NATO Science Partnership Subseries: 3 – serie

Minsk, Belarus was the site of the NATO ARW on Wide Band-Gap electronic Materials May 3 through 6,1994; 143 participants and observers from 15 countries met for the NATO Advanced Research Workshop on Wide Band-Gap Electronic Materials (NATO ARW). The meeting was marked by a remarkable free exchange between east and west on these topics by revealing technical achievements not widely known or available in the west because ofpast political climate or present economic realities in the Newly IndependentStates. The topics ranged from electron doping of diamond, n-type diamond, negative electron affinity ofdiamond, applications of aluminum nitride, doping ofboron nitride, wideband gap electronic applications, to nanophase diamond. Of the many high-lights during the scientific meetings, an energy sub band due to defects in the diamond lattice was described. These defects areresponsible for the light emission from a diamond Light Emitting Diode (LED) which was demonstrated at the NATO ARW. This diamond LED can emitred, green, and blue light. The potential for "high tech" nanostructure electronic devices such as quantum transistors was described which mightsome day revolutionize electronics.The prospectsofaluminum nitride for acusto devices,piezodevices, and electroluminescencedevices were discussed.

Multi-chip modules (MCMs) with high wiring density, controlled impedance interconnects and thermal management capability have been developed to address the problems posed by advances in electronic systems that make demands for higher speeds and complexity, highlighting recent advances in MCM-C technology. Developments in materials and processes which have led to increased interconnection density are reviewed for finer resolution thick film inks and high performance-low temperature dielectric tapes. Precision via generation by both laser and mechanical methods and enhanced screen printing technologies have provided feature resolution to the 50 mmm line/space level. MCM-C technology is compatible with thick film sensors and work is reviewed on environmental gas sensors, pressure and temperature sensors, and the development of novel materials in this area.

A recent major development in high technology, and one which bears considerable industrial potential, is the advent of low-dimensional semiconductor quantum structures. The research and development activity in this field is moving fast and it is thus important to afford scientists and engineers the opportunity to get updated by the best experts in the field. The present book draws together the latest developments in the fabrication technology of quantum structures, as well as a competent and extensive review of their fundamental properties and some remarkable applications. The book is based on a set of lectures that introduce different aspects of the basic knowledge available, it has a tutorial content and could be used as a textbook. Each aspect is reviewed, from elementary concepts up to the latest developments. Audience: Undergraduates and graduates in electrical engineering and physics schools. Also for active scientists and engineers, updating their knowledge and understanding of the frontiers of the technology.

In the last 15 years aqueous organometallic chemistry and catalysis has emerged from being a laboratory curiosity to become an established field of research. Topics reviewed here include mechanistic studies on the effect of water on catalyzed reactions, the preparation of water soluble phosphines as ligands for catalysis, metal catalyzed organic reactions in water (hydrogenation, hydroformylation, carbonylation, olefin metathesis, hydrophosphination, etc.), chiral ligands and enantioselective catalysis, organometallic radical photochemistry in aqueous solutions, bioorganometallic chemistry, organometallic reactions of biopolymers, and catalytic modification of biomembranes. The summary of recent results is supplemented by an assessment of probable future research trends. Audience: Researchers in both academia and industry, as well as graduate students of homogeneous catalysis.

Electricity is the most important secondary energy source, the present production rate, mainly from thermal electric power stations, being of the order of 1.3 TW. However, the total capacity of primary and rechargeable batteries currently in use is the same as the output of the world's power stations. But present battery systems will not meet future needs for the economical storage of large amounts of electrical energy for vehicles, public transport, road levelling, solar energy utilisation, civil video and audio, terrestrial and space communications, etc. Current accumulators based on aqueous acid or alkali systems do not have sufficient output and, moreover, the materials employed (Pb, Cd, Ni) are environmental pollutants that require safe recycling. Further, stocks of these strategic metals are being rapidly depleted. This book discusses actual field results with novel systems, such as rechargeable lithium batteries, zinc/air cells, metal-free accumulators, graphite/carbon devices and others, including fuel cells.The book stresses that a universal electrochemical system is not feasible: the choice of any system must depend on the concrete field of application and must be taken in consideration of a large number of technical, economic and environmental circumstances.

