engineers in the field of nanotechnologies and energy. The book focuses on the following topics: Li batteries (Chapters 1-4), supercapacitors (Chapter 5), dye-sensitizedsolar cells (Chapter 6), photocatalysis (Chapters 7-9), fuel cells (Chapter 10), electrocatalysis (Chapter 11), and electron beam lithography (Chapter 12). All 12 chapters were recruited from oral presentations at the symposium.

Professors and research advisors have always endeavored to make the opportunity to gain new knowledge available to their students. However, new knowledge takes different forms. From a student perspective, it comes from reading textbooks and primary literature or attending classes and seminars. Professors share in these activities with their students, but they know that physically taking part in the acquisition of new knowledge through active research is where thetrue excitement begins. For many, if not all, faculty members research is the source of passion for chemistry, and sharing it with a rising generation of chemists often comprises a substantial part of the decision to pursue a career in the field of undergraduate education.These chapters and additional ones provide starting points for developing such a culture at the department level. In several cases the starting point is redesigning introductory or research methods courses to place a stronger emphasis on authentic research and its associated skills. In other cases the establishment of a thriving research group by one faculty member is the catalyst for initiating the departmental transformation. There are also several examples of how to set up an undergraduateresearch group in departments that place a heavy emphasis on research, and those that place less emphasis on research. Many of these offer roadmaps for developing interdisciplinary research groups or translating resource-intensive graduate-level research to an environment that is resource-restrictive.In still other cases the research has an experiential learning component. For many of the above examples the departmental/institutional role is not always obvious and may not be influential or important. This is a reminder that undergraduate research need not be "institutional" to be successful.