In the 30 years since the invention of the CO2 gas laser, the major design issue has shifted from how to obtain the desired power level to how to achieve reliable operation. At the same time, the opening of many laser development facilities in the former Soviet Union has allowed their achievements and design approaches to be understood and appreciated. Further, the industrial laser user community has identified a number of emerging applications at higher power levels (15-20 kW) than are attainable by most commercial devices.

In June 25-30, 1995 the NATO Advanced Research Workshop on" PhotoactifOrganic Materials: Science and Applications, devoted to organic materials and their specific responses to the light beam in view of their exploitation in devices was held in Novotel hotel in Avignon, France. It consisted ofplenary lectures, given by leading specialists in tbis field, shorter oral contributions and a poster session. Three working groups discussed more specific aspects related to (i) molecular engineering, (ii) electroluminescence and photorefractive effects as weil as (iii) nonlinear optical response of these materials, respectively. It allowed deeper insights into different problems and aspects of the workshop field. The conclusions of working groups were presented last day by their leaders. These pointed out the progress, problems encountered as weil as possible developments. The presentations have been followed by a plenary, brainstorm . discussion. The talks presented ranged around the working group subjects. Important progress was noted in the field of organic light emitted diodes (LEDls), as discussed and presented by several speakers. Light emission over the entire visible spectrum, from blue to red is possible with organic polymers. Tbis can be done on large, flexible surfaces with low cost. The best organic LEDls show actually the operation life time of 1600 to 1700 hours at room temperature. One expects their commercialization in the near future. Sirnilarly, important progress has been accomplished with photorefractive of merit for these materials are better than those for polymers.

Dealing with the preparation, characterization and technological applications of monodisperse particles in the micro to nano size range, this work covers: the mechanisms by which uniform fine particles are formed and the search for new processes; the mechanism of the precipitation technique, requiring knowledge of the relationship between the complex solution chemistry and the products formed; and the sequence of events leading to the formation of monodisperse colloids. The following topics are presented: microparticles, nanoparticles, applications in the preparation of materials, synthesis and properties, environmental applications, and many others.

Low-dimensional semiconductor quantum structures are a major, high-technological development that has a considerable industrial potential. The field is developing rapidly and this work represents a guide to developments in device technology, fundamental properties, and some remarkable applications. The content is largely tutorial, and the book could be used as a textbook. It deals with the physics, fabrication, characteristics and performance of devices based on low-dimensional semiconductor structures. It opens with fabrication procedures. The fundamentals of quantum structures and electro-optical devices are dealt with extensively. Nonlinear optical devices are discussed from the point of view of physics and applications of exciton saturation in MQW structures. Waveguide-based devices are also described in terms of linear and nonlinear coupling. The basics of pseudomorphic HEMT technology, device physics and materials layer design are presented. Each aspect is reviewed from the elementary basics up to the latest developments. It should be of interest to undergraduates in electrical engineering, and graduates in physics and engineering schools.Useful for active scientists and engineers wishing to update their knowledge and understanding of recent developments.

This volume contains the edited version of lectures and selected research contributions presented at the NATO ADVANCED STUDY INSTITUTE on MECHANICAL BEHA VI OUR OF MATERIALS AT HIGH TEMPERATURE, held in Sesimbra, Portugal, 12th-22nd September 1995, and organized by 1ST-Lisbon Institute of Technology, PortugaL The Institute was attended by 88 participants, including 15 lecturers from 17 countries including five CP countries. The lecturers were leading scientists and technologists from universities, research institutions and industry. The students were mainly young PhD students and junior academic or research staff with postgraduate qualifications (MSc or PhD). Fourteen students were from the five CP countries. The students presented research papers or posters during the Institute reporting the current progress of their research projects. A total of thirty three lectures, ten research papers and fifty posters were presented. This book does not contain the poster presentations and seven research papers were selected for publication. All the sessions were very active and quite extensive discussions on scientific aspects took place during the Institute. The Advanced Study Institute provided a forum for interaction among scientists and engineers from different areas of research, and young researchers.

This volume documents the scientific events of the NATO Advanced Research Workshop (ARW) on The Preparation of Nanoparticles in Solutions and in Solids. The ARW was held in the second largest city in Hungary, Szeged, truthfully referred to as "the city of sunshine", from March 8 to March 13, 1996. The seventy-seven participants, including seventeen students, came from twentyone different countries. Housing all participants together and arranging a number of social activities fostered lively discussions both inside and outside of formal sessions. Twenty-one key lectures were presented in five sessions. Each session was followed by a fortyfive minutes of general discussion. One evening was devoted to the presentation of fifty-five posters. Thirty-two contribution were submitted and accepted for publication in the present volume. The volume also contains the minutes of the discussions, and a summary of the conclusions of the working groups. The ARW was organized under the auspices and financial support of NATO, City of Szeged, European Research Office of the US Army, Hungarian Academy of Sciences, Hungarian National Committee for Technological Development (OMBF), International Association of Colloid and Interface Scientists IACIS, and National Science Foundation (NSF). Both the organizers and participants gratefully acknowledge the generous support of the agencies. The Editors also thank the high quality and creative contributions of the participants. It is they who made this volume a reality. Janos H. fendler Irnre Dekany ix Glossary of Some Names and Acronyms Advanced Materials Man-made materials having superior mechanical, thennal, electrical, optical, and other desirable properties.

This book is the result of the contributions coming from the more than thirty key rd speakers of the 3 international Workshop on Nonlinear Microwave Magnetics held in th Roma, Italy from the 3rd to the 6 of October 1995. Since the 1990, in Ulyanovsk, when the Russian Academy of Sciences promoted the first Workshop of the series, the basic idea was to have a sort of Institutional Meeting collecting Scientists of the Magnetics Community devoted to Spin Wave Electronics at Microwave Frequencies. It was a succesful organization, and the birth of an effective interaction between eastern and western researchers overcame the meaning of the Workshop itself. Three years later, in Irvine, California, 1993, the Spin Wave Community was joined again. It was clear that the growing interest on hot topics of Nonlinear Microwave Magnetics involving both, applicative and fundamental aspects of microwave magnetic media, favoured the organization of further meetings on the same subject. So far, during the social dinner, in the middle between a serious proposal and the joke encouraged by the Californian Wine, Roma was proposed as the third place for the Workshop. Day after day, the joke became serious, and it was possible to solve the financial and logistic problems in time for the predicted deadline.

A comprehensive survey of the latest advances in surface engineering, particular emphasis being placed on the functionality of protective coatings and the relationships between properties, performance and experimental parameters used for the deposition of films on a variety of substrates. Topics covered include: protection against wear, erosion, corrosion, and friction, plasma assisted physical and chemical vapour deposition processes, low friction coatings operating in a hostile environment, polymer films for protection against mechanical damage and chemical attack, film structure characterization and correlations with mechanical properties, wear and corrosion resistant thermal spray coatings, functional gradient ceramic/metallic coatings produced with high energy laser beams, and energetic deposition processes for high temperature applications, protective coatings for optical systems, and ion beam assisted deposition for protection against aqueous corrosion. Fundamental, scientific, technical and economic aspects of both R&D and applications are dealt with in detail.

The aim of this NATO ASI has been to present an up-to-date overview of current areas of interest in amorphous materials. In order to limit the material to a manageable amount, the meeting was concerned exclusively with insulating and semiconducting materials. The lectures and seminars fill the gap between graduate courses and research seminars. The lecturers and seminar speakers were chosen as experts in their respective areas and the lectures and seminars that were given are presented in this volume. During the first week of the meeting. an emphasis was placed on introductory lectures, mainly associated with questions relating to the glass-formation and the structure of glasses. The second week focused more on research seminars. Each day of the meeting. about four posters were presented during the coffee breaks, and these formed an important focus for discussions. The posters are not reproduced in this volume as the editors wanted to have only larger contributions to make this volume more coherent. This volume is organized into four sections, starting with general considerations of the glass forming ability and techniques for the preparation of different kinds of glasses.

Organic solids exhibit a wide range of electrical and related properties. They occur as crystals, glasses, polymers and thin films; they may be insulators, semiconductors, conductors or superconductors; and they may show luminescence, nonlinear optical response, and complex dynamical behaviour. The book provides a broad survey of this area, written by international experts, one third being drawn from Eastern Europe. Electrical, optical, spectroscopic and structural aspects are all treated in a way that gives an excellent introduction to current themes in this highly interdisciplinary and practically important area. The coverage is especially strong in the areas where electrical and optical properties overlap, such as photoconductivity, electroluminescence, electroabsorption, electro-optics and photorefraction.

Despite the significant progress, which has been made in developing of ceramic materials desired for engineering applications, their mass production is still not on expected level. Among the key factors hindering higher exploitation of these materials the problems in processing were identified. The processing comprises powder production, mixing techniques, forming, and sintering. All of them are equally important and all of them can introduce defects into the material. Besides improvement in processing, the properties of ceramic materials can be considerably improved by the creation of composites. Composites formed at micro or macro level are able to form more flaw-tolerant material. Considerable research activities, working on above mentioned phenomena are in progress at industrial laboratories as well as other research centres. This volume presents the contributions to the Advanced Research Workshop "Engineering Ceramics '96" with 65 participants from 21 countries held on 12th - 15th May 1996 at Smolenice Castle, Slovakia, the conference site of Slovak Academy of Sciences. The book covers research activities on engineering ceramic materials and gives an overview with respect to recent developments.

Five questions dominated the ARW on Physics and Materials Science of High Temperature Superconductors, of which this book forms the permanent record. Briefly, these are: (i) How close are we to a unified theory? The consensus is that we are not. (ii) Flux pinning: can it be achieved in bulk materials? Still an open question. The following three questions are related. (iii) Can grain boundary contributions be brought under control? (iv) What is the real requirement for purity and general chemistry control? (v)What is the practical outlook for bulk products - tapes and wires? One of the conclusions is that the geometry and dimensions in thin films are the key parameters that facilitate the realization of high current densities and, consequently, their commercial application. On the other hand, the very large number of poorly understood microstructural, chemical and mechanical variables involved in the preparation of bulk materials are currently prohibiting large scale commercialization of wires and tapes.

Our understanding of the quantitative aspects of free radical chemistry and the involvement of radicals in such areas as biology, medicine and the environment has developed over recent years, yet the various topics are commonly discussed separately, in specific meetings and specialized publications. This volume draws together two important areas of free radical chemistry, using as a bridge the fundamental physical chemistry of free radicals (spectroscopic detection of free radicals, evaluation of absolute rate constants, elucidation of mechanisms of free radical reactions and catalysis, photochemical and radiation processes). The most relevant topics covered are the EPR detection of radicals in biochemical systems and in pollutant formation and degradation, oxidation processes in biology and in the troposphere, radiation and induced damage, and atmospheric pollutants arising from incomplete combustion. Also covered are the chemistry and biochemistry of nitric oxide and peroxynitrite, the chemistry and biochemistry of DNA radicals, the role of radicals in myeloperoxidase, lignineperoxidase, radicals and cardiovascular injury, radiation and the fragmentation of cells and tissues.

Recent advances in our understanding of complex composite media, especially chiral media for microwave applications, suggest the feasibility of creating novel materials with unusual properties and the possibility of constructing new microwave devices using such materials. The emphasis of the book is on bi-anisotropic materials, whose most interesting feature is the magnetoelectric interaction of the fields. The materials are expected to supply useful applications in radar technology, aerospace, microwave engineering, manufacturing technology, etc., such as absorbers for low-reflectivity shields, reciprocal phase shifters, polarization transformers. The first experiments with artificial bi-anisotropic media have been successfully carried out.

Californium-252 is a neutron emitter with a high specific activity, making it useful in a variety of applications, the most spectacular of which is in brachytherapy for cancer patients. Radiation oncology has exhausted nearly every option for treating radioresistant tumors by photon brachytherapy, and therefore new types of radiation need to be studied to improve the curability of cancer. Audience: Californium brachytherapy is used in only a few radiation therapy centers in the world, so the book will be highly instructive for radiation oncologists, medical physicists and radiobiologists. The nuclear techniques used in clinical applications may also interest nuclear physicists and engineers.

nd During June 13 -June 23 1996, the 2 EL. B. A. Foundation course on Genome, a NATO Advanced Study Institute, was held at Marcian Marina, Isle of Elba, Italy, - sponsored by the North Atlantic Treaty Organization and the EL. B. A. Fundation. The subject of the course was "Genome Structure and Function" with participants selected worldwire from 15 afferent countries. The purpose of the course and of the resulting book is the study of DNA structure (from the primary to the quintemary) and gene expression in the control of cell function and cell cycle progression; the topics were presented by top experts, covering both structural (cbwn to the atomic resolution) and functional (cbwn to gene level) aspects. The topics were presented by top experts and scientists active in the field, with the goal to give an insight into modm problems of genome study and recent ochievements in related fielm of molecular and cell biology, genetic engineering, biochemistry and biophysics, oncology and biotechnology. This resulting book is intenred to give a broad perspecti ve of the current stand of these fields.The major emphasis is towarm a reep unrerstanang of DNA structure and function in intetphase and metaphase chromosomes, originating by the parallel biophysical (namely NMR X-Ray and neutron scattering, spectropolarimetry, image analysis, calorimetry) and biochemical study conwcted on a wire range of cell systems placing the emphasis on either the higher orrer DNA structure or gene structure and function.

This text discusses the modelling and application of nonlinear microwave circuits, the problems of microwave electrodynamics, and applications of magnetic and high TC superconductor structures. Aspects of advanced methods for the structural investigation of materials and of MW remote sensing are also considered. The dual focus on both HTSC MW device physics and MW excitation in ferrites and magnetic films will foster the interaction of specialists in these different fields.

Ethylene is a simple gaseous plant hormone produced by higher plants, bacteria and fungi. Thanks to new tools that have become available in biochemistry and molecular genetics, parts of the ethylene biosynthesis, perception and signal transduction reactions have been elucidated. This knowledge has been applied to enhance the quality of a number of agronomically important crops. In Biology and Biotechnology of the Plant Hormone Ethylene, leading figures in the field provide surveys of the current state of ethylene biosynthesis and action, perception and signal transduction pathways, senescence, biotechnological control, and the involvement of ethylene in pathogenesis and stress. Audience: Indispensable to all academic, industrial and agricultural researchers as well as undergraduates and graduates in plant biology, biochemistry, genetics, molecular biology and food science.

M. BENcovA Slovak Foundation Education in Immunogenetics Kopanice 25, 821 04 Bratislava Slovak Republic Short History of Slovakia After the end of the 5th century, the major part of Central Europe was dominated by Slavs (Slovaks). They had already in the 7th century settle­ ments in the vicinity of towns Bratislava, Devin, Nitra to create the Slovak's state formation with the name "The Empire of Sam", territory of which corresponded to that of Slovakia of present. The Empire of Sam was also the first state formation in the Central Europe (as present states Czech Republic, Poland, Hungary, Slovakia etc. ) Very important town of this state was Nitra, with the biggest Castle in the Central Europe with his Duke Pribina. The first Church of the Central Europe was built here in the year 830, and it is now considered to be the "Slovak Bethlehem". In the year 880, Nitra also became the first Office of Bishops. Later, the Slovak Duke Pribina and Moravian Duke Mojmir (Moravia corresponded to eastern part of the present Czech Republic) joined their formations to common state "Greate Moravian Empire". The strongest King of the Great Moravian Empire was Svatopluk (864 A. D. ), who spread his empire over Czech Republic, Hungary and part of Poland, Ukraine and eastern Germany of present, which at that time still did not exist as state formations.

The Workshop on Physics and Application of Non-crystalline Semiconductors in Optoelectronics was held from 15 to 17 October 1996 in Chisinau. republic of Moldova and was devoted to the problems of non-crystalline semiconducting materials. The reports covered two mjlin topics: theoretical basis of physics of non -crystalline materials and experimental results. In the framework of these major topics there were treated many subjects. concerning the physics of non-crystalline semiconductors and their specific application: -optical properties of non-crystalline semiconductors; -doping of glassy semiconductors and photoinduced effects in chalcogenide glasses and their application for practical purposes; -methods for investigation of the structure in non-crystalline semiconductors -new glassy materials for IR trasmittance and optoelectronics. Reports and communications were presented on various aspects of the theory. new physical principles. studies of the atomic structure. search and development of optoelectronics devices. Special attention was paid to the actual subject of photoinduced transformations and its applications. Experimental investigations covered a rather wide spectrum of materials and physical phenomena. As a novel item it is worth to mention the study of nonlinear optical effects in amorphous semiconducting films. The third order optical non­ linearities. fast photoinduced optical absorption and refraction. acusto-optic effects recently discovered in non-crystalline semiconductors could potentially be utilised for optical signal processing. The important problems of photoinduced structural transformations and related phenomena. which are very attractive and actual both from the scientific and practical points of view. received much attention in discussions atthe conference.

The NATO Advanced Research Workshop (ARW) on "Regulation of Enzymatic Systems Detoxifying Xenobiotics in Plants" intended to provide a forum to scientists from academia, industry, and govemment for discussing and critically assessing recent advances in the field of xenobiotic metabolism in plants and for identifying new directions for future research. Plants function in a chemical environment made up of nutrients and xenobiotics. Xenobiotics (foreign chemicals) are natural or synthetic compounds that can not be utilized by plants for energy-yielding metabolism. Plants may be exposed to xenobiotics either deliberately, due to their use as pesticides or accidentally, from industrial, agricultural, and other uses. Plants, like most other organisms, evolved a remarkable battery or metabolic reactions to defend themselves against the potentially toxic effects of xenobiotics. The main enzymatic reactions utilized by plants for xenobiotic detoxification include oxidation, reduction, hydrolysis and conjugation with glutathione, sugars (e.g., glucose), and amino acids. Eventually, xenobiotic conjugates are converted to insoluble bound residues or to secondary conjugates, which are deposited in the vacuole of plant cells.

Diamond-based composites, with their advantages of hardness, high Young's modulus and the like, have demonstrated new and unusual features, such as stability to high temperatures and pressure shocks and a large internal surface that can be controlled to offer customised electrical, magnetic and optical properties, leading to efficient filters, absorbents, sensors and other tools for environmental control and monitoring. The current book covers the synthesis of materials, their characterization and properties, trends in high pressure and high temperature technologies, low pressure technologies, basic principles of DBC material science, and future developments in electronics, optics, industrial tools and components, biotechnology, and medicine. Wide band-gap materials are considered, ranging from molecular clusters, nanophase materials, growth, processing and synthesis. The processing of composite based materials can be classified into six basic methods: in situ growth, high pressure/high temperature catalytic conversion; mix and sinter (c-BN plus metal-ceramic polymer mix); direct sintering; direct polymorphic conversion; shock detonation; and SHS sintering.

The miniaturization and performance improvements provided by solid state lasers, fibre optics and avalanche photodiode detectors have given a significant impulse to the use of photon correlation techniques in the study of laser scattering by macromolecular suspensions, liquid surfaces, critical fluids and turbulent liquids. The improvements can be found in experimental technique, colloids and aggregation, polymers, gels, liquid crystals and mixtures, protein solutions and dense media. Powerful new methods of inverse problems are being applied to data analysis. Much progress is being made in the study of dense media using index matching techniques, two colour systems and the theory of photon diffusion. Other notable developments are phase transitions in the space shuttle microgravity environment, quantum cryptography and the application of photon correlation at X-ray wavelengths using synchrotron sources. Audience: Postgraduate and industrial researchers interested in particle sizing and particle interactions, the physical chemistry of polymers, proteins, enzymes, viruses and other macromolecules, optical instrumentation, and experiments in space.

A unique selection of papers on the most recent progress in the modelling of biological molecules containing metal ions. New approaches and techniques in this field are allowing researchers to discuss structures, electronic properties and reaction mechanisms of metalloproteins on the basis of computational studies. The book discusses different approaches in the development of new force fields and their application to the computation of the structures, electronic properties and dynamics of bioinorganic compounds as well as quantum mechanical and integrated QM/MM methods for understanding the function of metalloenzymes and the calculation of electrostatic interactions.